Methyl N-(methylcarbamoyloxy)ethanimidothioate

C5H10N2O2S

methyl N-(methylcarbamoyloxy)ethanimidothioate

CAS16752-77-5
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
16752-77-5
EC Number
240-815-0
UN Number
2757
Index Number
006-045-00-2
PubChem CID
4109

Physical-chemical properties

Molecular Formula
C5H10N2O2S
Molar Mass
162.21 g/mol
IUPAC Name
methyl N-(methylcarbamoyloxy)ethanimidothioate

Chemical Identifiers

InChI
InChI=1S/C5H10N2O2S/c1-4(10-3)7-9-5(8)6-2/h1-3H3,(H,6,8)
InChI Key
UHXUZOCRWCRNSJ-UHFFFAOYSA-N

Overview

Methyl N-(methylcarbamoyloxy)ethanimidothioate (CAS 16752-77-5) is an organosulfur compound with carbamate functionality used in specialized chemical applications. This chemical compound, also identified by EC number 240-815-0, belongs to the thiocarbamate family with a molecular formula of C5H10N2O2S and a molecular weight of 162.21 g/mol. The substance exhibits significant toxicological properties, classified under Acute Toxicity Category 2, requiring careful handling protocols in industrial environments. Its environmental impact profile includes both acute and chronic aquatic toxicity classifications, necessitating appropriate containment and disposal measures. The compound's hazard classification under GHS includes pictograms GHS06 (skull and crossbones) and GHS09 (environmental hazard), with "Danger" as the signal word. Transportation regulations classify it under ADR Class 6.1, indicating its toxic nature during shipping and storage operations. These safety characteristics place it in a similar risk category to other highly regulated substances such as sodium azide, though each compound requires specific handling protocols. In industrial applications, methyl N-(methylcarbamoyloxy)ethanimidothioate serves primarily in specialized synthesis processes where its unique carbamate-thioester structure provides specific reactivity patterns. The compound finds use in pharmaceutical intermediate production and advanced materials chemistry. Additionally, it functions as a specialized reagent in organic synthesis applications requiring selective nitrogen-sulfur bond formation. Due to its high toxicity profile and environmental concerns, proper personal protective equipment, adequate ventilation systems, and specialized waste management protocols are essential when working with this substance. OYSI maintains availability of this technical chemical for qualified industrial customers with appropriate handling capabilities and regulatory compliance.

Safety & Classification

Danger
Classification:

Acute Tox. 2 *; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H300

Fatal if swallowed.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Ingestion

Fatal

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2757
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameMethomyl (ISO)
Marine PollutantNo

Frequently Asked Questions

What is methyl N-(methylcarbamoyloxy)ethanimidothioate?

Methyl N-(methylcarbamoyloxy)ethanimidothioate is an organosulfur compound with the molecular formula C5H10N2O2S and CAS number 16752-77-5. This chemical substance has a molecular weight of 162.21 g/mol and belongs to the carbamate family. It is classified as highly toxic (Acute Tox. 2) and poses significant environmental hazards to aquatic life, requiring careful handling and specialized safety measures during industrial applications.

What are the physicochemical properties of methyl N-(methylcarbamoyloxy)ethanimidothioate?

Methyl N-(methylcarbamoyloxy)ethanimidothioate is a chemical compound with a molecular weight of 162.21 g/mol and the molecular formula C5H10N2O2S. As an organosulfur carbamate derivative, it typically exists as a solid or liquid at room temperature depending on purity and formulation. The compound contains both sulfur and nitrogen functional groups, which influence its reactivity and solubility characteristics in various solvents.

What is methyl N-(methylcarbamoyloxy)ethanimidothioate used for?

Methyl N-(methylcarbamoyloxy)ethanimidothioate is primarily used as an active ingredient in pesticide formulations, particularly as an insecticide and nematicide. Its carbamate structure allows it to inhibit acetylcholinesterase enzymes in target organisms. The compound is utilized in agricultural applications for crop protection and pest control. Due to its high toxicity classification, its use is restricted to professional applications with appropriate safety measures and regulatory compliance.

How to handle methyl N-(methylcarbamoyloxy)ethanimidothioate safely?

Methyl N-(methylcarbamoyloxy)ethanimidothioate requires extreme caution during handling due to its Acute Tox. 2 classification. Essential personal protective equipment includes chemical-resistant gloves, protective clothing, eye protection, and respiratory protection. Work must be conducted in well-ventilated areas or under fume extraction systems. Avoid skin contact, inhalation, and ingestion. Only trained personnel should handle this substance, following strict safety protocols and emergency procedures.

How to store methyl N-(methylcarbamoyloxy)ethanimidothioate correctly?

Methyl N-(methylcarbamoyloxy)ethanimidothioate must be stored in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Storage areas should be secure and accessible only to authorized personnel due to its high toxicity. The container should be kept tightly closed and labeled according to GHS requirements with appropriate hazard symbols (GHS06, GHS09). Store separately from food, feed, and drinking water to prevent contamination.

What to do in case of contact with methyl N-(methylcarbamoyloxy)ethanimidothioate?

Immediate medical attention is required for any contact with methyl N-(methylcarbamoyloxy)ethanimidothioate due to its high acute toxicity. For skin contact, remove contaminated clothing and rinse affected area with plenty of water. If inhaled, move to fresh air immediately. In case of eye contact, flush with water for at least 15 minutes. For ingestion, do not induce vomiting and seek emergency medical care. Always consult poison control centers and provide safety data sheet information to medical personnel.

How to dispose of methyl N-(methylcarbamoyloxy)ethanimidothioate appropriately?

Methyl N-(methylcarbamoyloxy)ethanimidothioate must be disposed of as hazardous waste according to local and national regulations. The substance cannot be disposed of in regular waste streams due to its toxicity and environmental hazard classification. Contact licensed hazardous waste disposal companies for proper collection and treatment. Empty containers should also be treated as hazardous waste. Follow all applicable environmental regulations including REACH and national waste management laws for compliant disposal.

How to transport methyl N-(methylcarbamoyloxy)ethanimidothioate?

Methyl N-(methylcarbamoyloxy)ethanimidothioate is classified under ADR Class 6.1 (Toxic substances), Packing Group II, indicating high toxicity requiring specialized transport conditions. Transportation must comply with dangerous goods regulations, using appropriate packaging, labeling, and documentation. Only certified carriers experienced in hazardous materials transport should handle shipments. Proper emergency response information and safety data sheets must accompany all shipments to ensure safe handling during transport.

Is methyl N-(methylcarbamoyloxy)ethanimidothioate subject to specific regulations?

Methyl N-(methylcarbamoyloxy)ethanimidothioate is subject to multiple regulatory frameworks including REACH registration requirements in Europe and CLP classification as Acute Tox. 2. While not currently listed as a Substance of Very High Concern (SVHC), its high toxicity and environmental hazard classification require compliance with strict handling, storage, and disposal regulations. Users must follow pesticide regulations if used for plant protection purposes and maintain appropriate safety documentation.

Where to buy methyl N-(methylcarbamoyloxy)ethanimidothioate in Europe?

Methyl N-(methylcarbamoyloxy)ethanimidothioate is available through OYSI, a specialized European distributor of technical chemicals. As a highly regulated substance requiring professional handling, OYSI ensures compliance with all European regulations including REACH and transport requirements. Purchase requires proper business credentials and demonstration of appropriate safety measures. OYSI provides technical support and regulatory documentation to ensure safe and compliant use of this hazardous chemical substance.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.