Ethoxy(diethyl)alumane

C6H15AlO

ethoxy(diethyl)alumane

CAS1586-92-1

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Identification

CAS Number
1586-92-1
EC Number
216-447-1
UN Number
3394
Index Number
013-004-00-2
PubChem CID
16683109

Physical-chemical properties

Molecular Formula
C6H15AlO
Molar Mass
130.16 g/mol
IUPAC Name
ethoxy(diethyl)alumane

Chemical Identifiers

InChI
InChI=1S/C2H5O.2C2H5.Al/c1-2-3;2*1-2;/h2H2,1H3;2*1H2,2H3;/q-1;;;+1
InChI Key
GCPCLEKQVMKXJM-UHFFFAOYSA-N

Overview

Ethoxy(diethyl)alumane (CAS 1586-92-1) is an organoaluminum compound characterized by its ethoxy and diethyl functional groups bonded to aluminum. This specialized organoaluminum compound represents an important class of organometallic reagents widely utilized in industrial chemical processes. With the molecular formula C6H15AlO and a molecular weight of 130.16 g/mol, ethoxy(diethyl)alumane features a unique combination of alkyl and alkoxy substituents attached to the central aluminum atom, providing distinctive reactivity patterns compared to fully alkylated aluminum compounds. As an organoaluminum species, this compound exhibits high reactivity toward moisture and oxygen, requiring careful handling under inert atmospheric conditions. The presence of both ethyl and ethoxy groups creates a mixed alkyl-alkoxy structure that offers specific advantages in catalytic applications where controlled reactivity is essential. Like other organoaluminum compounds such as tripropylalumane and trioctylalumane, it demonstrates strong Lewis acid properties and serves as an effective reducing agent in various chemical transformations. The compound finds primary application in polymerization catalysis, particularly as a cocatalyst in Ziegler-Natta systems for olefin polymerization. Its mixed substituent pattern provides optimal balance between reactivity and selectivity in these catalytic processes. Additionally, it serves as a valuable reagent in organic synthesis for carbon-carbon bond formation reactions and as an alkylating agent in specialized chemical manufacturing. Industrial applications also extend to the production of advanced materials where precise control of aluminum incorporation is required, including specialty ceramics and electronic materials precursors. OYSI provides ethoxy(diethyl)alumane to meet the demanding requirements of European chemical manufacturers and research institutions requiring high-quality organoaluminum reagents.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number3394
ADR Class4.2
Packing GroupI
Tunnel CodeB/E
Proper Shipping NameEthoxydiethylalumnium, flüssig, pyrophor
Marine PollutantNo

Frequently Asked Questions

What is ethoxy(diethyl)alumane?

Ethoxy(diethyl)alumane is an organoaluminum compound with the molecular formula C6H15AlO and CAS number 1586-92-1. This chemical features an aluminum center bonded to two ethyl groups and one ethoxy group, making it a trisubstituted aluminum derivative. With a molecular weight of 130.16 g/mol, it belongs to the family of alkylaluminum compounds commonly used in organometallic chemistry and industrial applications requiring aluminum-carbon bonds.

What are the physicochemical properties of ethoxy(diethyl)alumane?

Ethoxy(diethyl)alumane is typically a liquid organoaluminum compound that is highly reactive with moisture and air. Like most alkylaluminum compounds, it is likely colorless to pale yellow and has a characteristic organometallic odor. The compound is moisture-sensitive and will react vigorously with water, alcohols, and other protic solvents. It is soluble in non-polar organic solvents such as hydrocarbons and ethers but must be handled under inert atmosphere conditions.

What is ethoxy(diethyl)alumane used for?

Ethoxy(diethyl)alumane is primarily used as a catalyst or co-catalyst in polymerization reactions, particularly in the production of polyolefins and other synthetic polymers. It serves as an alkylating agent in organic synthesis and as a reducing agent in various chemical processes. The compound is also utilized in the preparation of other organometallic compounds and as a precursor for aluminum-containing materials in specialized industrial applications requiring controlled aluminum delivery.

How to handle ethoxy(diethyl)alumane safely?

Ethoxy(diethyl)alumane must be handled under strict inert atmosphere conditions using nitrogen or argon gas. Personnel should wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. All work should be conducted in well-ventilated areas or under fume hoods. Avoid contact with moisture, water, alcohols, and oxidizing agents. Use dry, inert solvents only and ensure all equipment is thoroughly dried before use to prevent violent reactions.

How to store ethoxy(diethyl)alumane correctly?

Ethoxy(diethyl)alumane should be stored in tightly sealed containers under inert atmosphere (nitrogen or argon) at controlled temperature conditions. Storage areas must be dry, well-ventilated, and protected from heat sources and direct sunlight. Keep away from water, alcohols, acids, bases, and oxidizing materials to prevent dangerous reactions. Containers should be made of compatible materials and regularly inspected for integrity. Storage facilities should have appropriate fire suppression systems designed for flammable liquids.

What to do in case of contact with ethoxy(diethyl)alumane?

Ethoxy(diethyl)alumane contact requires immediate emergency response due to its reactive nature. For skin contact, do not use water directly - first remove with a dry cloth, then flush with copious amounts of water and seek medical attention. For eye contact, rinse immediately with water for at least 15 minutes and get emergency medical care. If inhaled, move to fresh air and seek medical attention. In case of fire, use dry chemical extinguishers - never use water-based extinguishers.

How to dispose of ethoxy(diethyl)alumane appropriately?

Ethoxy(diethyl)alumane disposal must follow hazardous waste regulations and requires careful neutralization by trained professionals. The compound should be carefully quenched with appropriate alcohols under controlled conditions, never with water directly. Disposal must be conducted through licensed hazardous waste contractors familiar with organometallic compounds. Empty containers may still contain reactive residues and require special treatment. Consult local environmental authorities and waste management specialists for proper disposal procedures and documentation requirements.

How to transport ethoxy(diethyl)alumane?

Ethoxy(diethyl)alumane is classified under ADR Class 4.2 (substances liable to spontaneous combustion), Packing Group I, indicating high danger level. Transportation requires specialized packaging that prevents contact with moisture and air, using UN-approved containers with proper labeling and documentation. Vehicles must comply with ADR regulations for Class 4.2 materials, including appropriate placarding, emergency equipment, and trained drivers. Shipping documentation must include proper shipping names, hazard classes, and emergency contact information.

Is ethoxy(diethyl)alumane subject to particular regulations?

Ethoxy(diethyl)alumane is subject to various chemical safety regulations including REACH registration requirements in Europe for commercial use. While not classified as a Substance of Very High Concern (SVHC), it must comply with CLP regulation for classification, labeling, and packaging. Industrial users must implement appropriate risk management measures and maintain safety data sheets. Transportation is regulated under ADR/RID dangerous goods regulations, and workplace exposure may be subject to occupational health and safety requirements.

Where to buy ethoxy(diethyl)alumane in Europe?

Ethoxy(diethyl)alumane is available through OYSI, a specialized European distributor of technical chemicals with expertise in organometallic compounds. OYSI provides high-quality ethoxy(diethyl)alumane with proper documentation, safety data sheets, and regulatory compliance support. As a professional chemical distributor, OYSI ensures appropriate packaging, handling, and delivery throughout Europe while maintaining the product's integrity and providing technical support for safe handling and application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.