Naphthalen-1-ol

C10H8O

naphthalen-1-ol

CAS90-15-3
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
90-15-3
EC Number
201-969-4
UN Number
2811
Index Number
604-029-00-5
PubChem CID
7005

Physical-chemical properties

Molecular Formula
C10H8O
Molar Mass
144.17 g/mol
IUPAC Name
naphthalen-1-ol

Chemical Identifiers

InChI
InChI=1S/C10H8O/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7,11H
InChI Key
KJCVRFUGPWSIIH-UHFFFAOYSA-N

Overview

Naphthalen-1-ol (CAS 90-15-3) is an aromatic alcohol derivative featuring a hydroxyl group attached to the naphthalene ring system, exhibiting both phenolic and aromatic properties. This organic compound, also known by its IUPAC name naphthalen-1-ol, represents an important class of substituted naphthalene derivatives widely utilized in industrial chemistry. With the molecular formula C10H8O and a molar mass of 144.17 g/mol, this crystalline substance combines the structural characteristics of naphthalene with the reactive properties of a phenolic hydroxyl group. The compound is classified under EC number 201-969-4 and requires careful handling due to its significant safety profile. From a safety perspective, naphthalen-1-ol is classified as Acute Tox. 4 with multiple exposure routes, STOT SE 3, Skin Irrit. 2, and Eye Dam. 1, necessitating the "Danger" signal word and GHS07 and GHS05 pictograms. The substance falls under ADR transport class 6.1, reflecting its toxic properties. Proper personal protective equipment and ventilation systems are essential when handling this material, particularly given its potential for skin irritation and serious eye damage. In industrial applications, naphthalen-1-ol serves as a key intermediate in the synthesis of dyes, pharmaceuticals, and specialty chemicals. It is particularly valuable in the production of azo dyes and serves as a coupling component in various organic syntheses. The compound also finds use in the manufacture of antioxidants and rubber chemicals, where its phenolic structure provides desirable chemical reactivity. Unlike simpler compounds such as 2-hexoxyethanol, naphthalen-1-ol offers unique aromatic functionality that makes it indispensable for specific synthetic pathways. OYSI provides high-quality naphthalen-1-ol to European industrial customers, ensuring reliable supply chains for demanding chemical manufacturing processes.

Safety & Classification

Danger
Classification:

Acute Tox. 4 *; Acute Tox. 4 *; STOT SE 3; Skin Irrit. 2; Eye Dam. 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H312

Harmful in contact with skin.

H302

Harmful if swallowed.

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H318

Causes serious eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2811
ADR Class6.1
Packing GroupIII
Tunnel CodeE
Proper Shipping Name1-Naphthol
Marine PollutantNo

Frequently Asked Questions

What is naphthalen-1-ol?

Naphthalen-1-ol is an organic chemical compound with the molecular formula C10H8O and CAS number 90-15-3. It belongs to the naphthol family, featuring a naphthalene ring system with a hydroxyl group attached at the first position. With a molecular weight of 144.17 g/mol, this aromatic compound serves as an important intermediate in chemical synthesis and industrial applications.

What are the physicochemical properties of naphthalen-1-ol?

Naphthalen-1-ol is a crystalline solid at room temperature, typically appearing as white to pale yellow crystals or powder. It exhibits limited water solubility but dissolves readily in organic solvents such as ethanol, acetone, and benzene. The compound has a characteristic phenolic odor and is sensitive to light and air, which can cause discoloration over time.

What is naphthalen-1-ol used for?

Naphthalen-1-ol is primarily used as an intermediate in the production of dyes, pigments, and pharmaceutical compounds. It serves in the synthesis of azo dyes, antioxidants, and rubber chemicals. The compound is also utilized in the manufacture of perfumes, insecticides, and as a coupling agent in various chemical reactions within the fine chemicals industry.

How to handle naphthalen-1-ol safely?

Naphthalen-1-ol requires careful handling due to its classification as Acute Tox. 4, Skin Irrit. 2, and Eye Dam. 1. Essential protective equipment includes chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or under fume hoods to prevent inhalation. Avoid skin and eye contact, and ensure proper hygiene practices including thorough handwashing after handling.

How to store naphthalen-1-ol correctly?

Naphthalen-1-ol should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from direct sunlight and heat sources. Keep containers away from incompatible materials such as strong oxidizing agents and bases. Store below 25°C and protect from moisture to prevent degradation. Ensure proper labeling and implement appropriate inventory management practices.

What to do in case of contact with naphthalen-1-ol?

In case of skin contact, immediately remove contaminated clothing and wash affected area thoroughly with soap and water for at least 15 minutes. For eye contact, rinse immediately with plenty of clean water for at least 15 minutes and seek medical attention due to its Eye Dam. 1 classification. If inhaled, move to fresh air. Seek immediate medical attention for any exposure and provide safety data sheet to medical personnel.

How to dispose of naphthalen-1-ol appropriately?

Naphthalen-1-ol must be disposed of as hazardous waste according to local and national regulations. Contact licensed waste disposal companies for proper treatment and disposal. Do not discharge into sewers, water bodies, or soil. Small quantities may require incineration at authorized facilities with appropriate emission controls. Always consult local environmental authorities for specific disposal requirements.

How to transport naphthalen-1-ol?

Naphthalen-1-ol is classified under ADR Class 6.1 (toxic substances), Packing Group III. Transportation requires appropriate UN-specification packaging and proper labeling with GHS05 and GHS07 pictograms. Packages must display the 'Danger' signal word and relevant hazard statements. Ensure compliance with transport documentation requirements and driver training for hazardous materials transport.

Is naphthalen-1-ol subject to specific regulations?

Naphthalen-1-ol is regulated under the CLP Regulation with classifications including Acute Tox. 4, Skin Irrit. 2, Eye Dam. 1, and STOT SE 3. It requires safety data sheets and appropriate labeling. While not currently listed as an SVHC under REACH, standard registration requirements apply for manufacturers and importers above one tonne annually.

Where to buy naphthalen-1-ol in Europe?

Naphthalen-1-ol is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides reliable supply chains across Europe with proper documentation including certificates of analysis and safety data sheets. As an established chemical distributor, OYSI ensures compliance with European regulations and offers technical support for industrial applications requiring naphthalen-1-ol.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.