Bis(2-methylpropyl)alumane
C8H19Al
bis(2-methylpropyl)alumane
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Identification
- CAS Number
- 1191-15-7
- EC Number
- 214-729-9
- UN Number
- 3394
- PubChem CID
- 14487
Physical-chemical properties
- Molecular Formula
- C8H19Al
- Molar Mass
- 142.22 g/mol
- IUPAC Name
- bis(2-methylpropyl)alumane
Chemical Identifiers
- InChI
- InChI=1S/2C4H9.Al.H/c2*1-4(2)3;;/h2*4H,1H2,2-3H3;;
- InChI Key
- AZWXAPCAJCYGIA-UHFFFAOYSA-N
Overview
Bis(2-methylpropyl)alumane (CAS 1191-15-7) is an organoaluminum compound with the molecular formula C8H19Al and distinctive alkylating properties. This specialized organoaluminum compound belongs to the family of trialkylaluminum derivatives, characterized by its two isobutyl groups bonded to an aluminum center. With a molecular weight of 142.22 g/mol and EC number 214-729-9, bis(2-methylpropyl)alumane represents an important intermediate in organometallic chemistry applications. The compound exhibits typical organoaluminum reactivity patterns, making it particularly valuable in catalytic processes and synthetic chemistry applications. As an organoaluminum species, this compound demonstrates high reactivity toward moisture and oxygen, requiring careful handling under inert atmosphere conditions. Its classification under ADR Class 4.2 indicates its pyrophoric nature, necessitating specialized storage and transportation protocols. The substance shares structural similarities with related compounds such as tris(2-methylpropyl)alumane and tripropylalumane, though its specific stoichiometry provides distinct reactivity characteristics. The compound finds primary application in polymer chemistry as a cocatalyst in Ziegler-Natta polymerization systems, where it serves as an essential activating agent. Additionally, it functions as a reducing agent in specialized organic synthesis reactions and as a precursor for aluminum-containing thin films in semiconductor manufacturing processes. Its controlled reactivity profile makes it particularly suitable for applications requiring precise aluminum incorporation. OYSI maintains reliable supply chains for bis(2-methylpropyl)alumane, ensuring consistent availability for European industrial customers requiring this specialized organoaluminum compound for their technical applications.
Safety & Classification
No Hazard Classification
This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.
Transport (ADR)
| UN Number | 3394 |
| ADR Class | 4.2 |
| Packing Group | I |
| Tunnel Code | B/E |
| Proper Shipping Name | Diisobutylaluminiumhydrid, flüssig, pyrophor |
| Marine Pollutant | No |
Frequently Asked Questions
What is bis(2-methylpropyl)alumane?
Bis(2-methylpropyl)alumane is an organoaluminum compound with the molecular formula C8H19Al and CAS number 1191-15-7. This chemical features aluminum bonded to two 2-methylpropyl groups, giving it a molecular weight of 142.22 g/mol. As an organoaluminum compound, it belongs to a class of chemicals known for their reactivity and utility in various industrial applications, particularly in catalysis and chemical synthesis processes.
What are the physicochemical properties of bis(2-methylpropyl)alumane?
Bis(2-methylpropyl)alumane is typically a colorless to pale yellow liquid at room temperature due to its organoaluminum structure. The compound is highly reactive with moisture and oxygen, making it air and water sensitive. It has a molecular weight of 142.22 g/mol and is generally soluble in non-protic organic solvents such as hydrocarbons and ethers, while being incompatible with protic solvents due to its reactive aluminum center.
What is bis(2-methylpropyl)alumane used for?
Bis(2-methylpropyl)alumane is primarily used as a catalyst or co-catalyst in polymerization reactions, particularly in the production of polyolefins. It serves as an alkylating agent in organic synthesis and can be employed in the preparation of other organoaluminum compounds. The compound is also utilized in specialized chemical processes where controlled aluminum alkyl chemistry is required, including certain industrial synthesis applications and research activities.
How to handle bis(2-methylpropyl)alumane safely?
Bis(2-methylpropyl)alumane must be handled under inert atmosphere conditions using appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to prevent exposure to vapors. Due to its reactive nature, avoid contact with moisture, air, and incompatible materials. Use proper grounding procedures to prevent static discharge during transfer operations.
How to store bis(2-methylpropyl)alumane correctly?
Bis(2-methylpropyl)alumane must be stored under inert gas atmosphere (nitrogen or argon) in tightly sealed containers to prevent contact with moisture and oxygen. Storage should occur in a cool, dry place away from heat sources and incompatible materials such as water, alcohols, and oxidizing agents. Containers should be made of compatible materials and stored in secondary containment systems to prevent environmental release in case of leakage.
What to do in case of contact with bis(2-methylpropyl)alumane?
Immediate removal from exposure is essential in case of contact with bis(2-methylpropyl)alumane. For skin contact, remove contaminated clothing and flush affected areas with plenty of water. In case of eye contact, rinse immediately with water for at least 15 minutes. If inhaled, move to fresh air immediately. Seek immediate medical attention for all exposure routes. Do not induce vomiting if ingested and contact poison control or emergency services immediately.
How to dispose of bis(2-methylpropyl)alumane appropriately?
Bis(2-methylpropyl)alumane must be disposed of according to local, national, and international hazardous waste regulations. The compound should be neutralized carefully under controlled conditions before disposal, typically through controlled hydrolysis procedures. Contact certified hazardous waste disposal companies for proper treatment and disposal. Never discharge into drains, waterways, or soil. Maintain proper documentation of disposal procedures as required by applicable environmental regulations.
How to transport bis(2-methylpropyl)alumane?
Bis(2-methylpropyl)alumane is classified under ADR Class 4.2 (Substances liable to spontaneous combustion), Packing Group I, indicating high danger level. Transport requires specialized packaging that prevents contact with moisture and air, typically under inert atmosphere. Proper shipping documentation, labeling, and placarding are mandatory. Only authorized carriers trained in handling dangerous goods should transport this material, following all applicable dangerous goods transportation regulations.
Is bis(2-methylpropyl)alumane subject to specific regulations?
Bis(2-methylpropyl)alumane is subject to various chemical regulations including REACH registration requirements in the European Union for commercial use. It is not currently listed as a Substance of Very High Concern (SVHC). The compound must comply with CLP regulation requirements for classification and labeling, workplace safety regulations, and dangerous goods transport regulations. Users must ensure compliance with local chemical inventory and notification requirements.
Where to buy bis(2-methylpropyl)alumane in Europe?
Bis(2-methylpropyl)alumane is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this organoaluminum compound to industrial customers across Europe, ensuring proper packaging, documentation, and regulatory compliance. As a technical chemical requiring specialized handling and storage, it is typically sold to qualified industrial users with appropriate safety and handling capabilities. Contact OYSI directly for availability, technical specifications, and pricing information.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.