Methyl 2-methylprop-2-enoate

C5H8O2

methyl 2-methylprop-2-enoate

CAS80-62-6
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

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Identification

CAS Number
80-62-6
EC Number
201-297-1
UN Number
1247
Index Number
607-035-00-6
PubChem CID
6658

Physical-chemical properties

Molecular Formula
C5H8O2
Molar Mass
100.12 g/mol
IUPAC Name
methyl 2-methylprop-2-enoate

Chemical Identifiers

InChI
InChI=1S/C5H8O2/c1-4(2)5(6)7-3/h1H2,2-3H3
InChI Key
VVQNEPGJFQJSBK-UHFFFAOYSA-N

Overview

Methyl 2-methylprop-2-enoate (CAS 80-62-6) is an acrylic ester monomer with high reactivity and polymerization capabilities. This versatile chemical compound, also known by its IUPAC designation methyl 2-methylprop-2-enoate, serves as a fundamental building block in polymer chemistry and industrial manufacturing. With the molecular formula C5H8O2 and a molecular weight of 100.12 g/mol, this acrylic ester exhibits characteristic properties that make it valuable across multiple industrial sectors. The compound belongs to the same family of reactive monomers as styrene, sharing similar polymerization characteristics and industrial applications. The substance presents specific safety considerations, classified under GHS pictograms GHS02 and GHS07 with a "Danger" signal word. Key hazard classifications include flammable liquid category 2, skin irritation category 2, skin sensitization category 1, and specific target organ toxicity (single exposure) category 3. These properties necessitate careful handling procedures and appropriate safety measures during storage, transportation, and processing. The ADR classification as class 3 material reflects its flammable nature, requiring specialized logistics considerations. Primary industrial applications include polymer synthesis, where it functions as a monomer for producing various acrylic polymers and copolymers. The compound finds extensive use in adhesives formulation, coating systems, and specialty chemical manufacturing. Its reactivity profile makes it particularly suitable for applications requiring controlled polymerization processes and specific material properties. OYSI maintains reliable supply chains for methyl 2-methylprop-2-enoate, ensuring consistent availability for European industrial customers requiring this essential acrylic monomer for their manufacturing processes.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; STOT SE 3; Skin Irrit. 2; Skin Sens. 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H317

May cause an allergic skin reaction.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1247
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameMethylmethacrylat, Monomer, stabilisiert
Marine PollutantNo

Frequently Asked Questions

What is methyl 2-methylprop-2-enoate?

Methyl 2-methylprop-2-enoate is an organic chemical compound with the molecular formula C5H8O2 and CAS number 80-62-6. Also known as methyl methacrylate (MMA), it is a methyl ester of methacrylic acid with a molecular weight of 100.12 g/mol. This colorless liquid is classified as a flammable substance and skin sensitizer, featuring vinyl functionality that makes it highly reactive for polymerization processes.

What are the physicochemical properties of methyl 2-methylprop-2-enoate?

Methyl 2-methylprop-2-enoate is a colorless, transparent liquid with a characteristic sharp, fruity odor at room temperature. It has a molecular weight of 100.12 g/mol and exhibits limited solubility in water but good miscibility with most organic solvents. The compound is highly volatile and flammable, with strong reactivity due to its methacrylate double bond, making it prone to spontaneous polymerization under certain conditions.

What is methyl 2-methylprop-2-enoate used for?

Methyl 2-methylprop-2-enoate is primarily used as a monomer in the production of polymethyl methacrylate (PMMA) plastics and acrylic resins. It serves as a key raw material in manufacturing transparent plastics, coatings, adhesives, and dental materials. The compound is also utilized in the production of impact modifiers, textile finishing agents, and as a chemical intermediate in various polymerization processes across multiple industrial applications.

How to handle methyl 2-methylprop-2-enoate safely?

Methyl 2-methylprop-2-enoate requires careful handling due to its flammable nature and skin sensitizing properties. Wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Ensure adequate ventilation to prevent vapor accumulation and eliminate ignition sources. Handle in well-ventilated areas away from heat, sparks, and open flames. Avoid direct skin and eye contact, and implement proper grounding procedures during transfer operations.

How to store methyl 2-methylprop-2-enoate correctly?

Methyl 2-methylprop-2-enoate must be stored in a cool, dry, well-ventilated area away from heat sources, direct sunlight, and ignition sources. Keep containers tightly sealed and store below recommended temperature limits to prevent polymerization. Separate from strong oxidizers, acids, and bases to avoid incompatible reactions. Use appropriate secondary containment and ensure storage areas comply with flammable liquid storage regulations and local fire safety codes.

What to do in case of contact with methyl 2-methylprop-2-enoate?

Skin contact with methyl 2-methylprop-2-enoate requires immediate removal of contaminated clothing and thorough washing with soap and water for at least 15 minutes. For eye contact, flush immediately with clean water for 15 minutes and seek medical attention. If inhaled, move to fresh air immediately. In case of ingestion, do not induce vomiting and seek immediate medical assistance. Remove from heat sources and provide supportive care as needed.

How to dispose of methyl 2-methylprop-2-enoate appropriately?

Methyl 2-methylprop-2-enoate disposal must comply with local, national, and EU waste regulations as a hazardous chemical waste. Contact licensed waste disposal contractors specialized in flammable and hazardous organic chemicals. Do not discharge into sewers, water bodies, or regular waste streams. Small quantities may be allowed for controlled incineration at authorized facilities. Always consult current waste classification codes and disposal requirements before proceeding with disposal activities.

How to transport methyl 2-methylprop-2-enoate?

Methyl 2-methylprop-2-enoate is classified as ADR Class 3 (flammable liquids), Packing Group II for transportation purposes. Transport requires appropriate UN-specification packaging, proper labeling with GHS02 and GHS07 pictograms, and hazard identification numbers. Vehicles must comply with ADR regulations for flammable liquids, including proper ventilation, emergency equipment, and driver certification. Ensure proper documentation and emergency response information accompanies all shipments.

Is methyl 2-methylprop-2-enoate subject to specific regulations?

Methyl 2-methylprop-2-enoate is regulated under various European frameworks including REACH registration requirements and CLP classification regulations. It is classified with multiple hazard classes including flammable liquid, skin irritant, and skin sensitizer, requiring appropriate safety data sheets and hazard communication. While not currently listed as an SVHC substance, it remains subject to standard chemical safety assessments, workplace exposure limits, and industrial emissions regulations across EU member states.

Where to buy methyl 2-methylprop-2-enoate in Europe?

Methyl 2-methylprop-2-enoate is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across the continent. OYSI provides reliable supply chains for this important chemical intermediate, ensuring compliance with European regulations and quality standards. As a professional chemical distributor, OYSI offers technical support and appropriate documentation for industrial applications requiring this methacrylate monomer.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.