Alumane

AlH3

alumane

CAS7784-21-6

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Identification

CAS Number
7784-21-6
EC Number
232-053-2
UN Number
2463
PubChem CID
14488

Physical-chemical properties

Molecular Formula
AlH3
Molar Mass
30.00 g/mol
IUPAC Name
alumane

Chemical Identifiers

InChI
InChI=1S/Al.3H
InChI Key
AZDRQVAHHNSJOQ-UHFFFAOYSA-N

Overview

Alumane (CAS 7784-21-6) is an aluminum hydride compound with highly reactive properties and significant industrial applications as a reducing agent. Alumane represents one of the most important aluminum hydrides in industrial chemistry, serving as a powerful reducing agent across multiple sectors. This inorganic compound consists of aluminum bonded to three hydrogen atoms, creating a molecule with exceptional reactivity characteristics that make it valuable for specialized chemical processes. Unlike other metal hydrides such as silane, alumane exhibits unique stability properties under controlled conditions while maintaining its strong reducing capabilities. The compound demonstrates remarkable versatility in organic synthesis applications, where its selective reducing properties enable precise chemical transformations. Its molecular structure allows for controlled hydrogen transfer reactions, making it particularly useful in pharmaceutical intermediate production and fine chemical manufacturing. The substance's reactivity profile requires careful handling protocols, as it readily reacts with moisture and oxygen, necessitating inert atmosphere storage and handling procedures. Safety considerations are paramount when working with alumane, given its classification under ADR Class 4.3, indicating its nature as a substance that emits flammable gases when in contact with water. Professional handling equipment and specialized storage facilities are essential for safe utilization in industrial applications. Primary industrial applications include metal surface treatment processes, where alumane serves as an effective reducing agent for metal oxide removal and surface preparation. The compound also finds extensive use in semiconductor manufacturing for specialized etching and deposition processes, and in advanced materials synthesis where precise reduction reactions are required. OYSI maintains reliable supply chains for alumane, ensuring consistent availability for European industrial customers requiring this specialized reducing agent.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number2463
ADR Class4.3
Packing GroupI
Tunnel CodeE
Proper Shipping NameAluminiumhydrid
Marine PollutantNo

Frequently Asked Questions

What is alumane?

Alumane is an aluminum hydride compound with the chemical formula AlH3 and CAS number 7784-21-6. It represents the simplest binary compound of aluminum and hydrogen, with a molecular weight of 30.005 g/mol. This compound is highly reactive and serves as an important reducing agent in various chemical processes. Alumane is classified as a hazardous material under transport regulations due to its reactivity with water and potential for hydrogen gas generation.

What are the physicochemical properties of alumane?

Alumane exists as a white crystalline solid at room temperature that is extremely reactive with moisture and air. The compound readily decomposes in contact with water, releasing hydrogen gas and forming aluminum hydroxide. It has a molecular weight of 30.005 g/mol and is insoluble in most common solvents due to its ionic nature. Alumane must be handled under inert atmosphere conditions as it rapidly hydrolyzes when exposed to atmospheric moisture.

What is alumane used for?

Alumane serves primarily as a powerful reducing agent in organic synthesis and metallurgical applications. It is utilized in the production of high-purity aluminum compounds and as a hydrogen source in specialized chemical reactions. The compound finds applications in research laboratories for reduction reactions where strong reducing conditions are required. Additionally, alumane is used in certain specialized industrial processes requiring controlled hydrogen release or aluminum deposition under specific conditions.

How to handle alumane safely?

Alumane must be handled under strictly controlled inert atmosphere conditions using appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. All handling should occur in well-ventilated areas or under inert gas to prevent contact with moisture. Personnel should be trained in emergency procedures due to the compound's high reactivity. Work surfaces and equipment must be completely dry, and handling should be minimized to reduce exposure risks.

How to store alumane correctly?

Alumane requires storage in airtight containers under inert atmosphere, typically nitrogen or argon, to prevent contact with moisture and oxygen. Storage areas must be dry, cool, and well-ventilated with temperatures maintained below 25°C. The compound should be kept away from water sources, acids, and oxidizing materials. Storage containers must be made of compatible materials and regularly inspected for integrity. Access should be restricted to trained personnel only.

What to do in case of contact with alumane?

Immediate removal from exposure is essential if contact with alumane occurs. For skin contact, brush off dry material carefully without using water initially, then seek medical attention. Eye contact requires immediate irrigation with clean water after removing any solid particles. If ingested, do not induce vomiting and seek immediate medical care. In case of inhalation, move to fresh air immediately. Emergency responders should be informed of the chemical's identity and hazards.

How to dispose of alumane appropriately?

Alumane disposal must comply with local and international hazardous waste regulations due to its reactive nature. The compound should be carefully neutralized by trained professionals using controlled hydrolysis methods under inert conditions. Disposal must be arranged through licensed hazardous waste contractors experienced with reactive materials. Never dispose of alumane through regular waste streams or water systems. Complete documentation of disposal methods and destinations is required for regulatory compliance.

How to transport alumane?

Alumane is classified under ADR as Class 4.3 (substances which, in contact with water, emit flammable gases), Packing Group I, indicating high danger level. Transportation requires specialized packaging that prevents moisture ingress and proper hazard labeling. Vehicles must be equipped with appropriate safety equipment and drivers must be trained in dangerous goods transport. Shipping documentation must include proper shipping names, hazard classifications, and emergency response information.

Is alumane subject to specific regulations?

Alumane is regulated under European REACH legislation requiring registration for commercial use above specified tonnages. The compound is not currently classified as a Substance of Very High Concern (SVHC). Transport regulations under ADR/RID apply due to its reactive nature. Users must comply with CLP regulation requirements for classification, labeling, and packaging. Industrial users should maintain safety data sheets and ensure proper risk assessments are conducted before handling.

Where to buy alumane in Europe?

Alumane is available through OYSI, a specialized European distributor of technical chemicals with expertise in handling reactive compounds. OYSI provides proper packaging, documentation, and technical support for alumane purchases across Europe. As a specialized chemical requiring careful handling, alumane is typically available through established chemical suppliers with appropriate storage and transport capabilities. Customers should ensure their suppliers can provide proper safety documentation and technical support for this reactive compound.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.