Methyl 2-methylprop-2-enoate
C5H8O2
methyl 2-methylprop-2-enoate
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Identification
- CAS Number
- 80-62-6
- EC Number
- 201-297-1
- UN Number
- 1247
- Index Number
- 607-035-00-6
- PubChem CID
- 6658
Physical-chemical properties
- Molecular Formula
- C5H8O2
- Molar Mass
- 100.12 g/mol
- IUPAC Name
- methyl 2-methylprop-2-enoate
Chemical Identifiers
- InChI
- InChI=1S/C5H8O2/c1-4(2)5(6)7-3/h1H2,2-3H3
- InChI Key
- VVQNEPGJFQJSBK-UHFFFAOYSA-N
Overview
Methyl 2-methylprop-2-enoate (CAS 80-62-6) is an acrylic ester monomer with high reactivity and polymerization capability. This important industrial chemical, also known by its EC number 201-297-1, belongs to the family of methacrylic compounds and serves as a fundamental building block in polymer chemistry. With its molecular formula C5H8O2 and molecular weight of 100.12 g/mol, this colorless liquid exhibits characteristic properties that make it valuable across multiple manufacturing sectors. The substance presents significant safety considerations, classified under GHS pictograms GHS02 and GHS07 with a "Danger" signal word. Its hazard profile includes flammable liquid category 2, skin irritation category 2, skin sensitization category 1, and specific target organ toxicity (single exposure) category 3. As an ADR class 3 substance, proper handling protocols and storage conditions are essential to ensure workplace safety and regulatory compliance. Methyl 2-methylprop-2-enoate demonstrates excellent polymerization characteristics, making it particularly suitable for acrylic resin production, coating formulations, and adhesive manufacturing. The chemical industry frequently utilizes this monomer in the synthesis of polymethyl methacrylate and various copolymers. Its applications extend to specialty coatings where durability and chemical resistance are paramount, similar to applications involving styrene in certain polymer systems. The substance's reactivity profile requires careful temperature control and inhibitor management during storage and processing. Like ethylbenzene, proper ventilation systems and personal protective equipment are crucial when handling this material due to its vapor properties and potential health effects. OYSI maintains reliable supply chains for methyl 2-methylprop-2-enoate, supporting European manufacturers with consistent quality and comprehensive technical documentation.
Safety & Classification
Flam. Liq. 2; STOT SE 3; Skin Irrit. 2; Skin Sens. 1
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 1247 |
| ADR Class | 3 |
| Packing Group | II |
| Tunnel Code | D/E |
| Proper Shipping Name | Methylmethacrylat, Monomer, stabilisiert |
| Marine Pollutant | No |
Frequently Asked Questions
What is methyl 2-methylprop-2-enoate?
Methyl 2-methylprop-2-enoate is an organic chemical compound with the molecular formula C5H8O2 and CAS number 80-62-6. Also known as methyl methacrylate (MMA), it is a volatile ester with a molecular weight of 100.12 g/mol. This substance is classified as a flammable liquid and is considered hazardous due to its potential for skin irritation, sensitization, and specific target organ toxicity. It carries the danger signal word and requires careful handling in industrial applications.
What are the physicochemical properties of methyl 2-methylprop-2-enoate?
Methyl 2-methylprop-2-enoate is a colorless, volatile liquid at room temperature with a characteristic acrid odor. It has a molecular weight of 100.12 g/mol and the chemical formula C5H8O2. The substance is moderately soluble in water but highly soluble in organic solvents. It exhibits high volatility and flammability, classified as Flammable Liquid Category 2. The compound readily polymerizes under certain conditions and requires stabilizers to prevent unwanted reactions during storage and transport.
What is methyl 2-methylprop-2-enoate used for?
Methyl 2-methylprop-2-enoate serves as a crucial monomer in the production of polymethyl methacrylate (PMMA) plastics, commonly known as acrylic glass or plexiglass. It is extensively used in manufacturing transparent plastics, coatings, adhesives, and sealants. The chemical industry utilizes it for producing dental materials, bone cement, paints, and various polymer composites. Its polymerization properties make it valuable in creating durable, weather-resistant materials for automotive, construction, and optical applications.
How to handle methyl 2-methylprop-2-enoate safely?
Methyl 2-methylprop-2-enoate requires careful handling due to its flammable and irritating properties. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, and respiratory protection in poorly ventilated areas. Work should be conducted in well-ventilated spaces away from ignition sources, as it carries Flammable Liquid Category 2 classification. Avoid direct skin contact due to its skin irritation and sensitization potential (Skin Irrit. 2; Skin Sens. 1). Ensure proper grounding and bonding when transferring the substance.
How to store methyl 2-methylprop-2-enoate correctly?
Methyl 2-methylprop-2-enoate must be stored in a cool, well-ventilated area away from heat sources, sparks, and open flames due to its Flammable Liquid Category 2 classification. Storage containers should be tightly sealed and made of compatible materials. The substance should be kept away from strong oxidizers and polymerization initiators. Temperature control is crucial to prevent unwanted polymerization. Storage areas must comply with fire safety regulations and include appropriate fire suppression systems designed for flammable liquids.
What to do in case of contact with methyl 2-methylprop-2-enoate?
Immediate action is required upon contact with methyl 2-methylprop-2-enoate due to its irritating and sensitizing properties. For skin contact, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush immediately with clean water for 15 minutes while holding eyelids open. If inhaled, move the person to fresh air immediately. Seek medical attention if irritation persists or if large amounts were involved. Never induce vomiting if swallowed.
How to dispose of methyl 2-methylprop-2-enoate appropriately?
Methyl 2-methylprop-2-enoate must be disposed of as hazardous waste in accordance with local and European waste regulations. The substance cannot be discharged into sewers, waterways, or regular waste streams due to its flammable and potentially harmful properties. Disposal should be conducted through licensed hazardous waste treatment facilities capable of handling flammable organic compounds. Empty containers may retain hazardous residues and require proper cleaning or disposal as contaminated packaging. Always consult local environmental authorities for specific disposal requirements.
How to transport methyl 2-methylprop-2-enoate?
Methyl 2-methylprop-2-enoate is classified under ADR Class 3 (flammable liquids), Packing Group II, indicating moderate danger during transport. Transportation requires appropriate UN-approved packaging designed for flammable liquids and proper hazard labeling including GHS02 and GHS07 pictograms. Vehicles must carry appropriate fire extinguishing equipment and emergency response information. Drivers require ADR certification for dangerous goods transport. The substance must be secured to prevent movement and protected from heat sources during transit. Proper documentation and emergency contact information are mandatory.
Is methyl 2-methylprop-2-enoate subject to specific regulations?
Methyl 2-methylprop-2-enoate is regulated under European REACH and CLP regulations, requiring registration for commercial use and proper classification labeling. It carries multiple hazard classifications including Flammable Liquid 2, STOT SE 3, Skin Irritant 2, and Skin Sensitizer 1, mandating specific safety measures. The substance is not currently listed as a Substance of Very High Concern (SVHC). Occupational exposure limits may apply in workplace environments. Users must maintain safety data sheets and ensure compliance with national chemical safety regulations across EU member states.
Where to buy methyl 2-methylprop-2-enoate in Europe?
Methyl 2-methylprop-2-enoate is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this substance to industrial customers across Europe with proper documentation, safety data sheets, and regulatory compliance support. As a professional chemical distributor, OYSI ensures quality standards and can provide technical assistance for specific applications. Contact OYSI directly for availability, specifications, and delivery options. Due to its hazardous classification, purchase requires appropriate handling capabilities and may be subject to quantity restrictions for certain customer categories.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.