Nickel(2+) diformate
C2H2NiO4
nickel(2+) diformate
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Identification
- CAS Number
- 3349-06-2
- EC Number
- 222-101-0
- UN Number
- 3077
- Index Number
- 028-021-00-0
- PubChem CID
- 27506
Physical-chemical properties
- Molecular Formula
- C2H2NiO4
- Molar Mass
- 148.73 g/mol
- IUPAC Name
- nickel(2+) diformate
Chemical Identifiers
- InChI
- InChI=1S/2CH2O2.Ni/c2*2-1-3;/h2*1H,(H,2,3);/q;;+2/p-2
- InChI Key
- HZPNKQREYVVATQ-UHFFFAOYSA-L
Overview
Nickel(2+) diformate (CAS 3349-06-2) is an inorganic nickel salt with significant industrial applications and notable health hazard classifications. This chemical compound, also known by its IUPAC name nickel(2+) diformate, represents a critical intermediate in various industrial processes. With the molecular formula C2H2NiO4 and a molecular weight of 148.73 g/mol, this nickel-based compound is characterized by its formate anion structure. The substance is assigned EC number 222-101-0 and falls under ADR transport class 9, indicating its classification as a miscellaneous dangerous substance. The compound presents significant safety considerations, as evidenced by its comprehensive hazard classification including carcinogenicity (Carc. 1A), mutagenicity (Muta. 2), reproductive toxicity (Repr. 1B), specific target organ toxicity (STOT RE 1), and sensitization properties for both respiratory and skin contact. The GHS pictograms GHS08 and GHS09 reflect its health hazards and environmental dangers, while the "Danger" signal word emphasizes the severity of associated risks. These properties are typical of nickel compounds, sharing similarities with related substances such as diiodonickel in terms of their potential health impacts. Primary industrial applications include catalysis processes, electroplating operations, and specialized chemical synthesis where nickel formate serves as a precursor or reactive intermediate. The compound's unique chemical structure makes it valuable in producing nickel-based catalysts and in certain metallurgical applications requiring controlled nickel ion release. Due to its hazardous nature, proper handling protocols, adequate ventilation systems, and appropriate personal protective equipment are essential when working with nickel(2+) diformate. OYSI provides this specialized chemical compound to qualified industrial customers with comprehensive safety documentation and regulatory compliance support.
Safety & Classification
Carc. 1A; Muta. 2; Repr. 1B; STOT RE 1; Resp. Sens. 1; Skin Sens. 1; Aquatic Acute 1; Aquatic Chr...
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Suspected of causing genetic defects.
Causes damage to organs through prolonged or repeated exposure.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
Very toxic to aquatic life.
Very toxic to aquatic life with long lasting effects.
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 3077 |
| ADR Class | 9 |
| Packing Group | III |
| Tunnel Code | - |
| Proper Shipping Name | Nickel(II)-formiat |
| Marine Pollutant | No |
Frequently Asked Questions
What is nickel(2+) diformate?
Nickel(2+) diformate is an inorganic chemical compound with the molecular formula C2H2NiO4 and CAS number 3349-06-2. This nickel salt consists of a nickel(II) cation bound to two formate anions, resulting in a molecular weight of 148.73 g/mol. It is classified as a hazardous substance with multiple health and environmental risks, including carcinogenic, mutagenic, and reproductive toxicity properties, requiring careful handling in industrial applications.
What are the physicochemical properties of nickel(2+) diformate?
Nickel(2+) diformate is a solid crystalline compound at room temperature with a distinctive appearance typical of nickel salts. The substance has a molecular weight of 148.73 g/mol and contains nickel in its +2 oxidation state. Like most nickel compounds, it likely exhibits characteristic coloration and demonstrates solubility properties that make it suitable for various industrial processes. Its chemical structure consists of nickel coordinated with formate ligands.
What is nickel(2+) diformate used for?
Nickel(2+) diformate serves as an important industrial chemical primarily used in specialized manufacturing processes. Its applications typically include use as a catalyst precursor, in electroplating processes, and as a source of nickel ions in various chemical syntheses. The compound may also find applications in research and development activities where controlled nickel delivery is required. Due to its hazardous nature, its use is restricted to professional industrial settings with appropriate safety measures.
How to handle nickel(2+) diformate safely?
Nickel(2+) diformate requires strict safety protocols due to its carcinogenic, mutagenic, and sensitizing properties. Personal protective equipment must include respiratory protection, chemical-resistant gloves, safety goggles, and protective clothing to prevent skin and respiratory contact. Work should be conducted in well-ventilated areas or under fume extraction systems. Personnel must be trained in proper handling procedures and emergency response. Regular health monitoring may be required for workers with potential exposure.
How to store nickel(2+) diformate correctly?
Nickel(2+) diformate must be stored in tightly sealed containers in a cool, dry, well-ventilated area away from incompatible materials. Storage areas should be clearly labeled and access restricted to authorized personnel only. The substance should be kept away from sources of ignition, heat, and moisture. Secondary containment may be required to prevent environmental release. Regular inspection of storage containers and conditions is essential to maintain product integrity and safety.
What to do in case of contact with nickel(2+) diformate?
Immediate action is required for any contact with nickel(2+) diformate. For skin contact, remove contaminated clothing and wash affected area thoroughly with soap and water for at least 15 minutes. If inhaled, move to fresh air immediately and seek medical attention. For eye contact, flush with clean water for 15 minutes and remove contact lenses if present. In all cases, seek immediate medical attention and provide the safety data sheet to healthcare providers.
How to dispose of nickel(2+) diformate appropriately?
Nickel(2+) diformate disposal must comply with local and national hazardous waste regulations due to its toxic and environmental properties. The substance cannot be disposed of in regular waste streams and requires specialized hazardous waste treatment. Contact licensed waste disposal companies for proper collection and treatment. Never discharge into sewers, waterways, or soil. Waste containers must be properly labeled and documented according to regulatory requirements for hazardous materials.
How to transport nickel(2+) diformate?
Nickel(2+) diformate is classified as ADR Class 9 (Miscellaneous Dangerous Goods), Packing Group III, indicating moderate danger during transport. Transportation requires appropriate UN-approved packaging, proper labeling with hazard pictograms, and accompanying transport documents. Drivers and handlers must be trained in dangerous goods regulations. Vehicles should carry emergency equipment and spill containment materials. Transport should follow designated routes and comply with quantity limitations for this classification.
Is nickel(2+) diformate subject to specific regulations?
Nickel(2+) diformate is subject to comprehensive European chemical regulations including REACH registration requirements and CLP classification obligations. The substance carries multiple hazard classifications including Carcinogenic 1A, Mutagenic 2, and Reproductive toxicity 1B, triggering strict labeling and safety data sheet requirements. Occupational exposure limits may apply, and users must implement appropriate risk management measures. Import, use, and disposal are regulated under various environmental and workplace safety directives.
Where to buy nickel(2+) diformate in Europe?
Nickel(2+) diformate is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across Europe. OYSI provides this regulated chemical compound to qualified industrial users with proper documentation and safety data sheets. Due to the hazardous nature of this substance, purchases are restricted to professional users with appropriate handling capabilities and regulatory compliance. Contact OYSI directly for availability, specifications, and regulatory documentation requirements.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.