Nickel(2+) diformate

C2H2NiO4

nickel(2+) diformate

CAS3349-06-2
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
3349-06-2
EC Number
222-101-0
UN Number
3077
Index Number
028-021-00-0
PubChem CID
27506

Physical-chemical properties

Molecular Formula
C2H2NiO4
Molar Mass
148.73 g/mol
IUPAC Name
nickel(2+) diformate

Chemical Identifiers

InChI
InChI=1S/2CH2O2.Ni/c2*2-1-3;/h2*1H,(H,2,3);/q;;+2/p-2
InChI Key
HZPNKQREYVVATQ-UHFFFAOYSA-L

Overview

Nickel(2+) diformate (CAS 3349-06-2) is an inorganic nickel salt compound with significant industrial applications and notable health hazard properties. This nickel formate compound, with the molecular formula C2H2NiO4 and a molecular weight of 148.73 g/mol, represents an important member of the nickel salt family used in various technical applications. The substance is classified under EC number 222-101-0 and falls within ADR transport class 9, indicating its status as a miscellaneous dangerous substance requiring careful handling protocols. The compound exhibits extensive hazard classifications including Category 1A carcinogenicity, reproductive toxicity, and respiratory sensitization properties, necessitating stringent safety measures during storage, handling, and application. These characteristics place it alongside other nickel compounds such as diiodonickel in requiring specialized expertise for safe industrial use. The GHS08 and GHS09 pictograms indicate both health hazards and environmental dangers, with the "Danger" signal word reflecting the severity of potential risks. Nickel(2+) diformate finds primary applications in electroplating processes, where it serves as a nickel source for metal surface treatments. The compound is also utilized in catalyst preparation for various chemical synthesis reactions and in specialized coating formulations where controlled nickel content is essential. Similar to other nickel salts like bis(2-hydroxypropanoic acid);nickel, it plays a crucial role in materials science applications requiring precise nickel incorporation. The aquatic toxicity classification emphasizes the need for proper environmental controls and waste management procedures. Industrial users must implement appropriate ventilation systems, personal protective equipment protocols, and environmental monitoring to ensure compliance with occupational and environmental safety standards. OYSI maintains technical-grade nickel(2+) diformate availability for qualified industrial customers with appropriate safety handling capabilities.

Safety & Classification

Danger
Classification:

Carc. 1A; Muta. 2; Repr. 1B; STOT RE 1; Resp. Sens. 1; Skin Sens. 1; Aquatic Acute 1; Aquatic Chr...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H341

Suspected of causing genetic defects.

H372

Causes damage to organs through prolonged or repeated exposure.

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameNickel(II)-formiat
Marine PollutantNo

Frequently Asked Questions

What is nickel(2+) diformate?

Nickel(2+) diformate is an inorganic nickel salt with the molecular formula C2H2NiO4 and CAS number 3349-06-2. This chemical compound has a molecular weight of 148.73 g/mol and consists of a divalent nickel cation complexed with two formate anions. It belongs to the family of nickel compounds and presents significant health and environmental hazards, classified as a Category 1A carcinogen with additional reproductive and respiratory sensitization properties.

What are the physicochemical properties of nickel(2+) diformate?

Nickel(2+) diformate is a solid crystalline compound at room temperature with characteristic properties typical of nickel salts. The substance typically appears as colored crystals, as most nickel(II) compounds exhibit distinctive coloration due to d-electron transitions. Its molecular structure consists of nickel coordinated with formate ligands, contributing to its specific chemical behavior. The compound's solubility and other physical properties depend on environmental conditions such as temperature and pH.

What is nickel(2+) diformate used for?

Nickel(2+) diformate is primarily used in specialized industrial applications requiring nickel compounds. It serves as a precursor in catalysis processes, particularly in organic synthesis and chemical manufacturing. The compound may be utilized in electroplating processes, battery manufacturing, and as an intermediate in the production of other nickel-based materials. Its applications are typically restricted to professional industrial settings due to its hazardous classification and regulatory constraints.

How to handle nickel(2+) diformate safely?

Nickel(2+) diformate requires strict safety measures due to its carcinogenic and sensitizing properties. Personal protective equipment must include respiratory protection (P3 filter), chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation. Direct skin contact must be avoided at all costs. Only trained personnel should handle this substance, following established safety protocols and emergency procedures.

How to store nickel(2+) diformate correctly?

Nickel(2+) diformate must be stored in tightly sealed containers in a cool, dry, well-ventilated area away from incompatible materials. Storage areas should be restricted to authorized personnel only, with appropriate warning signs indicating the carcinogenic nature of the substance. The storage facility must comply with local regulations for hazardous substances. Containers should be properly labeled and protected from physical damage, moisture, and temperature fluctuations to maintain product integrity.

What to do in case of contact with nickel(2+) diformate?

Immediate action is required upon contact with nickel(2+) diformate. For skin contact, remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, rinse immediately with clean water for 15 minutes and seek medical attention. If inhaled, move the person to fresh air and seek immediate medical care. For ingestion, do not induce vomiting and seek emergency medical assistance immediately.

How to dispose of nickel(2+) diformate properly?

Nickel(2+) diformate must be disposed of as hazardous waste through licensed waste management companies specializing in heavy metal compounds. The substance cannot be disposed of in regular waste streams due to its carcinogenic properties and environmental toxicity. Disposal must comply with local and European waste regulations, including proper documentation and tracking. Empty containers may also require special treatment due to potential residual contamination with the hazardous substance.

How to transport nickel(2+) diformate?

Nickel(2+) diformate is classified as Class 9 dangerous goods under ADR regulations with Packing Group III designation. Transportation requires appropriate packaging, labeling with GHS08 and GHS09 pictograms, and proper shipping documentation. Vehicles must carry appropriate emergency equipment and drivers need hazardous materials training. The transport must comply with ADR/RID regulations for miscellaneous dangerous substances, including route restrictions and quantity limitations for different transport categories.

Is nickel(2+) diformate subject to specific regulations?

Nickel(2+) diformate is subject to comprehensive European chemical regulations including REACH registration requirements and CLP classification obligations. The substance must be classified with multiple hazard categories including Carc. 1A, Muta. 2, and Repr. 1B, requiring specific labeling and safety data sheets. Industrial users must implement appropriate risk management measures and may face restrictions under various chemical safety regulations. Workplace exposure limits and monitoring requirements may apply under occupational health legislation.

Where to buy nickel(2+) diformate in Europe?

Nickel(2+) diformate is available through specialized chemical distributors like OYSI, which serves the European market with professional-grade chemicals. Due to its hazardous classification, purchase is typically restricted to qualified industrial users with appropriate handling capabilities and regulatory compliance. Buyers must provide proper documentation and may need to demonstrate legitimate use and adequate safety measures. OYSI can provide technical support and regulatory guidance for European customers requiring this specialized nickel compound.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.