Heptane

C7H16

heptane

CAS142-82-5

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Identification

CAS Number
142-82-5
EC Number
205-563-8
UN Number
1206
Index Number
601-008-00-2
PubChem CID
8900

Physical-chemical properties

Molecular Formula
C7H16
Molar Mass
100.20 g/mol
IUPAC Name
heptane

Chemical Identifiers

InChI
InChI=1S/C7H16/c1-3-5-7-6-4-2/h3-7H2,1-2H3
InChI Key
IMNFDUFMRHMDMM-UHFFFAOYSA-N

Overview

Heptane (CAS 142-82-5) is a linear alkane hydrocarbon with seven carbon atoms, characterized by its low boiling point and excellent solvent properties. This saturated hydrocarbon belongs to the normal paraffin family and serves as an important industrial solvent and chemical intermediate. With its molecular formula C7H16 and molecular weight of 100.2 g/mol, heptane exhibits typical alkane characteristics including chemical stability, low polarity, and good miscibility with other organic compounds. The compound appears as a colorless liquid with a characteristic petroleum-like odor and demonstrates excellent volatility at ambient temperatures. As a flammable liquid classified under ADR Class 3 for transportation purposes, heptane requires standard hydrocarbon handling precautions including proper ventilation, ignition source control, and appropriate storage conditions. Its relatively low flash point necessitates careful consideration of static electricity buildup during transfer operations. The substance shows minimal toxicity concerns under normal industrial handling conditions, though prolonged exposure should be avoided through standard protective equipment usage. Heptane finds primary application as a reference fuel component in octane rating determinations, where it defines the zero point of the octane scale. The chemical industry utilizes heptane as an extraction solvent for oils and fats, as well as a reaction medium for various synthetic processes. Additionally, it serves as a specialty cleaning solvent in electronics manufacturing and precision cleaning applications. Related compounds such as 2-ethylbutyl acetate share similar solvent characteristics but offer different volatility profiles for specific applications. Laboratory and pharmaceutical sectors employ heptane for chromatographic separations and as a crystallization medium. OYSI supplies high-quality heptane to meet diverse industrial requirements across European markets.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number1206
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameHeptan
Marine PollutantNo

Frequently Asked Questions

What is heptane?

Heptane is a straight-chain alkane hydrocarbon with the molecular formula C7H16 and CAS number 142-82-5. It belongs to the family of saturated hydrocarbons and has a molecular weight of 100.2 g/mol. This colorless liquid is commonly used as a non-polar solvent and reference standard in various industrial applications due to its chemical stability and well-defined properties.

What are the physicochemical properties of heptane?

Heptane is a colorless, volatile liquid with a characteristic petroleum-like odor at room temperature. It has a boiling point of approximately 98°C and a melting point of -91°C. The substance is highly non-polar and insoluble in water but miscible with most organic solvents. It has a density of about 0.68 g/cm³ and exhibits low viscosity, making it an excellent solvent for non-polar compounds.

What is heptane used for?

Heptane serves multiple industrial purposes, primarily as a non-polar solvent in chemical processes and analytical applications. It is widely used in chromatography as a mobile phase, in paint and coating formulations, and as a cleaning agent for removing oils and greases. Additionally, heptane functions as a reference standard in octane rating determinations for gasoline and serves as an extraction solvent in pharmaceutical and chemical industries.

How to handle heptane safely?

Heptane requires careful handling due to its flammable nature and potential health effects. Always wear appropriate personal protective equipment including nitrile gloves, safety goggles, and protective clothing. Ensure adequate ventilation to prevent vapor accumulation and avoid ignition sources such as sparks, flames, or hot surfaces. Work in well-ventilated areas or under fume hoods, and have fire extinguishing equipment readily available.

How to store heptane correctly?

Heptane must be stored in a cool, dry, well-ventilated area away from heat sources, sparks, and flames. Use original containers or approved flammable liquid storage containers made of compatible materials. Keep containers tightly sealed and store below 25°C if possible. Ensure storage areas are equipped with appropriate fire suppression systems and avoid storing near oxidizing agents or incompatible chemicals.

What to do in case of contact with heptane?

Heptane exposure requires immediate action depending on the contact type. For skin contact, remove contaminated clothing and wash the affected area thoroughly with soap and water. In case of eye contact, flush immediately with clean water for at least 15 minutes. If inhaled, move the person to fresh air and seek medical attention if breathing difficulties occur. For ingestion, do not induce vomiting and seek immediate medical care.

How to dispose of heptane properly?

Heptane disposal must comply with local and national hazardous waste regulations. The substance cannot be disposed of in regular waste streams or poured down drains due to its flammable nature and environmental impact. Contact licensed hazardous waste disposal companies for proper collection and treatment. Small quantities may be suitable for solvent recovery programs, while contaminated materials require specialized handling according to waste classification codes.

How to transport heptane?

Heptane is classified under ADR Class 3 (flammable liquids), Packing Group II, requiring specific transport protocols. Shipments must use UN-approved packaging and proper hazard labels indicating flammable liquid classification. Transport vehicles need appropriate placarding and emergency equipment. Only certified carriers experienced in dangerous goods transport should handle heptane shipments, following all ADR regulations for European road transport.

Is heptane subject to specific regulations?

Heptane falls under various European chemical regulations including REACH registration requirements for manufacturers and importers. While not classified as a Substance of Very High Concern (SVHC), it must comply with CLP regulation for classification, labeling, and packaging. Industrial users must maintain safety data sheets and implement appropriate risk management measures. Transport is regulated under ADR as a Class 3 flammable liquid.

Where to buy heptane in Europe?

Heptane is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across the continent. OYSI provides high-quality heptane with proper documentation including safety data sheets and certificates of analysis. As an established chemical distributor, OYSI ensures compliance with European regulations and offers reliable supply chain solutions for various grade requirements and packaging options.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.