Zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate)

C8H12MnN4S8Zn

zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate)

CAS8018-01-7
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
8018-01-7
UN Number
3077
Index Number
006-076-00-1
PubChem CID
3034368

Physical-chemical properties

Molecular Formula
C8H12MnN4S8Zn
Molar Mass
541.10 g/mol
IUPAC Name
zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate)

Chemical Identifiers

InChI
InChI=1S/2C4H8N2S4.Mn.Zn/c2*7-3(8)5-1-2-6-4(9)10;;/h2*1-2H2,(H2,5,7,8)(H2,6,9,10);;/q;;2*+2/p-4
InChI Key
CHNQZRKUZPNOOH-UHFFFAOYSA-J

Overview

Zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate) (CAS 8018-01-7) is a complex organometallic dithiocarbamate compound containing both zinc and manganese cations with significant biological activity and industrial applications. This dual-metal dithiocarbamate complex represents an important class of organometallic compounds widely utilized in industrial applications. With a molecular formula of C8H12MnN4S8Zn and molecular weight of 541.1 g/mol, this compound combines the properties of both zinc and manganese metals with dithiocarbamate ligands, creating a versatile chemical with multiple industrial uses. The compound's structure features sulfur-rich coordination environments that provide unique chemical reactivity and stability characteristics. The substance presents significant safety considerations, classified with hazard classes including carcinogenicity (Carc. 2), reproductive toxicity (Repr. 1B), and specific target organ toxicity (STOT RE 2). It also exhibits skin sensitization properties and poses acute and chronic aquatic toxicity risks. The compound carries GHS08, GHS07, and GHS09 pictograms with a "Danger" signal word, reflecting its serious health and environmental hazards. Proper handling requires comprehensive safety protocols including appropriate personal protective equipment and containment measures. Primary industrial applications include fungicidal formulations, rubber vulcanization acceleration, and specialized chemical synthesis processes. The compound's dual-metal composition offers advantages in applications where both zinc and manganese properties are beneficial. Unlike simpler compounds such as cobalt(2+) sulfate, this complex dithiocarbamate structure provides enhanced stability and specific reactivity profiles. Its classification under ADR Class 9 miscellaneous dangerous goods requires specialized transportation and storage protocols. OYSI maintains availability of this specialized organometallic compound for qualified industrial customers with appropriate handling capabilities and regulatory compliance.

Safety & Classification

Danger
Classification:

Carc. 2; Repr. 1B; STOT RE 2; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H351

Suspected of causing cancer.

H373

May cause damage to organs through prolonged or repeated exposure.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameMancozeb (ISO)
Marine PollutantNo

Frequently Asked Questions

What is zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate)?

Zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate) is a complex organometallic compound containing zinc and manganese metals coordinated with dithiocarbamate ligands. With CAS number 8018-01-7 and molecular formula C8H12MnN4S8Zn, this substance has a molecular weight of 541.1 g/mol. It belongs to the family of metal dithiocarbamate complexes and is classified as a hazardous substance with multiple health and environmental concerns including carcinogenic, reproductive toxic, and aquatic toxic properties.

What are the physicochemical properties of zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate)?

Zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate) is a solid organometallic compound with a molecular weight of 541.1 g/mol and molecular formula C8H12MnN4S8Zn. As a metal dithiocarbamate complex, it typically appears as a colored solid due to the presence of transition metals (zinc and manganese). The compound contains multiple sulfur atoms and metal coordination sites, which influence its stability and reactivity. Specific physical properties such as melting point, solubility, and exact appearance may vary depending on the preparation method and purity.

What is zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate) used for?

Zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate) is primarily used as a fungicide and biocide in industrial applications. Metal dithiocarbamate complexes like this compound are employed in agricultural formulations, wood preservation, and as antimicrobial agents in various industrial processes. The combination of zinc and manganese provides enhanced biological activity compared to single-metal complexes. Due to its hazardous classification including carcinogenic and reproductive toxic properties, its use is strictly regulated and limited to professional applications with appropriate safety measures.

How to handle zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate) safely?

Zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate) requires strict safety precautions due to its carcinogenic (Carc. 2), reproductive toxic (Repr. 1B), and skin sensitizing (Skin Sens. 1) properties. Essential personal protective equipment includes respiratory protection, chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume extraction. Avoid skin contact, inhalation, and ingestion. The substance carries the 'Danger' signal word with GHS08, GHS07, and GHS09 pictograms, indicating serious health and environmental hazards.

How to store zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate) correctly?

Zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate) must be stored in a cool, dry, well-ventilated area away from incompatible materials. As an organometallic compound with multiple hazard classifications, it requires secure storage with restricted access due to its carcinogenic and reproductive toxic properties. Store in original, tightly sealed containers with appropriate hazard labeling. Avoid exposure to moisture, extreme temperatures, and sources of ignition. Storage areas should comply with local regulations for hazardous substances and include appropriate containment measures to prevent environmental release.

What to do in case of contact with zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate)?

Immediate action is required for any contact with zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate) due to its toxic properties. For skin contact, remove contaminated clothing and wash affected area thoroughly with soap and water. In case of eye contact, rinse immediately with plenty of clean water for at least 15 minutes. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult a physician after exposure, providing the safety data sheet. Due to its carcinogenic and reproductive toxic classification, professional medical evaluation is essential.

How to dispose of zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate) properly?

Zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate) requires specialized hazardous waste disposal due to its multiple dangerous properties including carcinogenic, reproductive toxic, and aquatic toxic classifications. Disposal must comply with local and European waste regulations, typically requiring treatment by authorized hazardous waste management facilities. The substance cannot be disposed of in regular waste streams or sewerage systems due to its environmental toxicity (Aquatic Acute 1, Aquatic Chronic 1). Consult local environmental authorities and use only licensed waste disposal contractors with appropriate permits for handling metal-containing hazardous substances.

How to transport zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate)?

Zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate) is classified as ADR Class 9 (Miscellaneous dangerous substances), Packing Group III for transportation purposes. This classification requires specific packaging, labeling, and documentation according to European transport regulations. Packages must bear appropriate hazard labels and proper shipping names. Transport vehicles need placarding and drivers require ADR certification. Due to its multiple hazard classifications including carcinogenic and environmental dangers, additional precautions may be required. Consult current ADR regulations and work with qualified transport companies experienced in handling hazardous chemicals.

Is zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate) subject to specific regulations?

Zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate) is subject to strict European chemical regulations under REACH and CLP due to its hazardous properties. While not currently listed as a Substance of Very High Concern (SVHC), its classification as carcinogenic (Carc. 2) and reproductive toxic (Repr. 1B) subjects it to authorization and restriction procedures. Users must comply with occupational exposure limits, safety data sheet requirements, and notification obligations. The substance may also fall under biocide regulations if used for antimicrobial purposes. Regular regulatory updates should be monitored as restrictions may be implemented.

Where to buy zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate) in Europe?

Zinc;manganese(2+);bis(N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate) is available through specialized chemical distributors like OYSI, a European distributor of technical chemicals. Due to its hazardous classification including carcinogenic and reproductive toxic properties, purchase is typically restricted to professional users with appropriate safety infrastructure and regulatory compliance. Buyers must demonstrate legitimate industrial use and proper handling capabilities. OYSI can provide technical support, safety documentation, and regulatory guidance for this specialized organometallic compound. Contact qualified chemical suppliers who maintain proper licensing for distributing hazardous substances in your region.

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Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.