Nickel(2+) dicyanide

C2N2Ni

nickel(2+) dicyanide

CAS557-19-7
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
557-19-7
EC Number
209-160-8
UN Number
1653
Index Number
028-034-00-1
PubChem CID
6093189

Physical-chemical properties

Molecular Formula
C2N2Ni
Molar Mass
110.73 g/mol
IUPAC Name
nickel(2+) dicyanide

Chemical Identifiers

InChI
InChI=1S/2CN.Ni/c2*1-2;/q2*-1;+2
InChI Key
NLEUXPOVZGDKJI-UHFFFAOYSA-N

Overview

Nickel(2+) dicyanide (CAS 557-19-7) is an inorganic cyanide compound with significant industrial applications and notable safety considerations requiring specialized handling protocols. This chemical substance, also known by its IUPAC designation nickel(2+) dicyanide, represents a specialized coordination compound containing nickel in its divalent oxidation state bonded to two cyanide ligands. With the molecular formula C2N2Ni and a molecular weight of 110.73 g/mol, this compound exhibits unique properties that make it valuable in various industrial processes while requiring stringent safety measures due to its hazardous nature. The substance is classified under multiple serious hazard categories, including Category 1A carcinogen, respiratory tract sensitizer, and skin sensitizer, necessitating comprehensive risk management protocols. Its classification as STOT RE 1 indicates specific target organ toxicity following repeated exposure, while its aquatic toxicity ratings reflect significant environmental concerns. These safety characteristics distinguish it from related nickel compounds such as nickel(2+) sulfite, which has different toxicological profiles and applications. The compound's ADR classification as Class 6.1 (toxic substances) underscores the critical importance of proper transportation and storage procedures. GHS pictograms GHS08 and GHS09 visually communicate its health hazards and environmental dangers, supporting workplace safety programs and regulatory compliance efforts. Primary industrial applications include specialized electroplating processes, catalyst formulations, and chemical synthesis operations where its unique coordination chemistry provides specific advantages. The compound also finds use in advanced materials manufacturing and certain analytical chemistry applications. OYSI maintains availability of nickel(2+) dicyanide for qualified industrial customers, ensuring proper documentation, safety data sheets, and regulatory compliance support throughout the supply chain.

Safety & Classification

Danger
Classification:

Carc. 1A; STOT RE 1; Resp. Sens. 1; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H372

Causes damage to organs through prolonged or repeated exposure.

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1653
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameNickelcyanid, fest
Marine PollutantNo

Frequently Asked Questions

What is nickel(2+) dicyanide?

Nickel(2+) dicyanide is an inorganic chemical compound with the molecular formula C2N2Ni and CAS number 557-19-7. This substance has a molecular weight of 110.73 g/mol and contains nickel in its +2 oxidation state combined with two cyanide groups. It is classified as a highly hazardous material due to its carcinogenic properties, respiratory and skin sensitization potential, and environmental toxicity. The compound is regulated under various safety frameworks due to its significant health and environmental risks.

What are the physicochemical properties of nickel(2+) dicyanide?

Nickel(2+) dicyanide is a solid compound at room temperature with specific physicochemical characteristics related to its inorganic nature. As a nickel-containing cyanide compound, it exhibits properties typical of transition metal complexes. The substance has a molecular weight of 110.73 g/mol and contains both metallic nickel and cyanide functional groups. Specific physical properties such as color, odor, and solubility would require detailed technical documentation for precise characterization.

What is nickel(2+) dicyanide used for?

Nickel(2+) dicyanide is primarily used in specialized industrial applications where nickel-cyanide chemistry is required. Common applications include electroplating processes, metal finishing operations, and as a precursor in certain chemical syntheses. Due to its hazardous classification as a carcinogen and respiratory sensitizer, its use is strictly controlled and limited to professional industrial settings with appropriate safety measures. The compound may also serve research purposes in analytical chemistry and materials science applications.

How to handle nickel(2+) dicyanide safely?

Nickel(2+) dicyanide requires extremely careful handling due to its carcinogenic and sensitizing properties. Essential personal protective equipment includes respiratory protection, chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Avoid skin and eye contact completely. Only trained personnel should handle this substance, following strict workplace safety protocols. Regular health monitoring may be required for workers with potential exposure to this hazardous material.

How to store nickel(2+) dicyanide correctly?

Nickel(2+) dicyanide must be stored in a secure, well-ventilated area away from incompatible materials and heat sources. Storage should comply with regulations for carcinogenic substances, typically requiring locked, designated areas with restricted access. Containers must be properly labeled and sealed to prevent contamination and exposure. Due to its aquatic toxicity, storage areas should have appropriate containment measures to prevent environmental release. Temperature and humidity control may be necessary to maintain product stability and prevent degradation.

What to do in case of contact with nickel(2+) dicyanide?

Immediate action is required in case of contact with nickel(2+) dicyanide due to its hazardous nature. For skin contact, remove contaminated clothing and wash affected areas thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush immediately with clean water for 15 minutes and seek medical attention. If inhaled, move the person to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention. Always contact emergency services and provide the safety data sheet to medical personnel.

How to dispose of nickel(2+) dicyanide appropriately?

Nickel(2+) dicyanide disposal must comply with hazardous waste regulations due to its carcinogenic and environmental properties. The substance cannot be disposed of through regular waste streams and requires specialized hazardous waste treatment facilities. Disposal must follow local and national environmental regulations, typically requiring manifest documentation and certified waste handlers. Due to its heavy metal content and cyanide groups, specific treatment processes may be required before final disposal. Contact licensed hazardous waste disposal companies for proper handling and documentation.

How to transport nickel(2+) dicyanide?

Nickel(2+) dicyanide is classified under ADR Class 6.1 (toxic substances) Packing Group II, indicating significant transport restrictions. Transportation requires proper dangerous goods packaging, labeling with appropriate hazard pictograms (GHS08, GHS09), and documentation including transport permits. Only certified dangerous goods transporters should handle shipments. Vehicles must comply with ADR regulations including proper placarding, emergency equipment, and driver certification. Packaging must meet UN specification standards for Class 6.1 materials with appropriate containment and leak prevention measures.

Is nickel(2+) dicyanide subject to particular regulations?

Nickel(2+) dicyanide is subject to extensive regulatory oversight due to its hazardous classification. Under EU CLP regulation, it carries multiple hazard classifications including carcinogenicity (1A), respiratory sensitization, and aquatic toxicity. REACH registration requirements apply for commercial use within the EU. Workplace exposure limits and occupational health surveillance may be mandated. Environmental discharge restrictions apply due to its aquatic toxicity. Import/export may require special permits, and use restrictions could apply in certain applications or concentrations.

Where to buy nickel(2+) dicyanide in Europe?

Nickel(2+) dicyanide is available through specialized chemical distributors in Europe, including OYSI, which supplies industrial chemicals to European markets. Due to its hazardous classification, purchase requires appropriate business licenses, safety certifications, and compliance with regulatory requirements. Buyers must demonstrate legitimate industrial use and appropriate handling capabilities. OYSI can provide technical support, safety documentation, and regulatory compliance assistance for European customers requiring this specialized chemical compound for professional applications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.