Ethaneperoxoic acid

C2H4O3

ethaneperoxoic acid

CAS79-21-0
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
79-21-0
EC Number
201-186-8
UN Number
Index Number
607-094-00-8
PubChem CID
6585

Physical-chemical properties

Molecular Formula
C2H4O3
Molar Mass
76.05 g/mol
IUPAC Name
ethaneperoxoic acid

Chemical Identifiers

InChI
InChI=1S/C2H4O3/c1-2(3)5-4/h4H,1H3
InChI Key
KFSLWBXXFJQRDL-UHFFFAOYSA-N

Overview

Ethaneperoxoic acid (CAS 79-21-0) is a potent organic peroxide with strong oxidizing properties and significant industrial bleaching capabilities. This chemical compound, also known as peracetic acid, represents one of the most versatile and reactive organic peroxides available in industrial applications. With its molecular formula C2H4O3 and molecular weight of 76.05 g/mol, ethaneperoxoic acid exhibits exceptional antimicrobial and bleaching properties that make it indispensable across numerous industrial sectors. The compound belongs to the organic peroxide family, characterized by its inherent instability and powerful oxidizing nature. Safety considerations are paramount when handling ethaneperoxoic acid, as evidenced by its classification under multiple hazard categories including Organic Peroxide D, Acute Toxicity 2-3, and Skin Corrosion 1A. The substance requires careful storage and handling protocols due to its corrosive nature and potential for dangerous reactions. Its GHS pictogrammes (GHS02, GHS06, GHS05, GHS09) clearly indicate fire, toxicity, corrosion, and environmental hazards, necessitating appropriate personal protective equipment and containment measures. Industrial applications of ethaneperoxoic acid span several sectors, with primary uses in disinfection and sterilization processes within food processing, healthcare, and water treatment facilities. The compound serves as an effective bleaching agent in textile and pulp industries, offering advantages over traditional chlorine-based systems. Additionally, it functions as a valuable intermediate in chemical synthesis processes, sometimes used alongside other reactive compounds like prop-2-enal in specialized applications. OYSI maintains reliable supply chains for ethaneperoxoic acid, ensuring consistent availability for European industrial customers requiring this critical chemical component.

Safety & Classification

Danger
Classification:

Org. Perox. D; Acute Tox. 2; Acute Tox. 2; Acute Tox. 3; Skin Corr. 1A; Aquatic Acute 1; Aquatic ...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H242

Heating may cause a fire.

H330

Fatal if inhaled.

H310

Fatal in contact with skin.

H301

Toxic if swallowed.

H314

Causes severe skin burns and eye damage.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Fatal

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Frequently Asked Questions

What is ethaneperoxoic acid?

Ethaneperoxoic acid is an organic peroxide compound with the molecular formula C2H4O3 and CAS number 79-21-0. Also known as peroxyacetic acid or peracetic acid, it is a highly reactive chemical oxidizing agent with a molecular weight of 76.05 g/mol. This compound is classified as a dangerous substance due to its peroxide nature, acute toxicity, and corrosive properties, requiring careful handling and specialized safety measures.

What are the physicochemical properties of ethaneperoxoic acid?

Ethaneperoxoic acid is typically a colorless liquid with a sharp, pungent odor resembling acetic acid. It is highly soluble in water and polar organic solvents. The compound is thermally unstable and can decompose explosively under certain conditions. It has strong oxidizing properties and is corrosive to metals, skin, and mucous membranes. The substance readily decomposes into acetic acid, oxygen, and water, especially when heated or in contact with catalysts.

What is ethaneperoxoic acid used for?

Ethaneperoxoic acid is primarily used as a powerful disinfectant and sterilizing agent in food processing, healthcare, and water treatment industries. It serves as an effective antimicrobial agent against bacteria, viruses, fungi, and spores. Additionally, it is employed in textile bleaching, paper manufacturing, and as an oxidizing agent in various chemical synthesis processes. Its broad-spectrum antimicrobial properties make it valuable for surface disinfection and equipment sterilization applications.

How to handle ethaneperoxoic acid safely?

Ethaneperoxoic acid requires extensive personal protective equipment including chemical-resistant gloves, safety goggles, face shields, and acid-resistant clothing. Work must be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Avoid contact with skin, eyes, and clothing as it causes severe burns. Use only non-metallic tools and containers to prevent catalytic decomposition. Keep away from heat sources, incompatible materials, and ensure emergency shower facilities are readily accessible.

How to store ethaneperoxoic acid correctly?

Ethaneperoxoic acid must be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Use only approved containers made of compatible materials, avoiding metal containers that can catalyze decomposition. Store separately from incompatible substances including bases, reducing agents, and organic materials. Maintain storage temperatures as recommended by the manufacturer and regularly inspect containers for signs of deterioration or leakage. Implement proper inventory rotation practices.

What to do in case of contact with ethaneperoxoic acid?

Ethaneperoxoic acid exposure requires immediate emergency response due to its corrosive nature. For skin contact, immediately flush with copious amounts of water for at least 15 minutes while removing contaminated clothing. In case of eye contact, rinse thoroughly with water for at least 15 minutes and seek immediate medical attention. If inhaled, move the person to fresh air and provide oxygen if breathing is difficult. Seek immediate medical attention for all exposure incidents.

How to dispose of ethaneperoxoic acid appropriately?

Ethaneperoxoic acid disposal must comply with local, national, and European waste regulations due to its hazardous classification. The substance should be treated as hazardous waste and disposed of through licensed waste management companies. Small quantities may be carefully neutralized with appropriate alkaline solutions under controlled conditions by trained personnel. Never dispose of in regular drains or municipal waste systems. Consult local environmental authorities for specific disposal requirements and approved waste treatment facilities.

How to transport ethaneperoxoic acid?

Ethaneperoxoic acid transport is subject to dangerous goods regulations and requires specialized handling procedures. The substance must be packaged in approved containers that meet specific performance standards for organic peroxides. Transportation requires proper documentation, hazard labeling, and compliance with ADR/RID regulations for European road and rail transport. Only qualified carriers with appropriate permits and training should handle the transportation. Emergency response information must accompany all shipments.

Is ethaneperoxoic acid subject to specific regulations?

Ethaneperoxoic acid is subject to comprehensive European chemical regulations including REACH registration requirements and CLP classification obligations. The substance is classified under multiple hazard classes including organic peroxides, acute toxicity, and skin corrosion categories. It is not currently listed as an SVHC (Substance of Very High Concern). Companies handling this chemical must comply with occupational health and safety regulations, environmental discharge limits, and maintain appropriate safety data sheets and risk assessments.

Where to buy ethaneperoxoic acid in Europe?

Ethaneperoxoic acid is available through specialized chemical distributors across Europe, including OYSI, which serves as a reliable European distributor of technical chemicals. Due to its hazardous classification and regulatory requirements, purchases typically require proper business credentials, safety documentation, and compliance with intended use restrictions. Professional chemical suppliers can provide technical support, safety data sheets, and ensure proper packaging and transportation. Contact established distributors for availability, specifications, and regulatory compliance assistance.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.