Dichloronickel

Cl2Ni

dichloronickel

CAS7718-54-9
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
7718-54-9
EC Number
231-743-0
UN Number
3288
Index Number
028-011-00-6
PubChem CID
24385

Physical-chemical properties

Molecular Formula
Cl2Ni
Molar Mass
129.60 g/mol
IUPAC Name
dichloronickel

Chemical Identifiers

InChI
InChI=1S/2ClH.Ni/h2*1H;/q;;+2/p-2
InChI Key
QMMRZOWCJAIUJA-UHFFFAOYSA-L

Overview

Dichloronickel (CAS 7718-54-9) is an inorganic nickel compound with significant industrial applications and notable safety considerations due to its carcinogenic properties. This crystalline chemical compound, with the molecular formula Cl2Ni and a molecular weight of 129.6 g/mol, represents one of the most important nickel halides in industrial chemistry. Also known by its IUPAC designation dichloronickel, this substance appears as a yellow to brown solid that is highly soluble in water and polar solvents. The compound's classification under multiple hazard categories, including Category 1A carcinogen, Category 2 mutagen, and Category 1B reproductive toxicant, necessitates stringent handling protocols and specialized safety measures. The chemical structure of dichloronickel features nickel in its +2 oxidation state, coordinated with two chloride ions. This configuration makes it particularly valuable as a catalyst precursor and intermediate in various chemical processes. Unlike other toxic compounds such as phenylhydrazine or N-methylaniline, dichloronickel's primary hazards stem from its metal content rather than organic toxicity pathways, requiring different risk management approaches. Industrial applications of dichloronickel include its use as a catalyst in organic synthesis reactions, particularly in cross-coupling reactions and hydrogenation processes. The compound also serves as a precursor for manufacturing other nickel-based chemicals and materials used in electronics and specialized coatings. Additionally, it finds application in electroplating solutions where controlled nickel deposition is required. Given its ADR Class 6.1 classification and multiple GHS pictograms (GHS08, GHS06, GHS09), proper storage, handling, and transportation protocols are essential. OYSI maintains availability of high-quality dichloronickel with comprehensive safety documentation and technical support for qualified industrial customers.

Safety & Classification

Danger
Classification:

Carc. 1A; Muta. 2; Repr. 1B; Acute Tox. 3 *; Acute Tox. 3 *; STOT RE 1; Skin Irrit. 2; Resp. Sens...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H341

Suspected of causing genetic defects.

H331

Toxic if inhaled.

H301

Toxic if swallowed.

H372

Causes damage to organs through prolonged or repeated exposure.

H315

Causes skin irritation.

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3288
ADR Class6.1
Packing GroupIII
Tunnel CodeE
Proper Shipping NameNickeldichlorid
Marine PollutantNo

Frequently Asked Questions

What is dichloronickel?

Dichloronickel is an inorganic chemical compound with the molecular formula Cl2Ni and CAS number 7718-54-9. This nickel salt has a molecular weight of 129.6 g/mol and is classified as a highly hazardous substance due to its carcinogenic, mutagenic, and reproductive toxic properties. It carries the GHS danger signal word and requires strict handling protocols in industrial applications.

What are the physicochemical properties of dichloronickel?

Dichloronickel is typically found as a solid crystalline material at room temperature. As an anhydrous nickel chloride compound, it exhibits hygroscopic properties and is highly soluble in water and polar solvents. The compound appears as yellow-green crystals in its anhydrous form and demonstrates typical ionic compound characteristics with high melting and boiling points.

What is dichloronickel used for?

Dichloronickel is primarily used as a catalyst in organic synthesis reactions and as a precursor for preparing other nickel compounds. It serves as an important intermediate in electroplating processes, battery manufacturing, and specialized chemical syntheses. The compound is also utilized in research applications and as a starting material for producing nickel-based catalysts in industrial chemical processes.

How to handle dichloronickel safely?

Dichloronickel requires strict safety protocols due to its classification as Carc. 1A, Muta. 2, and Repr. 1B. Essential PPE includes respiratory protection, chemical-resistant gloves, safety goggles, and protective clothing. Work must be conducted in well-ventilated areas or under fume hoods. Avoid skin contact, inhalation, and ingestion. Regular health monitoring is recommended for workers exposed to this substance.

How to store dichloronickel correctly?

Dichloronickel must be stored in tightly sealed containers in a cool, dry, well-ventilated area away from incompatible materials. Due to its hygroscopic nature, moisture protection is essential. Storage areas should be secure with restricted access due to the substance's high toxicity classification. Keep away from heat sources, oxidizing agents, and ensure appropriate labeling with GHS pictograms GHS06, GHS08, and GHS09.

What to do in case of contact with dichloronickel?

Dichloronickel exposure requires immediate action due to its acute toxicity. For skin contact, remove contaminated clothing and rinse thoroughly with water for at least 15 minutes. If inhaled, move to fresh air immediately and seek medical attention. In case of eye contact, flush with water for 15 minutes. For ingestion, do not induce vomiting and seek immediate medical help. Always consult emergency services for serious exposures.

How to dispose of dichloronickel appropriately?

Dichloronickel disposal must comply with hazardous waste regulations due to its high toxicity classification. The substance requires specialized hazardous waste treatment and cannot be disposed of through regular waste streams. Contact licensed hazardous waste disposal companies for proper collection and treatment. Ensure proper documentation and follow local environmental regulations for heavy metal-containing waste disposal.

How to transport dichloronickel?

Dichloronickel is classified under ADR Class 6.1 (Toxic substances), Packing Group III for transportation purposes. It requires appropriate hazardous goods packaging, labeling, and documentation according to dangerous goods regulations. Transporters must be certified for handling Class 6.1 materials and vehicles must display proper hazard placards. Shipping documentation must include safety data sheets and emergency response information.

Is dichloronickel subject to specific regulations?

Dichloronickel is subject to strict regulatory oversight under REACH and CLP regulations in Europe due to its classification as carcinogenic, mutagenic, and toxic for reproduction. While not currently listed as an SVHC, it requires safety data sheets, proper classification, and labeling. Industrial users must implement risk management measures and may need authorization for certain uses under chemical safety legislation.

Where to buy dichloronickel in Europe?

Dichloronickel is available through OYSI, a European distributor of technical chemicals specializing in hazardous substances. As a professional chemical supplier, OYSI provides proper documentation, safety data sheets, and regulatory compliance support for dichloronickel purchases. Due to the substance's high hazard classification, sales are restricted to qualified industrial and research customers with appropriate handling capabilities.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.