Chloro-ethyl-(2-methylpropyl)alumane
C6H14AlCl
chloro-ethyl-(2-methylpropyl)alumane
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Identification
- CAS Number
- 13320-53-1
- EC Number
- 236-357-6
- UN Number
- 3394
- PubChem CID
- 83339
Physical-chemical properties
- Molecular Formula
- C6H14AlCl
- Molar Mass
- 148.61 g/mol
- IUPAC Name
- chloro-ethyl-(2-methylpropyl)alumane
Chemical Identifiers
- InChI
- InChI=1S/C4H9.C2H5.Al.ClH/c1-4(2)3;1-2;;/h4H,1H2,2-3H3;1H2,2H3;;1H/q;;+1;/p-1
- InChI Key
- MDUJPDJIABVTQO-UHFFFAOYSA-M
Overview
Chloro-ethyl-(2-methylpropyl)alumane (CAS 13320-53-1) is an organoaluminum compound characterized by its reactive aluminum-carbon bonds and pyrophoric properties. This specialized organoaluminum reagent belongs to a class of highly reactive chemical compounds featuring aluminum directly bonded to organic groups. With the molecular formula C6H14AlCl and a molecular weight of 148.61 g/mol, chloro-ethyl-(2-methylpropyl)alumane exhibits the characteristic reactivity profile expected from mixed alkylaluminum compounds. The compound's structure incorporates both ethyl and isobutyl substituents alongside a chlorine atom, creating a versatile intermediate for various synthetic applications. The compound is classified under ADR Class 4.2 as a pyrophoric substance, indicating its tendency to ignite spontaneously upon contact with air at ambient temperatures. This property necessitates careful handling under inert atmosphere conditions, typically requiring storage and manipulation in nitrogen or argon environments. Like other members of the organoaluminum family, including tris(2-methylpropyl)alumane and tripropylalumane, this compound demonstrates high sensitivity to moisture and oxygen, forming aluminum oxides and releasing flammable hydrocarbon gases upon exposure. In industrial applications, chloro-ethyl-(2-methylpropyl)alumane serves primarily as a catalyst component in polymerization processes, particularly in the production of polyolefins where precise control of molecular weight and polymer architecture is required. The compound also finds application in organic synthesis as a reducing agent and in specialized metallurgical processes where selective aluminum introduction is necessary. OYSI maintains reliable supply chains for chloro-ethyl-(2-methylpropyl)alumane, ensuring consistent availability for European industrial customers requiring this specialized organoaluminum compound.
Safety & Classification
No Hazard Classification
This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.
Transport (ADR)
| UN Number | 3394 |
| ADR Class | 4.2 |
| Packing Group | I |
| Tunnel Code | B/E |
| Proper Shipping Name | Ethylisobutylaluminiumchlorid, flüssig, pyrophor |
| Marine Pollutant | No |
Frequently Asked Questions
What is chloro-ethyl-(2-methylpropyl)alumane?
Chloro-ethyl-(2-methylpropyl)alumane is an organoaluminum compound with the molecular formula C6H14AlCl and CAS number 13320-53-1. This chemical features an aluminum center bonded to an ethyl group, a 2-methylpropyl group, and a chlorine atom. With a molecular weight of 148.61 g/mol, it belongs to the family of alkylaluminum compounds commonly used in industrial applications requiring aluminum-carbon bonds.
What are the physicochemical properties of chloro-ethyl-(2-methylpropyl)alumane?
Chloro-ethyl-(2-methylpropyl)alumane is typically a liquid or low-melting solid at room temperature due to its organoaluminum structure. Like most alkylaluminum compounds, it is highly reactive with moisture and oxygen, requiring anhydrous conditions for stability. The compound is likely colorless to pale yellow and exhibits high reactivity toward protic solvents. Its molecular structure makes it soluble in non-polar organic solvents but incompatible with water.
What is chloro-ethyl-(2-methylpropyl)alumane used for?
Chloro-ethyl-(2-methylpropyl)alumane is primarily used as a catalyst or co-catalyst in polymerization reactions, particularly in the production of polyolefins. It serves as an alkylating agent in organic synthesis and can be employed in Ziegler-Natta catalysis systems. The compound is also utilized in aluminum-carbon bond forming reactions and as a reducing agent in specialized chemical processes requiring controlled aluminum delivery.
How to handle chloro-ethyl-(2-methylpropyl)alumane safely?
Chloro-ethyl-(2-methylpropyl)alumane must be handled under strict anhydrous conditions using appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under inert atmosphere to prevent moisture contact. Use non-sparking tools and avoid contact with water or alcohols. Emergency shower and eyewash stations should be readily accessible during handling operations.
How to store chloro-ethyl-(2-methylpropyl)alumane correctly?
Chloro-ethyl-(2-methylpropyl)alumane must be stored in tightly sealed containers under inert gas atmosphere, typically nitrogen or argon, to prevent moisture and oxygen exposure. Storage areas should be cool, dry, and well-ventilated, away from water sources, alcohols, and oxidizing agents. Containers should be made of compatible materials and regularly inspected for integrity. Emergency response equipment must be available in storage areas.
What to do in case of contact with chloro-ethyl-(2-methylpropyl)alumane?
In case of skin contact with chloro-ethyl-(2-methylpropyl)alumane, immediately remove contaminated clothing and flush the affected area with large amounts of water for at least 15 minutes. For eye contact, rinse thoroughly with water and seek immediate medical attention. If inhaled, move the person to fresh air and provide respiratory support if needed. Never use water on spilled material due to violent reaction potential. Seek immediate medical attention for all exposures.
How to dispose of chloro-ethyl-(2-methylpropyl)alumane properly?
Chloro-ethyl-(2-methylpropyl)alumane disposal must be performed by licensed hazardous waste contractors following local and European waste regulations. The compound cannot be disposed of through normal drainage systems due to its reactivity with water. Controlled hydrolysis or incineration under specialized conditions may be required. Consult local environmental authorities for specific disposal requirements and ensure proper waste classification documentation is maintained throughout the disposal process.
How to transport chloro-ethyl-(2-methylpropyl)alumane?
Chloro-ethyl-(2-methylpropyl)alumane is classified under ADR Class 4.2 (Substances liable to spontaneous combustion), Packing Group I, indicating high transport risk. Special packaging requirements include hermetically sealed containers with inert gas protection and appropriate hazard labeling. Transportation must comply with dangerous goods regulations, requiring trained personnel and proper documentation. Vehicles must be equipped with appropriate emergency response equipment and follow designated routing restrictions.
Is chloro-ethyl-(2-methylpropyl)alumane subject to specific regulations?
Chloro-ethyl-(2-methylpropyl)alumane is subject to standard European chemical regulations including REACH registration requirements and CLP classification rules. The compound is not listed as a Substance of Very High Concern (SVHC) but must comply with standard industrial chemical handling and reporting requirements. Users must maintain safety data sheets and ensure proper risk assessments are conducted before use in accordance with European occupational safety regulations.
Where to buy chloro-ethyl-(2-methylpropyl)alumane in Europe?
Chloro-ethyl-(2-methylpropyl)alumane is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across Europe. OYSI provides this organoaluminum compound with proper documentation, safety data sheets, and regulatory compliance support. As a specialty chemical requiring expert handling, procurement should only be made through qualified distributors who understand the technical requirements and safety protocols necessary for this reactive compound.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.