Ethanethiol

C2H6S

ethanethiol

CAS75-08-1
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

Consulting for Ethanethiol

Our experts support you with application, dosage, and compliance.

Request Consultation

Identification

CAS Number
75-08-1
EC Number
200-837-3
UN Number
2363
Index Number
016-022-00-9
PubChem CID
6343

Physical-chemical properties

Molecular Formula
C2H6S
Molar Mass
62.14 g/mol
IUPAC Name
ethanethiol

Chemical Identifiers

InChI
InChI=1S/C2H6S/c1-2-3/h3H,2H2,1H3
InChI Key
DNJIEGIFACGWOD-UHFFFAOYSA-N

Overview

Ethanethiol (CAS 75-08-1) is an aliphatic thiol compound with a characteristic strong odor and high flammability properties. This low molecular weight organosulfur compound serves as a critical industrial chemical in various technical applications across European markets. Ethanethiol belongs to the thiol family, characterized by the presence of a sulfhydryl (-SH) functional group attached to an ethyl carbon chain. Its molecular structure (C2H6S) makes it one of the simplest mercaptans, sharing certain reactive properties with other sulfur-containing compounds, though it differs significantly from nitrogen-based chemicals like prop-2-enenitrile in terms of reactivity patterns and industrial uses. The compound presents significant safety considerations due to its classification under multiple hazard categories. Its Flam. Liq. 1 classification indicates extremely flammable properties, requiring careful handling protocols and appropriate storage conditions. The acute toxicity ratings (Acute Tox. 3 and 4) necessitate proper personal protective equipment and ventilation systems during industrial processing. Additionally, its aquatic toxicity classifications (Aquatic Acute 1 and Aquatic Chronic 1) demand strict environmental protection measures during handling and disposal. Ethanethiol finds primary applications in chemical synthesis as an intermediate compound, particularly in pharmaceutical manufacturing and specialty chemical production. The petrochemical industry utilizes it as an odorant additive for natural gas detection, leveraging its distinctively strong smell for safety purposes. It also serves as a precursor in the synthesis of various organosulfur compounds used in agricultural and industrial formulations. OYSI provides ethanethiol to qualified industrial customers throughout Europe, ensuring compliance with ADR Class 3 transportation requirements and comprehensive technical support for safe handling procedures.

Safety & Classification

Danger
Classification:

Flam. Liq. 1; Acute Tox. 3; Acute Tox. 4; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H224

Extremely flammable liquid and vapour.

H331

Toxic if inhaled.

H302

Harmful if swallowed.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2363
ADR Class3
Packing GroupI
Tunnel CodeD/E
Proper Shipping NameEthylmercaptan
Marine PollutantNo

Frequently Asked Questions

What is ethanethiol?

Ethanethiol is an organosulfur compound with the molecular formula C2H6S and a molecular weight of 62.14 g/mol. It belongs to the thiol family, characterized by the presence of a sulfur-hydrogen (-SH) functional group. This chemical is classified as a highly flammable liquid with acute toxicity properties and environmental hazards. Ethanethiol is known for its extremely strong, unpleasant odor reminiscent of rotten eggs or garlic, making it detectable at very low concentrations.

What are the physicochemical properties of ethanethiol?

Ethanethiol is a colorless liquid at room temperature with an extremely pungent, offensive odor that can be detected at parts-per-billion levels. It has a low boiling point and high volatility, making it readily evaporate into vapor. The compound is slightly soluble in water but miscible with most organic solvents including alcohols and ethers. Its molecular structure consists of an ethyl group bonded to a sulfur atom, which in turn is bonded to a hydrogen atom.

What is ethanethiol used for?

Ethanethiol serves primarily as an odorant additive for natural gas and propane to enable leak detection, as these gases are naturally odorless. It is also used as an intermediate in the synthesis of pharmaceuticals, pesticides, and other organosulfur compounds. In the chemical industry, ethanethiol finds applications in the production of plastics, rubber chemicals, and as a building block for various sulfur-containing molecules. Additionally, it may be used in analytical chemistry and research applications.

How to handle ethanethiol safely?

Ethanethiol requires strict safety measures due to its high flammability and toxicity. Personnel must wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection in well-ventilated areas. All ignition sources must be eliminated from the work area. Handle only in areas equipped with emergency shower and eyewash facilities. Use explosion-proof electrical equipment and ensure proper grounding of containers. Work should be conducted in a fume hood or with adequate local exhaust ventilation.

How to store ethanethiol correctly?

Ethanethiol must be stored in a cool, dry, well-ventilated area away from heat sources, sparks, and open flames due to its Class I flammability. Use only approved containers and keep them tightly sealed to prevent vapor escape and odor issues. Store separately from oxidizing agents, strong acids, and bases to avoid incompatible reactions. The storage area should have appropriate fire suppression systems and leak detection equipment. Ensure compliance with local fire codes and maintain appropriate inventory limits.

What to do in case of contact with ethanethiol?

Ethanethiol exposure requires immediate action due to its acute toxicity. For skin contact, remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, rinse immediately with plenty of clean water for at least 15 minutes and seek medical attention. If inhaled, move the person to fresh air immediately and seek medical help if breathing difficulties occur. For ingestion, do not induce vomiting and seek immediate medical attention.

How to dispose of ethanethiol appropriately?

Ethanethiol disposal must comply with local, national, and European waste regulations due to its hazardous classification. The substance cannot be disposed of in regular waste streams and requires treatment at authorized hazardous waste facilities. Small quantities may be incinerated under controlled conditions with appropriate scrubbing systems to handle sulfur dioxide formation. Container disposal must follow specific protocols for flammable and toxic substances. Always consult with certified waste management companies and maintain proper documentation for regulatory compliance.

How to transport ethanethiol?

Ethanethiol is classified under ADR Class 3 (flammable liquids), Packing Group I, indicating high danger during transport. It requires UN-specification packaging and proper hazard labeling with flammable, toxic, and environmental hazard pictogrammes. Transport vehicles must comply with ADR regulations including appropriate equipment for dangerous goods. Drivers require ADR training certification, and transport documents must accompany shipments. Emergency response information and appropriate fire extinguishing equipment must be available during transport. Shipments should avoid extreme temperatures and rough handling.

Is ethanethiol subject to particular regulations?

Ethanethiol is subject to comprehensive European chemical regulations including REACH registration requirements and CLP classification as a dangerous substance. It carries the signal word 'Danger' with multiple hazard classifications including flammable liquid, acute toxicity, and aquatic hazards. While not currently listed as an SVHC (Substance of Very High Concern), it requires safety data sheets, proper labeling, and risk assessments. Workplace exposure limits may apply, and users must implement appropriate risk management measures according to chemical safety regulations.

Where to buy ethanethiol in Europe?

Ethanethiol is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across the continent. As a professional chemical distributor, OYSI provides proper documentation, safety data sheets, and regulatory compliance support for ethanethiol purchases. Due to the substance's hazardous nature, procurement is typically limited to qualified industrial users with appropriate handling capabilities. Contact OYSI directly for availability, technical specifications, and delivery options tailored to your specific industrial requirements and location within Europe.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.