4,5,6,7-tetrachloro-2-benzofuran-1,3-dione

C8Cl4O3

CAS117-08-8
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
117-08-8
EC Number
204-171-4
UN Number
3077
Index Number
607-242-00-1
PubChem CID
8326

Physical-chemical properties

Molecular Formula
C8Cl4O3
Molar Mass
285.90 g/mol
IUPAC Name
4,5,6,7-tetrachloro-2-benzofuran-1,3-dione

Chemical Identifiers

InChI
InChI=1S/C8Cl4O3/c9-3-1-2(8(14)15-7(1)13)4(10)6(12)5(3)11
InChI Key
AUHHYELHRWCWEZ-UHFFFAOYSA-N

Overview

4,5,6,7-tetrachloro-2-benzofuran-1,3-dione (CAS 117-08-8) is a chlorinated aromatic compound with strong oxidizing properties and high chemical stability. This tetrachlorinated benzofuran derivative, also known by its EC number 204-171-4, represents a specialized chemical intermediate widely utilized in industrial synthesis applications. With a molecular formula of C8Cl4O3 and molecular weight of 285.9 g/mol, this compound exhibits the characteristic properties of halogenated aromatic systems, including enhanced thermal stability and resistance to degradation. The compound's safety profile requires careful handling protocols due to its classification as Eye Dam. 1, Resp. Sens. 1, and Skin Sens. 1 under GHS regulations. The presence of GHS05, GHS08, and GHS09 pictogrammes indicates serious eye damage potential, respiratory sensitization risks, and environmental hazards. Its Aquatic Acute 1 and Aquatic Chronic 1 classifications reflect significant aquatic toxicity, necessitating stringent containment measures during storage and handling. Primary industrial applications include use as a chemical intermediate in pharmaceutical synthesis, where its stable aromatic framework serves as a building block for complex drug molecules. The compound also finds application in specialty polymer production and as a reagent in organic synthesis processes. Unlike simpler aromatic compounds such as benzene-1,4-diol, this tetrachlorinated derivative offers enhanced selectivity in specific chemical transformations. The substance falls under ADR Class 9 for transportation, requiring appropriate hazardous materials handling procedures. Its classification alongside other specialized chemicals demonstrates the compound's role in advanced chemical manufacturing processes requiring precise molecular structures. OYSI maintains reliable supply chains for 4,5,6,7-tetrachloro-2-benzofuran-1,3-dione to support European industrial customers' specialized chemical requirements.

Safety & Classification

Danger
Classification:

Eye Dam. 1; Resp. Sens. 1; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H318

Causes serious eye damage.

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameTetrachlorphthalsäureanhydrid
Marine PollutantNo

Frequently Asked Questions

What is 4,5,6,7-tetrachloro-2-benzofuran-1,3-dione?

4,5,6,7-tetrachloro-2-benzofuran-1,3-dione is a chlorinated organic compound with the molecular formula C8Cl4O3 and CAS number 117-08-8. This chemical belongs to the benzofuran family and contains four chlorine atoms attached to the aromatic ring structure. With a molecular weight of 285.9 g/mol, it is classified as a hazardous substance requiring careful handling due to its potential health and environmental risks.

What are the physicochemical properties of 4,5,6,7-tetrachloro-2-benzofuran-1,3-dione?

4,5,6,7-tetrachloro-2-benzofuran-1,3-dione is typically a solid crystalline compound at room temperature with a molecular weight of 285.9 g/mol. The presence of four chlorine atoms and the benzofuran structure influence its physical properties, including its stability and reactivity. Due to its highly chlorinated nature, it generally exhibits low water solubility but may dissolve in organic solvents. The compound's specific physical characteristics should be verified through technical data sheets.

What is 4,5,6,7-tetrachloro-2-benzofuran-1,3-dione used for?

4,5,6,7-tetrachloro-2-benzofuran-1,3-dione is primarily used as an intermediate in organic synthesis and chemical manufacturing processes. Its chlorinated benzofuran structure makes it valuable for producing specialized chemicals, pharmaceuticals, and industrial compounds. The substance may also serve as a building block for developing pesticides, dyes, or other complex organic molecules. Its applications are typically limited to professional and industrial settings due to its hazardous classification.

How to handle 4,5,6,7-tetrachloro-2-benzofuran-1,3-dione safely?

4,5,6,7-tetrachloro-2-benzofuran-1,3-dione requires strict safety measures due to its classification as Eye Dam. 1, Resp. Sens. 1, and Skin Sens. 1. Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection. Work in well-ventilated areas or under fume hoods to prevent inhalation. Avoid direct skin and eye contact, and ensure emergency eyewash stations are readily available. Follow all workplace safety protocols and consult the safety data sheet before handling.

How to store 4,5,6,7-tetrachloro-2-benzofuran-1,3-dione correctly?

4,5,6,7-tetrachloro-2-benzofuran-1,3-dione should be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers tightly sealed in their original packaging and store in a designated chemical storage area with appropriate secondary containment. Due to its environmental hazard classification (Aquatic Acute 1, Aquatic Chronic 1), prevent any potential release to the environment. Separate from incompatible materials and ensure storage areas are equipped with appropriate spill control measures.

What to do in case of contact with 4,5,6,7-tetrachloro-2-benzofuran-1,3-dione?

In case of eye contact with 4,5,6,7-tetrachloro-2-benzofuran-1,3-dione, immediately flush with plenty of water for at least 15 minutes and seek immediate medical attention due to its Eye Dam. 1 classification. For skin contact, remove contaminated clothing and wash thoroughly with soap and water. If inhaled, move to fresh air immediately and seek medical attention if respiratory symptoms develop. For ingestion, do not induce vomiting and seek immediate medical care. Always consult the safety data sheet for detailed first aid measures.

How to dispose of 4,5,6,7-tetrachloro-2-benzofuran-1,3-dione appropriately?

4,5,6,7-tetrachloro-2-benzofuran-1,3-dione must be disposed of as hazardous waste through licensed waste management companies in accordance with local, national, and EU regulations. Due to its environmental hazard classification (Aquatic Acute 1, Aquatic Chronic 1), prevent any release to water systems or soil. Do not dispose of via regular waste streams or pour down drains. Contact certified hazardous waste disposal services and provide them with the safety data sheet and waste classification information for proper treatment.

How to transport 4,5,6,7-tetrachloro-2-benzofuran-1,3-dione?

4,5,6,7-tetrachloro-2-benzofuran-1,3-dione is classified as ADR Class 9 (Miscellaneous dangerous substances), Packing Group III for transportation. This classification requires appropriate packaging, labeling, and documentation according to ADR regulations. Transport vehicles must display the correct placards and carry emergency response information. Only authorized carriers with proper training and equipment should handle the transportation. Ensure packages are properly secured and protected from damage during transit to prevent any releases.

Is 4,5,6,7-tetrachloro-2-benzofuran-1,3-dione subject to specific regulations?

4,5,6,7-tetrachloro-2-benzofuran-1,3-dione is subject to REACH registration requirements and CLP classification regulations within the EU. While it is not currently listed as a Substance of Very High Concern (SVHC), its hazard classification requires compliance with workplace safety regulations, environmental protection laws, and transport regulations (ADR Class 9). Users must ensure proper risk assessments, safety data sheet availability, and adherence to occupational exposure limits where established. Regular regulatory updates should be monitored.

Where to buy 4,5,6,7-tetrachloro-2-benzofuran-1,3-dione in Europe?

4,5,6,7-tetrachloro-2-benzofuran-1,3-dione is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this substance to qualified industrial and research customers with proper handling capabilities and regulatory compliance. Due to its hazardous classification, purchases typically require verification of proper storage, handling facilities, and intended use. Contact OYSI directly for availability, technical specifications, and regulatory documentation including safety data sheets and certificates of analysis.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.