Diphenyldiazene

C12H10N2

diphenyldiazene

CAS103-33-3
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
103-33-3
EC Number
203-102-5
UN Number
3077
Index Number
611-001-00-6
PubChem CID
2272

Physical-chemical properties

Molecular Formula
C12H10N2
Molar Mass
182.22 g/mol
IUPAC Name
diphenyldiazene

Chemical Identifiers

InChI
InChI=1S/C12H10N2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10H
InChI Key
DMLAVOWQYNRWNQ-UHFFFAOYSA-N

Overview

Diphenyldiazene (CAS 103-33-3) is an aromatic azo compound characterized by its distinctive N=N double bond linking two phenyl rings. This organic chemical compound, also known by its IUPAC name diphenyldiazene, represents a fundamental member of the azo compound family with the molecular formula C12H10N2 and a molecular weight of 182.22 g/mol. The substance features a characteristic azo bridge (-N=N-) connecting two benzene rings, giving it unique chemical properties that make it valuable in various industrial applications. Diphenyldiazene presents significant safety considerations due to its hazard profile, classified as carcinogenic category 1B and mutagenic category 2, requiring careful handling protocols. The compound carries the "Danger" signal word and displays GHS08, GHS07, and GHS09 pictograms, indicating serious health hazards and environmental risks. Its acute toxicity classification and potential for causing specific target organ toxicity upon repeated exposure necessitate appropriate protective measures during handling and storage. The substance also poses aquatic hazards, being classified as both acute and chronic aquatic toxin category 1. In industrial applications, diphenyldiazene serves primarily as an intermediate in organic synthesis and as a precursor for various chemical manufacturing processes. The compound finds use in the production of dyes and pigments, leveraging its azo functionality for color development. Additionally, it functions as a chemical intermediate in pharmaceutical synthesis, where its structural features enable the formation of more complex molecular architectures. Like other aromatic compounds such as 4-[(4-amino-3-chlorophenyl)methyl]-2-chloroaniline, diphenyldiazene requires specialized handling due to its toxicological profile. OYSI provides diphenyldiazene to qualified industrial customers with comprehensive safety documentation and technical support for compliant handling procedures.

Safety & Classification

Danger
Classification:

Carc. 1B; Muta. 2; Acute Tox. 4 *; Acute Tox. 4 *; STOT RE 2 *; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H350

May cause cancer.

H341

Suspected of causing genetic defects.

H332

Harmful if inhaled.

H302

Harmful if swallowed.

H373

May cause damage to organs through prolonged or repeated exposure.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameAzobenzen, fest
Marine PollutantNo

Frequently Asked Questions

What is diphenyldiazene?

Diphenyldiazene is an organic chemical compound with the molecular formula C12H10N2 and CAS number 103-33-3. It has a molecular weight of 182.22 g/mol and belongs to the diazene family of compounds. This substance is classified as a carcinogen category 1B and mutagen category 2, making it a highly hazardous chemical requiring strict safety protocols. It appears as crystalline solid and is primarily used in specialized industrial applications where its unique chemical properties are essential.

What are the physicochemical properties of diphenyldiazene?

Diphenyldiazene is a crystalline solid at room temperature with distinctive physicochemical characteristics. The compound typically appears as orange to red crystals and has limited solubility in water but dissolves well in organic solvents. It exhibits thermal instability and can decompose upon heating. The substance has a characteristic aromatic odor and demonstrates photosensitivity, meaning it can undergo chemical changes when exposed to light, which is important for storage and handling considerations.

What is diphenyldiazene used for?

Diphenyldiazene is primarily used as an intermediate in organic synthesis and as a precursor for various chemical compounds. It serves as an important building block in the pharmaceutical industry for synthesizing specific drug compounds and in the production of dyes and pigments. The compound is also utilized in research applications for studying azo chemistry and as a reagent in specialized analytical procedures. Its applications are typically restricted to professional and industrial settings due to its hazardous nature.

How to handle diphenyldiazene safely?

Diphenyldiazene requires strict safety protocols due to its carcinogenic and mutagenic properties. Personnel must wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Skin and eye contact must be avoided at all costs. Regular health monitoring of exposed workers is essential, and proper training on handling procedures is mandatory before working with this substance.

How to store diphenyldiazene correctly?

Diphenyldiazene must be stored in a cool, dry, and well-ventilated area away from direct sunlight and heat sources due to its thermal and photosensitivity. The substance should be kept in tightly sealed, chemically compatible containers, preferably in dark conditions. Storage areas must be secure and accessible only to authorized personnel. The compound should be segregated from incompatible materials including strong oxidizers and reducing agents. Regular inspection of storage conditions and container integrity is essential for safety.

What to do in case of contact with diphenyldiazene?

Immediate action is critical in case of diphenyldiazene exposure due to its toxic properties. For skin contact, remove contaminated clothing immediately and wash the affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush with clean water for at least 15 minutes and seek immediate medical attention. If inhaled, move the person to fresh air immediately. For ingestion, do not induce vomiting and seek emergency medical care. Always consult a physician after any exposure incident.

How to dispose of diphenyldiazene appropriately?

Diphenyldiazene disposal must comply with local and international hazardous waste regulations due to its classification as a carcinogen and environmental hazard. The substance cannot be disposed of in regular waste streams and requires specialized hazardous waste treatment facilities. Containers must be properly labeled and handled by certified waste management companies. Incineration at high temperatures in approved facilities is typically the preferred disposal method. Documentation of disposal procedures must be maintained for regulatory compliance and traceability.

How to transport diphenyldiazene?

Diphenyldiazene is classified as ADR Class 9 (Miscellaneous dangerous goods) Packing Group III for transportation purposes. The substance must be packaged in UN-approved containers with proper labeling including hazard pictograms GHS07, GHS08, and GHS09. Transport documents must include the correct shipping name, UN number, and hazard class. Vehicles must be equipped with appropriate safety equipment and drivers must have proper dangerous goods training. Temperature control may be necessary to prevent thermal decomposition during transport.

Is diphenyldiazene subject to specific regulations?

Diphenyldiazene is subject to comprehensive regulatory oversight under REACH, CLP, and other international chemical safety frameworks due to its hazardous properties. The substance requires safety data sheets and risk assessments for commercial use. Its classification as Carc. 1B and Muta. 2 means it falls under strict occupational exposure limits and worker protection requirements. Companies handling this substance must comply with registration, evaluation, and authorization procedures. Regular monitoring and reporting of usage may be required by regulatory authorities.

Where to buy diphenyldiazene in Europe?

Diphenyldiazene is available through specialized chemical distributors in Europe, including OYSI, which serves as a reliable supplier for professional and industrial customers. Due to its hazardous classification, purchase typically requires proper licensing, safety documentation, and proof of legitimate industrial use. Buyers must demonstrate adequate safety infrastructure and trained personnel for handling. OYSI can provide technical support, safety documentation, and ensure compliance with European regulations for customers requiring this specialized chemical compound.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.