Trioctylalumane

C24H51Al

trioctylalumane

CAS1070-00-4

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Identification

CAS Number
1070-00-4
EC Number
213-964-4
UN Number
3394
Index Number
013-004-00-2
PubChem CID
16682948

Physical-chemical properties

Molecular Formula
C24H51Al
Molar Mass
366.60 g/mol
IUPAC Name
trioctylalumane

Chemical Identifiers

InChI
InChI=1S/3C8H17.Al/c3*1-3-5-7-8-6-4-2;/h3*1,3-8H2,2H3;
InChI Key
LFXVBWRMVZPLFK-UHFFFAOYSA-N

Overview

Trioctylalumane (CAS 1070-00-4) is an organoaluminum compound with three octyl groups bonded to a central aluminum atom, featuring high reactivity and pyrophoric properties. This specialized organoaluminum reagent belongs to the family of trialkylaluminum compounds, which are essential intermediates in organometallic chemistry and industrial catalysis. The molecule consists of an aluminum center covalently bonded to three linear octyl chains, resulting in a highly reactive organometallic structure with significant synthetic utility. Due to its extended alkyl chains, trioctylalumane exhibits distinct solubility characteristics and reactivity patterns compared to shorter-chain analogs such as tripropylalumane and tributylalumane. The compound presents notable safety considerations as an ADR Class 4.2 substance, indicating its spontaneous combustibility properties. Like other trialkylaluminum compounds, it reacts violently with water, alcohols, and protic solvents, requiring strict anhydrous handling conditions and inert atmosphere storage. The material typically appears as a colorless to pale yellow liquid with high sensitivity to air and moisture, necessitating specialized storage and handling protocols in industrial applications. Primary industrial applications include its use as a cocatalyst in polyolefin production, particularly in Ziegler-Natta and metallocene catalyst systems for polyethylene and polypropylene manufacturing. The compound also serves as a reducing agent in specialized organic syntheses and as an alkylating reagent for preparing other organometallic compounds. Additionally, it finds application in the production of high-performance aluminum-based catalysts for various petrochemical processes. OYSI maintains reliable supply chains for trioctylalumane, ensuring consistent availability for European industrial customers requiring this specialized organometallic reagent.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number3394
ADR Class4.2
Packing GroupI
Tunnel CodeB/E
Proper Shipping NameTrioctylaluminium, flüssig, pyrophor
Marine PollutantNo

Frequently Asked Questions

What is trioctylalumane?

Trioctylalumane is an organoaluminum compound with the molecular formula C24H51Al and CAS number 1070-00-4. This chemical substance has a molecular weight of 366.6 g/mol and belongs to the family of trialkylaluminum compounds. It is characterized by three octyl groups bonded to a central aluminum atom, making it a highly reactive organometallic compound used in various industrial applications.

What are the physicochemical properties of trioctylalumane?

Trioctylalumane is typically a colorless to pale yellow liquid at room temperature with low volatility due to its high molecular weight. The compound is highly sensitive to moisture and air, readily reacting with water and oxygen. It is soluble in non-polar organic solvents such as hydrocarbons and ethers but reacts violently with polar protic solvents like water and alcohols.

What is trioctylalumane used for?

Trioctylalumane is primarily used as a catalyst or co-catalyst in polymerization reactions, particularly in the production of polyolefins. It serves as an alkylating agent in organic synthesis and as a precursor for aluminum-containing thin films in semiconductor manufacturing. Additionally, it finds applications in the preparation of other organometallic compounds and as a reducing agent in specialized chemical processes.

How to handle trioctylalumane safely?

Trioctylalumane must be handled under inert atmosphere conditions using appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods due to its pyrophoric nature. Avoid contact with water, moisture, and oxidizing agents. Use only spark-free tools and equipment to prevent ignition of this highly reactive compound.

How to store trioctylalumane correctly?

Trioctylalumane should be stored in tightly sealed containers under inert gas atmosphere (nitrogen or argon) to prevent contact with air and moisture. Storage areas must be cool, dry, and well-ventilated, away from heat sources, ignition sources, and incompatible materials such as water, alcohols, and oxidizing agents. Containers should be made of compatible materials and properly labeled according to safety regulations.

What to do in case of contact with trioctylalumane?

Trioctylalumane contact requires immediate action due to its reactive nature. In case of skin contact, remove contaminated clothing and flush the affected area with large amounts of water. For eye contact, rinse immediately with water for at least 15 minutes. If inhaled, move to fresh air immediately. Seek medical attention promptly in all cases and never use water on spills as it may cause violent reactions.

How to dispose of trioctylalumane appropriately?

Trioctylalumane disposal must follow strict hazardous waste regulations due to its reactive and pyrophoric properties. The compound should be carefully neutralized by trained professionals using appropriate quenching agents under controlled conditions. Never dispose of it in regular waste streams or pour it down drains. Contact licensed hazardous waste disposal companies and follow local environmental regulations for proper disposal procedures.

How to transport trioctylalumane?

Trioctylalumane is classified under ADR Class 4.2 (substances liable to spontaneous combustion) with Packing Group I, indicating high danger level. Transportation requires specialized packaging that prevents contact with air and moisture. Vehicles must be properly placarded and drivers trained in hazardous materials handling. Shipments must comply with international dangerous goods regulations and be accompanied by proper documentation and emergency response information.

Is trioctylalumane subject to particular regulations?

Trioctylalumane is subject to various chemical safety regulations including REACH registration requirements in Europe and classification under the CLP Regulation. As an organometallic compound, it may be subject to specific handling and reporting requirements. While not currently listed as a SVHC substance, users must comply with occupational safety standards and environmental protection measures when handling this reactive chemical.

Where to buy trioctylalumane in Europe?

Trioctylalumane is available through OYSI, a European distributor specializing in technical chemicals and organometallic compounds. As an established chemical supplier, OYSI can provide this specialized organoaluminum compound to qualified industrial customers across Europe. Contact OYSI directly for availability, technical specifications, and ordering information, ensuring compliance with all safety and regulatory requirements for handling this reactive substance.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.