Dimethylmercury
C2H6Hg
dimethylmercury
Consulting for Dimethylmercury
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Identification
- CAS Number
- 593-74-8
- EC Number
- 209-805-3
- UN Number
- 3383
- Index Number
- 080-007-00-3
- PubChem CID
- 11645
Physical-chemical properties
- Molecular Formula
- C2H6Hg
- Molar Mass
- 230.66 g/mol
- IUPAC Name
- dimethylmercury
Chemical Identifiers
- InChI
- InChI=1S/2CH3.Hg/h2*1H3;
- InChI Key
- ATZBPOVXVPIOMR-UHFFFAOYSA-N
Overview
Dimethylmercury (CAS 593-74-8) is an organometallic compound with extreme toxicity and high environmental persistence. Dimethylmercury represents one of the most hazardous organomercury compounds encountered in chemical applications, characterized by its exceptional toxicity profile and bioaccumulation potential. This colorless liquid compound, with the molecular formula C2H6Hg and a molecular weight of 230.66 g/mol, exhibits unique properties that make it both scientifically valuable and extraordinarily dangerous to handle. The compound's classification under multiple acute toxicity categories (Acute Tox. 1 and 2) reflects its severe health risks, including potential fatal outcomes through dermal, inhalation, or oral exposure. Its GHS06 and GHS08 pictograms emphasize both acute toxicity and serious health hazards, while the GHS09 designation highlights significant aquatic environmental concerns. The ADR Class 6.1 classification requires specialized transportation protocols due to its toxic nature. Unlike less volatile mercury compounds such as mercury(2+) dithiocyanate, dimethylmercury readily penetrates standard laboratory protective equipment, making it particularly hazardous during handling operations. Its STOT RE 2 classification indicates potential for repeated exposure organ damage, particularly affecting the central nervous system. Primary industrial applications include specialized analytical chemistry procedures, research into mercury methylation processes, and as a reference standard in environmental mercury analysis. The compound also serves in certain catalytic processes where its unique organometallic properties are essential. OYSI maintains strict safety protocols for dimethylmercury handling and distribution, ensuring compliance with European chemical regulations while supporting specialized industrial and research applications requiring this highly controlled substance.
Safety & Classification
Acute Tox. 2 *; Acute Tox. 1; Acute Tox. 2 *; STOT RE 2 *; Aquatic Acute 1; Aquatic Chronic 1
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 3383 |
| ADR Class | 6.1 |
| Packing Group | I |
| Tunnel Code | C/D |
| Proper Shipping Name | Dimethylquecksilber |
| Marine Pollutant | No |
Frequently Asked Questions
What is dimethylmercury?
Dimethylmercury is an extremely toxic organomercury compound with the molecular formula C2H6Hg and CAS number 593-74-8. This chemical substance has a molecular weight of 230.66 g/mol and represents one of the most dangerous mercury compounds known. It is classified with the highest toxicity categories and carries significant environmental hazards. Due to its extreme toxicity and ability to penetrate protective equipment, dimethylmercury requires exceptional safety measures and is restricted to specialized research applications only.
What are the physicochemical properties of dimethylmercury?
Dimethylmercury is a volatile, colorless liquid at room temperature with a characteristic metallic odor. The compound has a molecular formula C2H6Hg and molecular weight of 230.66 g/mol. It exhibits high volatility and lipophilicity, making it extremely dangerous as it can easily penetrate skin, rubber gloves, and other protective materials. The substance is slightly soluble in water but highly soluble in organic solvents, contributing to its rapid absorption through biological membranes.
What is dimethylmercury used for?
Dimethylmercury is primarily used as a reference standard in analytical chemistry and specialized research applications involving mercury speciation studies. Its use is extremely limited due to its extraordinary toxicity and is restricted to essential scientific research where no safer alternatives exist. The compound may be used in calibration procedures for mercury detection instruments and in studies investigating mercury bioaccumulation and environmental fate. Most historical industrial applications have been completely phased out due to safety concerns.
How to handle dimethylmercury safely?
Dimethylmercury requires the highest level of safety precautions including specialized laminated protective gloves (never latex or nitrile), full face respirators with mercury vapor cartridges, and work exclusively in certified fume hoods. Personnel must wear complete protective clothing and undergo specific training before handling. Work should be limited to essential quantities only, with continuous monitoring for mercury vapor. Emergency procedures and antidotes must be immediately available, and medical surveillance is mandatory for all exposed personnel.
How to store dimethylmercury correctly?
Dimethylmercury must be stored in tightly sealed, compatible containers within secondary containment systems in well-ventilated, temperature-controlled areas below 25°C. Storage areas require restricted access, mercury vapor monitoring, and emergency response equipment. The substance must be kept away from heat sources, incompatible materials, and areas with human traffic. Containers should be regularly inspected for integrity, and storage quantities must be minimized. Specialized disposal procedures must be established before procurement.
What to do in case of contact with dimethylmercury?
Dimethylmercury exposure requires immediate medical attention regardless of the exposure route. Remove contaminated clothing immediately and flush affected skin with copious amounts of water for at least 15 minutes. For inhalation exposure, move to fresh air immediately and provide oxygen if breathing is difficult. Contact poison control and emergency medical services instantly, informing them of dimethylmercury exposure. Time is critical as delayed treatment significantly worsens prognosis. Never induce vomiting if ingested.
How to dispose of dimethylmercury appropriately?
Dimethylmercury disposal requires specialized hazardous waste management through certified mercury waste treatment facilities capable of handling extremely toxic organomercury compounds. The substance cannot be disposed of through normal chemical waste streams and requires specific incineration or specialized treatment processes. All contaminated materials including gloves, containers, and equipment must be treated as hazardous mercury waste. Disposal must comply with national and international mercury waste regulations and requires proper documentation and chain of custody procedures.
How to transport dimethylmercury?
Dimethylmercury is classified as ADR Class 6.1 (Toxic substances) Packing Group I, indicating maximum danger level for toxic materials during transport. Transportation requires specialized packaging meeting UN specifications, proper hazard labeling with GHS06, GHS08, and GHS09 pictograms, and documentation indicating 'DANGER' signal word. Only certified dangerous goods transporters can handle shipments, and emergency response information must accompany all shipments. Quantity restrictions and route limitations may apply depending on transportation mode and jurisdiction.
Is dimethylmercury subject to particular regulations?
Dimethylmercury is subject to extensive regulatory controls under REACH, CLP, and mercury-specific legislation including the Minamata Convention restrictions. The substance requires registration for manufacture or import above threshold quantities and is subject to strict authorization procedures. National mercury regulations may impose additional restrictions on procurement, use, and disposal. Academic and research institutions typically require institutional review board approval and specialized safety protocols before allowing dimethylmercury use in research projects.
Where to buy dimethylmercury in Europe?
Dimethylmercury is available through OYSI as a specialized European distributor of chemical products, subject to strict regulatory compliance and customer qualification requirements. Due to its extreme toxicity classification (Acute Tox. 1), procurement requires demonstration of legitimate research needs, appropriate safety infrastructure, and regulatory compliance documentation. OYSI ensures proper packaging, documentation, and transport arrangements meeting all European chemical safety and mercury handling regulations. Availability may be subject to additional authorization requirements depending on intended use.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.