Lithium;silicon

LiSi

lithium;silicon

CAS68848-64-6

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Identification

CAS Number
68848-64-6
UN Number
1417
PubChem CID
53470676

Physical-chemical properties

Molecular Formula
LiSi
Molar Mass
35.10 g/mol
IUPAC Name
lithium;silicon

Chemical Identifiers

InChI
InChI=1S/Li.Si
InChI Key
ZVLDJSZFKQJMKD-UHFFFAOYSA-N

Overview

Lithium silicon (CAS 68848-64-6) is an intermetallic compound combining lithium and silicon elements with unique electrochemical and structural properties. This binary compound represents an important class of materials in advanced technology applications, particularly in energy storage and semiconductor industries. Lithium silicon compounds exhibit distinctive characteristics due to the combination of lithium's high electrochemical activity and silicon's semiconductor properties. The molecular formula LiSi indicates a 1:1 stoichiometric ratio between lithium and silicon atoms, resulting in a relatively low molecular weight of 35.1 g/mol. The compound's classification under ADR class 4.3 indicates it falls under substances that emit flammable gases when in contact with water, requiring careful handling and storage protocols. This reactivity stems primarily from the lithium component, which readily reacts with moisture and oxygen in ambient conditions. Proper storage requires inert atmosphere conditions and moisture-free environments to maintain material integrity and prevent unwanted reactions. Lithium silicon finds significant applications in advanced battery technologies, particularly as anode materials in lithium-ion batteries where it offers superior capacity compared to conventional graphite anodes. The compound is also utilized in specialized metallurgical processes and as a precursor material in semiconductor manufacturing. Similar to other reactive metal compounds like mercury sodium and potassium sodium, lithium silicon requires specialized handling procedures due to its chemical reactivity. The unique combination of properties makes this material valuable for research and development in energy storage solutions and advanced materials applications. OYSI provides lithium silicon as part of our comprehensive portfolio of specialized chemical compounds for European industrial clients.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number1417
ADR Class4.3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameLithiumsilicium
Marine PollutantNo

Frequently Asked Questions

What is lithium silicon?

Lithium silicon is an intermetallic compound with the chemical formula LiSi and molecular weight of 35.1 g/mol. This binary compound combines lithium and silicon atoms in a 1:1 ratio, forming a unique material with distinctive properties. It belongs to the class of alkali metal silicides and exhibits characteristics typical of intermetallic compounds. The CAS number 68848-64-6 specifically identifies this compound in chemical databases and regulatory frameworks worldwide.

What are the physicochemical properties of lithium silicon?

Lithium silicon is a solid intermetallic compound at room temperature with a molecular formula of LiSi and molecular weight of 35.1 g/mol. As an intermetallic compound, it typically appears as a crystalline solid with metallic luster. The compound exhibits properties intermediate between its constituent elements, combining lithium's reactivity with silicon's structural characteristics. Its exact physical appearance, solubility, and thermal properties depend on the specific crystal structure and preparation method.

What is lithium silicon used for?

Lithium silicon serves primarily in specialized industrial applications where its unique intermetallic properties are advantageous. Common uses include advanced materials research, potential applications in battery technology development, and as a precursor for specialized silicon-lithium compounds. It may also find applications in metallurgy and materials science research. The compound's specific properties make it valuable for developing new materials with tailored electrical, mechanical, or thermal characteristics in specialized industrial processes.

How to handle lithium silicon safely?

Lithium silicon requires careful handling due to its classification under ADR Class 4.3 (substances which, in contact with water, emit flammable gases). Use appropriate personal protective equipment including safety glasses, chemical-resistant gloves, and protective clothing. Work in well-ventilated areas and avoid contact with moisture or water. Keep away from heat sources, sparks, and open flames. Handle in dry conditions and use proper grounding procedures to prevent static electricity buildup during transfer operations.

How to store lithium silicon correctly?

Lithium silicon must be stored in dry, cool conditions away from moisture and water sources due to its ADR 4.3 classification. Use airtight, moisture-proof containers in a well-ventilated storage area. Keep away from heat sources, ignition sources, and incompatible materials such as oxidizing agents and acids. Store in original containers with proper labeling and maintain inventory records. Ensure storage areas have appropriate fire suppression systems and emergency response equipment readily available.

What to do in case of contact with lithium silicon?

Lithium silicon exposure requires immediate response depending on the contact type. For skin contact, remove contaminated clothing and wash affected area thoroughly with water. In case of eye contact, flush immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move person to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult safety data sheets for specific first aid measures and contact emergency services when necessary.

How to dispose of lithium silicon appropriately?

Lithium silicon disposal must comply with local and European waste regulations for hazardous materials. The compound cannot be disposed of as regular waste due to its reactive nature and ADR 4.3 classification. Contact licensed hazardous waste disposal companies for proper collection and treatment. Small quantities should be neutralized following approved procedures before disposal. Maintain disposal records and ensure compliance with WEEE, RoHS, and local environmental regulations. Never dispose of in sewers, soil, or regular waste streams.

How to transport lithium silicon?

Lithium silicon transport follows ADR Class 4.3 regulations as substances that emit flammable gases when in contact with water, classified as Packing Group II. Proper UN specification packaging is required, along with appropriate hazard labels and transport documentation. Vehicles must carry appropriate emergency equipment and drivers need ADR certification. Shipments require proper segregation from incompatible materials and must follow prescribed transport routes with emergency response information readily available throughout transit.

Is lithium silicon subject to particular regulations?

Lithium silicon is subject to various European chemical regulations including REACH registration requirements, though it is not classified as a Substance of Very High Concern (SVHC). Transport regulations under ADR apply due to its Class 4.3 classification. Standard CLP labeling and safety data sheet requirements apply for commercial handling. Industrial users must comply with occupational safety regulations and environmental protection measures. Import/export may require additional documentation depending on quantities and end-use applications.

Where to buy lithium silicon in Europe?

Lithium silicon is available through OYSI, a specialized European distributor of technical chemicals and advanced materials. OYSI provides this compound to industrial customers, research institutions, and specialized manufacturers across Europe. As a professional chemical distributor, OYSI ensures proper handling, documentation, and compliance with European regulations including REACH and ADR transport requirements. Contact OYSI directly for availability, technical specifications, and delivery options tailored to your specific application requirements and location within Europe.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.