Heptane

C7H16

heptane

CAS142-82-5

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Identification

CAS Number
142-82-5
EC Number
205-563-8
UN Number
1206
Index Number
601-008-00-2
PubChem CID
8900

Physical-chemical properties

Molecular Formula
C7H16
Molar Mass
100.20 g/mol
IUPAC Name
heptane

Chemical Identifiers

InChI
InChI=1S/C7H16/c1-3-5-7-6-4-2/h3-7H2,1-2H3
InChI Key
IMNFDUFMRHMDMM-UHFFFAOYSA-N

Overview

Heptane (CAS 142-82-5) is a straight-chain saturated hydrocarbon with seven carbon atoms and excellent solvent properties. This aliphatic alkane represents one of the most important industrial solvents in the C7 hydrocarbon family, offering exceptional chemical stability and controlled volatility characteristics. With its molecular formula C7H16 and molar mass of 100.2 g/mol, heptane exhibits typical properties of medium-chain alkanes, making it particularly valuable in various technical applications requiring precise solvent performance. As a colorless, flammable liquid with a characteristic petroleum-like odor, heptane demonstrates low polarity and excellent miscibility with other hydrocarbons and organic compounds. The substance falls under ADR transport class 3, requiring appropriate handling procedures for flammable liquids. Its boiling point of approximately 98°C and relatively low surface tension make it an ideal candidate for applications demanding specific evaporation rates and surface interaction properties. Heptane finds extensive use in the pharmaceutical industry as an extraction solvent and reaction medium, particularly in processes requiring non-polar solvent systems. The rubber and adhesives industry utilizes heptane for polymer dissolution and processing applications, while the analytical chemistry sector employs it as a reference standard for octane rating determinations. Unlike more complex compounds such as 2,2,5-trimethylhex-4-enal, heptane's simple structure provides predictable behavior in industrial processes. Laboratory applications include chromatography mobile phases, where heptane's consistent properties ensure reproducible analytical results. The compound also serves as a cleaning agent in specialized industrial applications and as a component in various formulations requiring controlled volatility characteristics. OYSI supplies technical-grade heptane to meet diverse industrial requirements across European markets.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number1206
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameHeptan
Marine PollutantNo

Frequently Asked Questions

What is heptane?

Heptane is a straight-chain alkane hydrocarbon with the molecular formula C7H16 and CAS number 142-82-5. This colorless liquid belongs to the family of saturated hydrocarbons and has a molecular weight of 100.2 g/mol. Heptane is commonly found in petroleum and is widely used as a non-polar solvent in various industrial applications due to its excellent solvent properties for organic compounds.

What are the physicochemical properties of heptane?

Heptane is a colorless, volatile liquid with a characteristic gasoline-like odor at room temperature. It has a boiling point of approximately 98°C and a melting point of -91°C. The substance is highly hydrophobic, meaning it is virtually insoluble in water but readily miscible with other organic solvents such as alcohols, ethers, and other hydrocarbons. Its low polarity makes it an excellent non-polar solvent.

What is heptane used for?

Heptane is primarily used as a non-polar solvent in laboratory and industrial applications, particularly for extracting oils, fats, and other organic compounds. It serves as a reference standard in octane rating determinations for gasoline, where it represents zero octane rating. Additionally, heptane is utilized in chromatography, as a cleaning agent for removing adhesive residues, and in the production of rubber cement and other industrial formulations.

How to handle heptane safely?

Heptane should be handled with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or under fume hoods to prevent vapor accumulation, as heptane vapors can be harmful when inhaled. Avoid contact with skin and eyes, and eliminate all ignition sources including sparks, open flames, and hot surfaces, as heptane is highly flammable with a low flash point.

How to store heptane correctly?

Heptane must be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources, sparks, and open flames. Storage areas should be equipped with appropriate fire suppression systems and maintained at temperatures below 25°C when possible. Keep containers away from incompatible materials such as strong oxidizing agents, acids, and bases. Ensure proper grounding of containers during transfer operations to prevent static electricity buildup.

What to do in case of contact with heptane?

Heptane exposure requires immediate action depending on the type of contact. For skin contact, remove contaminated clothing and wash the affected area thoroughly with soap and water. In case of eye contact, flush immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move the person to fresh air immediately. If ingested, do not induce vomiting and seek immediate medical attention.

How to dispose of heptane appropriately?

Heptane must be disposed of as hazardous waste in accordance with local, national, and European waste regulations. Never dispose of heptane down drains, sewers, or into the environment. Contact licensed waste management companies for proper collection and disposal. Small quantities can often be recycled through solvent recovery processes. Always consult local authorities and follow waste classification codes for proper disposal documentation and procedures.

How to transport heptane?

Heptane is classified under ADR Class 3 (flammable liquids), Packing Group II, requiring specific packaging and labeling for transport. Containers must meet UN specification standards and display appropriate hazard labels including flammable liquid warnings. Transport vehicles must be equipped with appropriate safety equipment and drivers must hold valid ADR certification. Proper shipping documentation including transport documents and emergency response information must accompany all shipments.

Is heptane subject to particular regulations?

Heptane is regulated under European REACH legislation requiring registration for commercial use above certain tonnage thresholds. It falls under CLP regulation for classification, labeling, and packaging requirements. While not currently listed as a Substance of Very High Concern (SVHC), users must comply with workplace exposure limits and safety data sheet requirements. Industrial users should verify compliance with local environmental and occupational health regulations.

Where to buy heptane in Europe?

Heptane is available through OYSI, a European distributor of chemical products serving industrial and professional customers across Europe. OYSI provides high-quality heptane with proper documentation including certificates of analysis and safety data sheets. As a specialized chemical distributor, OYSI ensures compliance with European regulations and offers technical support for proper handling and application of heptane in various industrial processes.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.