Trioctylalumane
C24H51Al
trioctylalumane
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Identification
- CAS Number
- 1070-00-4
- EC Number
- 213-964-4
- UN Number
- 3394
- Index Number
- 013-004-00-2
- PubChem CID
- 16682948
Physical-chemical properties
- Molecular Formula
- C24H51Al
- Molar Mass
- 366.60 g/mol
- IUPAC Name
- trioctylalumane
Chemical Identifiers
- InChI
- InChI=1S/3C8H17.Al/c3*1-3-5-7-8-6-4-2;/h3*1,3-8H2,2H3;
- InChI Key
- LFXVBWRMVZPLFK-UHFFFAOYSA-N
Overview
Trioctylalumane (CAS 1070-00-4) is an organoaluminum compound with three octyl groups bonded to a central aluminum atom, exhibiting pyrophoric properties. This specialized organoaluminum compound represents an important class of organometallic chemicals used in various industrial applications. With its molecular formula C24H51Al and molecular weight of 366.6 g/mol, trioctylalumane features three linear octyl chains attached to aluminum, giving it distinct properties compared to shorter-chain analogs like tripropylalumane or tributylalumane. The compound's structure provides enhanced solubility in organic solvents and modified reactivity patterns that make it valuable for specific chemical processes. As a pyrophoric substance classified under ADR Class 4.2, trioctylalumane requires careful handling and storage under inert atmospheric conditions to prevent spontaneous ignition upon contact with air or moisture. The compound demonstrates high reactivity toward water, alcohols, and other protic solvents, making proper safety protocols essential during handling and storage operations. Its long alkyl chains contribute to increased thermal stability compared to lower homologs while maintaining the characteristic high Lewis acidity of organoaluminum compounds. Trioctylalumane finds primary applications in polymerization catalysis, particularly as a cocatalyst in olefin polymerization systems where its extended alkyl chains can influence polymer properties. It also serves as an alkylating agent in organic synthesis and as a component in specialized catalyst systems for various chemical transformations. Additionally, the compound is utilized in certain surface modification processes where controlled aluminum incorporation is required. OYSI maintains reliable supply chains for trioctylalumane and related organoaluminum compounds, ensuring consistent availability for European industrial customers requiring these specialized chemical intermediates.
Safety & Classification
No Hazard Classification
This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.
Transport (ADR)
| UN Number | 3394 |
| ADR Class | 4.2 |
| Packing Group | I |
| Tunnel Code | B/E |
| Proper Shipping Name | Trioctylaluminium, flüssig, pyrophor |
| Marine Pollutant | No |
Frequently Asked Questions
What is trioctylalumane?
Trioctylalumane is an organoaluminum compound with the molecular formula C24H51Al and CAS number 1070-00-4. This chemical substance consists of an aluminum atom bonded to three octyl groups, giving it a molecular weight of 366.6 g/mol. As a specialized organometallic compound, trioctylalumane belongs to the family of alkylaluminum chemicals used in various industrial applications requiring aluminum-carbon bonding properties.
What are the physicochemical properties of trioctylalumane?
Trioctylalumane is typically a colorless to pale yellow liquid at room temperature due to its long alkyl chain structure. The compound exhibits low solubility in water but shows good solubility in organic solvents such as hydrocarbons and ethers. Its high molecular weight (366.6 g/mol) and branched structure contribute to its relatively high boiling point and viscosity compared to simpler alkylaluminum compounds.
What is trioctylalumane used for?
Trioctylalumane is primarily used as a catalyst or co-catalyst in polymerization reactions, particularly in the production of polyolefins. It serves as an activator in metallocene catalysis systems and finds applications in alkylation reactions. The compound is also utilized in the synthesis of other organometallic compounds and as a reducing agent in specialized chemical processes within the petrochemical and polymer industries.
How to handle trioctylalumane safely?
Trioctylalumane requires careful handling due to its classification as ADR Class 4.2 (spontaneously combustible substances). Personnel should wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under inert atmosphere to prevent contact with air and moisture. Keep away from heat sources, open flames, and oxidizing materials during handling operations.
How to store trioctylalumane correctly?
Trioctylalumane must be stored under inert gas atmosphere (nitrogen or argon) in tightly sealed containers to prevent oxidation and spontaneous combustion. Storage areas should be cool, dry, and well-ventilated, away from heat sources and incompatible materials such as water, alcohols, and oxidizing agents. Containers should be made of compatible materials and properly labeled according to ADR Class 4.2 requirements.
What to do in case of contact with trioctylalumane?
Trioctylalumane contact requires immediate action due to its reactive nature. For skin contact, remove contaminated clothing and flush the affected area with plenty of water for at least 15 minutes. In case of eye contact, rinse immediately with water and seek medical attention. If inhaled, move the person to fresh air and provide respiratory support if needed. Never use water directly on spilled material due to potential violent reactions.
How to dispose of trioctylalumane properly?
Trioctylalumane disposal must comply with local and national hazardous waste regulations as it is classified as dangerous goods. The compound should be carefully neutralized using appropriate methods under controlled conditions, typically involving reaction with alcohols or water under inert atmosphere. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Never dispose of untreated material in regular waste streams or sewage systems.
How to transport trioctylalumane?
Trioctylalumane is classified under ADR Class 4.2 (spontaneously combustible substances) Packing Group I, indicating high danger level during transport. Packages must comply with specific UN packaging requirements and be properly labeled with appropriate hazard labels. Transport vehicles must carry appropriate documentation and emergency response information. Only trained personnel should handle transportation, and specific routing restrictions may apply depending on local regulations.
Is trioctylalumane subject to specific regulations?
Trioctylalumane is subject to REACH regulation as a chemical substance placed on the European market, requiring registration for quantities above specified thresholds. The compound must comply with CLP regulation for classification and labeling requirements. As it is not listed as a SVHC (Substance of Very High Concern), standard registration procedures apply. Users must maintain safety data sheets and comply with occupational exposure limits where applicable.
Where to buy trioctylalumane in Europe?
Trioctylalumane is available through OYSI, a specialized European distributor of technical chemicals and organometallic compounds. As an established chemical distributor, OYSI provides trioctylalumane to industrial customers across Europe with appropriate documentation, safety data sheets, and regulatory compliance. Contact OYSI directly for availability, specifications, packaging options, and delivery arrangements to your specific location within Europe.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.