Lithium;silicon

LiSi

lithium;silicon

CAS68848-64-6

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Identification

CAS Number
68848-64-6
UN Number
1417
PubChem CID
53470676

Physical-chemical properties

Molecular Formula
LiSi
Molar Mass
35.10 g/mol
IUPAC Name
lithium;silicon

Chemical Identifiers

InChI
InChI=1S/Li.Si
InChI Key
ZVLDJSZFKQJMKD-UHFFFAOYSA-N

Overview

Lithium silicon (CAS 68848-64-6) is an intermetallic compound combining lithium and silicon atoms with notable electrochemical and thermal properties. This binary intermetallic compound represents an important class of materials where alkali metals form stable phases with metalloid elements. Lithium silicon exhibits unique characteristics that stem from the combination of lithium's highly reactive metallic nature with silicon's semiconducting properties. The compound forms through direct reaction between the constituent elements under controlled atmospheric conditions, typically requiring inert gas environments due to lithium's extreme reactivity with moisture and oxygen. The material displays interesting electrochemical behavior, particularly in energy storage applications where the lithium-silicon interaction plays a crucial role in battery performance. Unlike simpler alkali metal compounds such as potassium sodium alloys, lithium silicon forms distinct crystalline phases with specific stoichiometric ratios. The compound's properties differ significantly from other intermetallic systems like mercury sodium, demonstrating the unique nature of lithium-silicon bonding. From a safety perspective, lithium silicon requires careful handling protocols due to its classification under ADR Class 4.3, indicating its potential to release flammable gases when in contact with water. Proper storage in moisture-free environments and appropriate personal protective equipment are essential for safe handling. Industrial applications include advanced battery electrode materials, specialized alloys for electronics manufacturing, and research applications in materials science. The compound serves as a precursor for developing high-performance lithium-ion battery anodes and specialized semiconductor applications. OYSI maintains strategic inventory of lithium silicon to support European industrial customers requiring reliable access to this specialized intermetallic compound for their technical applications.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number1417
ADR Class4.3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameLithiumsilicium
Marine PollutantNo

Frequently Asked Questions

What is lithium silicon?

Lithium silicon is an intermetallic compound with the chemical formula LiSi and molecular weight of 35.1 g/mol. This binary alloy combines lithium and silicon atoms in a specific stoichiometric ratio, forming a distinct crystalline structure. It belongs to a class of materials known for their unique electrochemical and physical properties, making them valuable in specialized industrial applications requiring the combined characteristics of both lithium and silicon elements.

What are the physicochemical properties of lithium silicon?

Lithium silicon is a solid intermetallic compound at room temperature with distinctive metallic characteristics. As an alloy of lithium and silicon, it typically exhibits a grayish metallic appearance and is odorless. The compound shows limited stability in air due to lithium's reactivity and has poor solubility in water. Its density and melting point fall between those of pure lithium and silicon, with the exact properties depending on the specific crystal structure and preparation method.

What is lithium silicon used for?

Lithium silicon is primarily used in advanced battery technology, particularly as an anode material in high-performance lithium-ion batteries. The compound offers superior energy storage capacity compared to conventional graphite anodes, making it valuable for electric vehicle batteries and portable electronics. Additionally, it finds applications in specialized metallurgy, semiconductor research, and as a precursor for other lithium-silicon compounds used in materials science and electrochemical research applications.

How to handle lithium silicon safely?

Lithium silicon requires careful handling due to its reactive nature, particularly with moisture and air. Always wear appropriate personal protective equipment including safety goggles, chemical-resistant gloves, and protective clothing. Work in well-ventilated areas or under inert atmosphere when possible to prevent oxidation. Avoid contact with water or humid conditions as this can cause vigorous reactions. Use non-sparking tools and ensure proper grounding to prevent static electricity buildup during handling operations.

How to store lithium silicon correctly?

Lithium silicon must be stored in a cool, dry environment away from moisture, air, and incompatible materials. Use airtight containers with inert gas atmosphere (argon or nitrogen) to prevent oxidation and degradation. Keep away from water, alcohols, acids, and strong oxidizing agents. Storage areas should be well-ventilated, temperature-controlled, and equipped with appropriate fire suppression systems. Regular inspection of containers for signs of corrosion or deterioration is essential for maintaining product quality.

What to do in case of contact with lithium silicon?

Lithium silicon exposure requires immediate action depending on the contact type. For skin contact, remove contaminated clothing and rinse affected area thoroughly with water for at least 15 minutes, then seek medical attention. If inhaled, move to fresh air immediately and monitor breathing. For eye contact, flush with clean water for 15 minutes and seek immediate medical care. In case of ingestion, do not induce vomiting and seek emergency medical attention immediately while providing material safety information to healthcare providers.

How to dispose of lithium silicon appropriately?

Lithium silicon disposal must comply with local and international hazardous waste regulations due to its reactive metallic nature. The material should never be disposed of in regular waste streams or sewage systems. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities may be neutralized under controlled conditions by trained personnel, but large amounts require specialized handling. Always consult local environmental authorities for specific disposal requirements and maintain proper documentation of waste disposal activities.

How to transport lithium silicon?

Lithium silicon is classified under ADR Class 4.3 (Substances which, in contact with water, emit flammable gases), Packing Group II. Transportation requires UN-approved packaging designed for dangerous goods, with proper labeling and documentation including dangerous goods declarations. Vehicles must be equipped with appropriate safety equipment and drivers need ADR certification. The material should be protected from moisture during transport and emergency response information must be readily available throughout the shipping process.

Is lithium silicon subject to specific regulations?

Lithium silicon is subject to various chemical regulations including REACH registration requirements in Europe, though it is not classified as a Substance of Very High Concern (SVHC). The compound must comply with CLP regulation for classification, labeling, and packaging. Due to its ADR classification as dangerous goods, it falls under transportation regulations for hazardous materials. Users must ensure compliance with local occupational health and safety standards and may need to fulfill notification requirements depending on usage quantities and applications.

Where to buy lithium silicon in Europe?

Lithium silicon is available through specialized chemical distributors across Europe, with OYSI serving as a reliable European supplier for this technical compound. As a professional distributor of chemical products, OYSI can provide lithium silicon with proper documentation, safety data sheets, and regulatory compliance support. When sourcing this material, ensure your supplier meets quality standards and can provide certificates of analysis, proper packaging for dangerous goods, and technical support for safe handling and application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.