Mercury(2+) dithiocyanate
C2HgN2S2
mercury(2+) dithiocyanate
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Identification
- CAS Number
- 592-85-8
- EC Number
- 209-773-0
- UN Number
- 1646
- Index Number
- 080-002-00-6
- PubChem CID
- 11615
Physical-chemical properties
- Molecular Formula
- C2HgN2S2
- Molar Mass
- 316.80 g/mol
- IUPAC Name
- mercury(2+) dithiocyanate
Chemical Identifiers
- InChI
- InChI=1S/2CHNS.Hg/c2*2-1-3;/h2*3H;/q;;+2/p-2
- InChI Key
- GBZANUMDJPCQHY-UHFFFAOYSA-L
Overview
Mercury(2+) dithiocyanate (CAS 592-85-8) is an inorganic mercury compound with highly toxic properties and environmental persistence. This organometallic compound, also known by its IUPAC designation mercury(2+) dithiocyanate, represents one of the most hazardous mercury-based chemicals in industrial applications. With a molecular formula of C2HgN2S2 and molecular weight of 316.8 g/mol, this substance exhibits extreme toxicity across multiple exposure pathways. The compound carries the most severe hazard classifications including Acute Toxicity Category 1 and 2, along with specific target organ toxicity and acute aquatic toxicity ratings. The presence of both mercury and thiocyanate groups in its structure contributes to its potent biological activity and environmental impact. Unlike related mercury compounds such as dimethylmercury or (2-hydroxyphenoxy)-phenylmercury, mercury(2+) dithiocyanate demonstrates unique coordination chemistry through its sulfur-nitrogen bridging ligands. This structural arrangement influences both its physical properties and toxicological profile. Safety considerations are paramount when handling this material, as indicated by its GHS06, GHS08, and GHS09 pictograms and "Danger" signal word. The compound requires ADR Class 6.1 transportation protocols due to its poisonous nature. Its classification as both acutely and chronically toxic to aquatic environments necessitates stringent containment and disposal procedures. Primary industrial applications include specialized analytical chemistry procedures, certain electroplating processes, and as a reagent in organometallic synthesis where its unique coordination properties are specifically required. OYSI maintains availability of mercury(2+) dithiocyanate for qualified industrial customers requiring this specialized mercury compound for technical applications.
Safety & Classification
Acute Tox. 2 *; Acute Tox. 1; Acute Tox. 2 *; STOT RE 2 *; Aquatic Acute 1; Aquatic Chronic 1
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 1646 |
| ADR Class | 6.1 |
| Packing Group | II |
| Tunnel Code | D/E |
| Proper Shipping Name | Quecksilberthiocyanat |
| Marine Pollutant | No |
Frequently Asked Questions
What is mercury(2+) dithiocyanate?
Mercury(2+) dithiocyanate is an inorganic mercury compound with the chemical formula C2HgN2S2 and CAS number 592-85-8. This substance has a molecular weight of 316.8 g/mol and contains mercury in its +2 oxidation state bound to two thiocyanate groups. It is classified as extremely hazardous with acute toxicity properties and environmental dangers, requiring strict safety protocols for handling and use in professional applications.
What are the physicochemical properties of mercury(2+) dithiocyanate?
Mercury(2+) dithiocyanate is a solid inorganic compound that typically appears as a crystalline material. As a mercury-containing substance, it exhibits significant density and stability under normal conditions. The compound contains sulfur and nitrogen atoms coordinated to the central mercury ion, giving it distinct chemical reactivity. Its physicochemical properties are influenced by the presence of mercury, making it both chemically stable and highly toxic.
What is mercury(2+) dithiocyanate used for?
Mercury(2+) dithiocyanate is primarily used in specialized analytical chemistry applications and as a reagent in certain industrial processes. Due to its extreme toxicity and environmental hazards, its applications are heavily restricted and limited to controlled professional environments. The compound may be used in research laboratories for specific analytical procedures or as an intermediate in certain chemical syntheses, always under strict safety protocols and regulatory compliance.
How to handle mercury(2+) dithiocyanate safely?
Mercury(2+) dithiocyanate requires extreme safety precautions due to its Acute Tox. 1 and 2 classifications. Essential protective equipment includes chemical-resistant gloves, safety goggles, and respiratory protection in well-ventilated areas or fume hoods. Personnel must be trained in mercury handling procedures, and emergency protocols must be established. Work surfaces should be non-porous and easy to decontaminate. Avoid skin contact, inhalation, and ingestion completely.
How to store mercury(2+) dithiocyanate correctly?
Mercury(2+) dithiocyanate must be stored in a cool, dry, well-ventilated area away from incompatible materials and heat sources. Use original containers with tight-fitting lids in secondary containment systems to prevent spills. Storage areas should be clearly labeled, access-restricted, and equipped with emergency response materials. Keep away from acids, bases, and oxidizing agents. Regular inventory checks and container inspections are essential for safe storage management.
What to do in case of contact with mercury(2+) dithiocyanate?
Immediate action is critical for mercury(2+) dithiocyanate exposure due to its extreme toxicity. For skin contact, remove contaminated clothing and flush with water for at least 15 minutes. If inhaled, move to fresh air immediately. For eye contact, rinse thoroughly with water. Never induce vomiting if ingested. Seek immediate medical attention for any exposure, informing medical personnel of the specific mercury compound involved and bringing the safety data sheet.
How to dispose of mercury(2+) dithiocyanate appropriately?
Mercury(2+) dithiocyanate disposal requires specialized hazardous waste management due to its mercury content and extreme toxicity. The substance must be collected by licensed hazardous waste contractors and treated at approved facilities capable of handling mercury compounds. Never dispose of in regular waste, sewers, or environment. Container disposal also requires special handling. Consult local environmental authorities and follow all applicable mercury waste regulations for proper disposal procedures.
How to transport mercury(2+) dithiocyanate?
Mercury(2+) dithiocyanate is classified under ADR Class 6.1 (toxic substances) Packing Group II, requiring specialized transport procedures. Packaging must meet UN specifications with appropriate labeling including GHS06, GHS08, and GHS09 pictograms. Transport documents must identify the substance correctly, and drivers require hazardous materials certification. Only authorized carriers experienced in toxic substance transport should handle shipments, following all applicable dangerous goods regulations.
Is mercury(2+) dithiocyanate subject to specific regulations?
Mercury(2+) dithiocyanate is subject to extensive regulations including REACH registration requirements, CLP classification obligations, and mercury-specific restrictions under EU and international law. The substance falls under toxic substance regulations, environmental protection laws, and occupational health standards. Users must comply with notification requirements, exposure limits, and waste management regulations. Regular regulatory updates should be monitored as mercury compound restrictions continue to evolve globally.
Where to buy mercury(2+) dithiocyanate in Europe?
Mercury(2+) dithiocyanate is available through OYSI, a European distributor specializing in technical chemical products. As a restricted mercury compound, procurement requires proper documentation, end-use certification, and compliance with regulatory requirements. OYSI can provide guidance on regulatory compliance and proper handling procedures. Due to the substance's extreme hazards and regulatory restrictions, availability may be limited to qualified professional users with demonstrated legitimate applications.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.