O-ethylhydroxylamine

C2H7NO

CAS624-86-2
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
624-86-2
EC Number
402-030-3
UN Number
1992
Index Number
007-015-00-1
PubChem CID
69357

Physical-chemical properties

Molecular Formula
C2H7NO
Molar Mass
61.08 g/mol
IUPAC Name
O-ethylhydroxylamine

Chemical Identifiers

InChI
InChI=1S/C2H7NO/c1-2-4-3/h2-3H2,1H3
InChI Key
AQFWNELGMODZGC-UHFFFAOYSA-N

Overview

O-ethylhydroxylamine (CAS 624-86-2) is an organic hydroxylamine derivative with notable reactivity and significant safety considerations for industrial applications. This chemical compound, with the molecular formula C2H7NO and a molecular weight of 61.08 g/mol, represents an important member of the hydroxylamine family used in various industrial processes. O-ethylhydroxylamine is characterized by its flammable liquid properties and requires careful handling due to its multiple hazard classifications, including acute toxicity and potential for specific target organ toxicity with repeated exposure. The compound exhibits significant safety concerns, as indicated by its Danger signal word and multiple GHS pictograms including GHS02 (flame), GHS06 (skull and crossbones), GHS08 (health hazard), and GHS09 (environment). Its classification as a Class 3 substance under ADR transportation regulations reflects its flammable liquid nature, requiring specialized storage and transport conditions. The substance can cause eye irritation and skin sensitization, necessitating appropriate personal protective equipment during handling. In industrial applications, O-ethylhydroxylamine finds use primarily as an intermediate in organic synthesis, particularly in the production of pharmaceuticals and specialty chemicals. It serves as a valuable reagent in the formation of oximes and other nitrogen-containing compounds. The compound is also utilized in certain polymer chemistry applications where controlled reactivity is required. Unlike more volatile compounds such as prop-2-enenitrile, O-ethylhydroxylamine offers specific reactivity patterns that make it suitable for targeted synthetic pathways. OYSI maintains reliable supply chains for O-ethylhydroxylamine, ensuring consistent availability for European industrial customers requiring this specialized chemical intermediate.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; Acute Tox. 3 *; Acute Tox. 3 *; Acute Tox. 3 *; STOT RE 1; Eye Irrit. 2; Skin Sens....

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H331

Toxic if inhaled.

H311

Toxic in contact with skin.

H301

Toxic if swallowed.

H372

Causes damage to organs through prolonged or repeated exposure.

H319

Causes serious eye irritation.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Toxic

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1992
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameO-Ethylhydroxylamin
Marine PollutantNo

Frequently Asked Questions

What is O-ethylhydroxylamine?

O-ethylhydroxylamine is an organic chemical compound with the molecular formula C2H7NO and CAS number 624-86-2. This hydroxylamine derivative has a molecular weight of 61.08 g/mol and is classified as a hazardous substance with multiple danger classifications including flammable liquid, acute toxicity, and specific target organ toxicity. It requires careful handling due to its significant health and safety risks.

What are the physicochemical properties of O-ethylhydroxylamine?

O-ethylhydroxylamine is a liquid compound with flammable properties, as indicated by its Flam. Liq. 2 classification. The substance has a molecular mass of 61.08 g/mol and contains nitrogen and oxygen functional groups that contribute to its reactivity. Its physical state and flammable nature require specific storage and handling precautions to prevent ignition and ensure safe use.

What is O-ethylhydroxylamine used for?

O-ethylhydroxylamine is primarily used as a chemical intermediate in organic synthesis and pharmaceutical manufacturing. Its hydroxylamine structure makes it valuable for various chemical reactions, particularly in the preparation of specialized compounds. Due to its high toxicity profile and flammable nature, its applications are typically restricted to professional industrial settings with appropriate safety controls and expertise.

How to handle O-ethylhydroxylamine safely?

O-ethylhydroxylamine requires strict safety protocols due to its Acute Tox. 3 classification and multiple hazard pictograms (GHS02, GHS06, GHS08, GHS09). Essential protective equipment includes chemical-resistant gloves, safety goggles, and respiratory protection. Work should be conducted in well-ventilated areas or fume hoods, away from ignition sources. Emergency procedures must be established, and only trained personnel should handle this substance.

How to store O-ethylhydroxylamine correctly?

O-ethylhydroxylamine must be stored in a cool, dry, well-ventilated area away from heat sources and ignition points due to its Flam. Liq. 2 classification. Storage containers should be tightly sealed and made of compatible materials. The storage area should be equipped with appropriate fire suppression systems and spill containment measures. Access should be restricted to authorized personnel only.

What to do in case of contact with O-ethylhydroxylamine?

O-ethylhydroxylamine exposure requires immediate medical attention due to its Acute Tox. 3 classification. For skin contact, remove contaminated clothing and rinse thoroughly with water. In case of eye contact, flush immediately with plenty of water and seek medical care due to Eye Irrit. 2 classification. If inhaled or ingested, seek immediate medical attention. Always consult the safety data sheet for specific first aid measures.

How to dispose of O-ethylhydroxylamine appropriately?

O-ethylhydroxylamine disposal must comply with local and European waste regulations due to its hazardous classification. The substance cannot be disposed of as regular waste and requires specialized hazardous waste treatment. Contact licensed waste disposal companies familiar with toxic and flammable chemical waste. Never pour down drains or dispose of in regular trash due to environmental and safety risks.

How to transport O-ethylhydroxylamine?

O-ethylhydroxylamine is classified under ADR Class 3, Packing Group II for transportation, indicating it is a flammable liquid requiring specific transport protocols. Packaging must meet UN specifications for dangerous goods, and vehicles must be properly placarded. Transport should only be conducted by certified carriers familiar with dangerous goods regulations and emergency response procedures for flammable toxic substances.

Is O-ethylhydroxylamine subject to special regulations?

O-ethylhydroxylamine is subject to multiple regulatory frameworks including CLP regulation due to its hazard classifications and REACH registration requirements. While not currently listed as an SVHC substance, its Acute Tox. 3 and STOT RE 1 classifications place it under strict handling and notification requirements. Users must comply with occupational exposure limits and reporting obligations under European chemical legislation.

Where to buy O-ethylhydroxylamine in Europe?

O-ethylhydroxylamine is available through specialized chemical distributors in Europe, including OYSI, which supplies industrial chemicals to European markets. Due to its hazardous classification requiring ADR Class 3 transport protocols, purchasing should only be conducted through established suppliers with proper dangerous goods handling capabilities and regulatory compliance. Professional documentation and safety data sheets are provided with all shipments.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.