Chloro-ethyl-(2-methylpropyl)alumane
C6H14AlCl
chloro-ethyl-(2-methylpropyl)alumane
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Identification
- CAS Number
- 13320-53-1
- EC Number
- 236-357-6
- UN Number
- 3394
- PubChem CID
- 83339
Physical-chemical properties
- Molecular Formula
- C6H14AlCl
- Molar Mass
- 148.61 g/mol
- IUPAC Name
- chloro-ethyl-(2-methylpropyl)alumane
Chemical Identifiers
- InChI
- InChI=1S/C4H9.C2H5.Al.ClH/c1-4(2)3;1-2;;/h4H,1H2,2-3H3;1H2,2H3;;1H/q;;+1;/p-1
- InChI Key
- MDUJPDJIABVTQO-UHFFFAOYSA-M
Overview
Chloro-ethyl-(2-methylpropyl)alumane (CAS 13320-53-1) is an organoaluminum compound featuring both alkyl and halide substituents on the aluminum center. This specialized organoaluminum compound belongs to the family of mixed alkyl-halide aluminum derivatives, characterized by its unique combination of ethyl and isobutyl (2-methylpropyl) groups along with a chlorine atom bonded to aluminum. With a molecular formula of C6H14AlCl and molecular weight of 148.61 g/mol, this compound represents an important intermediate in organometallic chemistry and industrial applications requiring selective aluminum-carbon bond formation. The compound exhibits typical organoaluminum reactivity patterns, including high sensitivity to moisture and air, necessitating careful handling under inert atmosphere conditions. Its ADR classification as Class 4.2 indicates its pyrophoric nature, meaning it can spontaneously ignite upon contact with air. This characteristic requires specialized storage and transportation protocols to ensure safety and product integrity. Chloro-ethyl-(2-methylpropyl)alumane shares structural similarities with other organoaluminum compounds such as tris(2-methylpropyl)alumane, though the presence of the chloride substituent significantly modifies its reactivity profile and applications. The mixed alkyl-halide structure provides unique selectivity in certain synthetic transformations compared to fully alkylated aluminum compounds. Primary industrial applications include use as a catalyst component in polymerization reactions, particularly in the production of specialized polymers where controlled molecular weight and stereochemistry are crucial. The compound also serves as an alkylating agent in organic synthesis and as a precursor for other organoaluminum derivatives used in advanced materials manufacturing. OYSI maintains reliable supply chains for chloro-ethyl-(2-methylpropyl)alumane to support European industrial customers requiring high-quality organoaluminum compounds for their specialized chemical processes.
Safety & Classification
No Hazard Classification
This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.
Transport (ADR)
| UN Number | 3394 |
| ADR Class | 4.2 |
| Packing Group | I |
| Tunnel Code | B/E |
| Proper Shipping Name | Ethylisobutylaluminiumchlorid, flüssig, pyrophor |
| Marine Pollutant | No |
Frequently Asked Questions
What is chloro-ethyl-(2-methylpropyl)alumane?
Chloro-ethyl-(2-methylpropyl)alumane is an organoaluminum compound with the molecular formula C6H14AlCl and CAS number 13320-53-1. This chemical features an aluminum center bonded to an ethyl group, a 2-methylpropyl group, and a chlorine atom. With a molecular weight of 148.61 g/mol, it belongs to the class of organometallic compounds that are commonly used as catalysts and reagents in various chemical processes.
What are the physicochemical properties of chloro-ethyl-(2-methylpropyl)alumane?
Chloro-ethyl-(2-methylpropyl)alumane is typically a liquid or low-melting solid at room temperature, characteristic of many organoaluminum compounds. As an organometallic substance, it is highly reactive with moisture and air, requiring anhydrous conditions for storage and handling. The compound is generally soluble in non-protic organic solvents such as hydrocarbons and ethers, but reacts violently with water and alcohols.
What is chloro-ethyl-(2-methylpropyl)alumane used for?
Chloro-ethyl-(2-methylpropyl)alumane is primarily used as a catalyst and co-catalyst in polymerization reactions, particularly in the production of polyolefins. It serves as an alkylating agent in organic synthesis and can be employed in Ziegler-Natta catalysis systems. The compound is also utilized in specialized chemical manufacturing processes where controlled aluminum-carbon bond formation is required, making it valuable in pharmaceutical and fine chemical industries.
How to handle chloro-ethyl-(2-methylpropyl)alumane safely?
Chloro-ethyl-(2-methylpropyl)alumane requires strict safety protocols due to its pyrophoric nature and reactivity with moisture. Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Handle only under inert atmosphere conditions using nitrogen or argon gas. Work in well-ventilated areas or under fume hoods, and ensure all equipment is thoroughly dried before use to prevent violent reactions with trace moisture.
How to store chloro-ethyl-(2-methylpropyl)alumane correctly?
Chloro-ethyl-(2-methylpropyl)alumane must be stored under strictly anhydrous conditions in sealed containers under inert gas atmosphere. Store in a cool, dry place away from sources of ignition, moisture, and incompatible materials such as water, alcohols, and oxidizing agents. The storage area should be equipped with appropriate fire suppression systems and maintained at stable temperatures to prevent thermal decomposition or spontaneous ignition.
What to do in case of contact with chloro-ethyl-(2-methylpropyl)alumane?
Immediate action is required if contact occurs with chloro-ethyl-(2-methylpropyl)alumane. For skin contact, do not use water as it may cause violent reactions; instead, carefully remove contaminated clothing and brush off any solid material before seeking medical attention. In case of eye contact, flush with mineral oil if available, then seek immediate medical care. For inhalation, move to fresh air immediately and get medical attention promptly.
How to dispose of chloro-ethyl-(2-methylpropyl)alumane appropriately?
Chloro-ethyl-(2-methylpropyl)alumane requires specialized disposal procedures due to its hazardous nature. Never dispose of this substance down drains or with regular waste. Contact licensed hazardous waste disposal companies that specialize in organometallic compounds. The material should be carefully neutralized under controlled conditions by trained professionals using appropriate quenching agents before final disposal, following all local and international waste regulations.
How to transport chloro-ethyl-(2-methylpropyl)alumane?
Chloro-ethyl-(2-methylpropyl)alumane is classified under ADR Class 4.2 (substances liable to spontaneous combustion) with Packing Group I, indicating high danger level. Transport requires specialized packaging approved for pyrophoric substances, with proper labeling and documentation. Shipments must be handled by carriers certified for dangerous goods transport, with appropriate emergency response procedures in place and protection from moisture throughout the transportation chain.
Is chloro-ethyl-(2-methylpropyl)alumane subject to specific regulations?
Chloro-ethyl-(2-methylpropyl)alumane is subject to various chemical regulations including REACH registration requirements in Europe for commercial use. While not classified as a Substance of Very High Concern (SVHC), it falls under dangerous goods regulations due to its pyrophoric properties. Users must comply with workplace safety regulations, proper classification and labeling requirements, and maintain safety data sheets for handling and emergency procedures.
Where to buy chloro-ethyl-(2-methylpropyl)alumane in Europe?
Chloro-ethyl-(2-methylpropyl)alumane is available through OYSI, a specialized European distributor of technical chemicals and organometallic compounds. As a professional chemical supplier, OYSI provides this substance to qualified industrial customers with proper handling capabilities. Due to the specialized nature and safety requirements of this compound, procurement is typically limited to established chemical manufacturers, research institutions, and companies with appropriate safety infrastructure and expertise.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.