Dilithium;peroxide
Li2O2
dilithium;peroxide
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Identification
- CAS Number
- 12031-80-0
- EC Number
- 234-758-0
- UN Number
- 1472
- PubChem CID
- 25489
Physical-chemical properties
- Molecular Formula
- Li2O2
- Molar Mass
- 45.90 g/mol
- IUPAC Name
- dilithium;peroxide
Chemical Identifiers
- InChI
- InChI=1S/2Li.O2/c;;1-2/q2*+1;-2
- InChI Key
- HPGPEWYJWRWDTP-UHFFFAOYSA-N
Overview
Dilithium peroxide (CAS 12031-80-0) is an inorganic lithium compound with strong oxidizing properties and high reactivity characteristics. This alkaline earth metal peroxide represents a significant class of oxidizing agents used across various industrial applications. With the molecular formula Li2O2 and a molecular weight of 45.9 g/mol, dilithium peroxide exhibits distinctive chemical behavior that makes it valuable in specialized technical processes. The compound is classified under ADR transport class 5.1, indicating its oxidizing nature and the specific handling protocols required during transportation and storage. Dilithium peroxide demonstrates strong oxidizing capabilities, making it reactive with organic materials and reducing agents. Its lithium-oxygen structure provides unique reactivity patterns compared to other metal peroxides in the same chemical family. The compound requires careful handling due to its oxidizing properties, though it does not carry specific GHS pictograms or signal words under standard classification systems. Storage must be conducted in dry conditions away from combustible materials and reducing agents to prevent unwanted reactions. Industrial applications of dilithium peroxide primarily focus on its role as an oxidizing agent in chemical synthesis processes and specialized battery technologies. The compound finds use in advanced lithium-air battery research, where its oxygen-release properties contribute to energy storage mechanisms. Additionally, it serves in certain bleaching processes and as an oxygen source in controlled chemical reactions, similar to applications found with other oxidizers like magnesium diperchlorate and barium(2+) dinitrate. OYSI provides dilithium peroxide to European industrial customers requiring high-quality oxidizing agents for their technical applications.
Safety & Classification
No Hazard Classification
This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.
Transport (ADR)
| UN Number | 1472 |
| ADR Class | 5.1 |
| Packing Group | II |
| Tunnel Code | E |
| Proper Shipping Name | Lithiumperoxid |
| Marine Pollutant | No |
Frequently Asked Questions
What is dilithium peroxide?
Dilithium peroxide is an inorganic chemical compound with the molecular formula Li2O2 and CAS number 12031-80-0. This lithium-based peroxide has a molecular weight of 45.9 g/mol and belongs to the family of alkali metal peroxides. It is characterized by its oxidizing properties and is classified as a Class 5.1 oxidizing substance under ADR transport regulations. The compound plays important roles in various industrial applications requiring controlled oxidation processes.
What are the physicochemical properties of dilithium peroxide?
Dilithium peroxide appears as a white to yellowish crystalline solid at room temperature. The compound is hygroscopic, meaning it readily absorbs moisture from air, and decomposes upon contact with water, releasing oxygen gas. It has a molecular weight of 45.9 g/mol and exhibits strong oxidizing properties. Like other lithium peroxides, it is thermally unstable at elevated temperatures and can decompose to form lithium oxide and oxygen.
What is dilithium peroxide used for?
Dilithium peroxide is primarily used as an oxidizing agent in various industrial applications and chemical synthesis processes. It serves as an oxygen source in specialized reactions and can be utilized in battery technologies and energy storage systems. The compound is also employed in research and development applications where controlled oxidation is required. Its unique properties make it valuable in certain pharmaceutical intermediates and specialty chemical manufacturing processes.
How to handle dilithium peroxide safely?
Dilithium peroxide should be handled with appropriate personal protective equipment including safety goggles, gloves, and protective clothing due to its oxidizing properties. Work should be conducted in well-ventilated areas away from combustible materials and ignition sources. Avoid contact with skin, eyes, and respiratory system. Use non-sparking tools and ensure proper grounding of equipment. Handle with care to prevent mechanical shock or friction, and always follow established safety protocols for oxidizing substances.
How to store dilithium peroxide correctly?
Dilithium peroxide must be stored in a cool, dry place away from heat sources, direct sunlight, and combustible materials. Keep containers tightly closed in their original packaging to prevent moisture absorption and contamination. Store separately from reducing agents, acids, and organic materials to prevent incompatible reactions. Ensure storage areas are well-ventilated and equipped with appropriate fire suppression systems. Regular inspection of containers for signs of deterioration is recommended.
What to do in case of contact with dilithium peroxide?
In case of skin contact with dilithium peroxide, immediately remove contaminated clothing and rinse the affected area with plenty of water for at least 15 minutes. For eye contact, flush thoroughly with water and seek immediate medical attention. If inhaled, move the person to fresh air and seek medical advice if breathing difficulties occur. In case of ingestion, do not induce vomiting and seek immediate medical attention. Always consult safety data sheets for specific emergency procedures.
How to dispose of dilithium peroxide appropriately?
Dilithium peroxide disposal must comply with local and national hazardous waste regulations as it is classified as an oxidizing substance. The compound should never be disposed of through regular waste streams or sewerage systems. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities may be neutralized under controlled conditions by qualified personnel, but this should only be done following established safety protocols and regulatory requirements.
How to transport dilithium peroxide?
Dilithium peroxide is classified under ADR Class 5.1 (Oxidizing substances) Packing Group II, requiring specific transport regulations. It must be packaged in UN-approved containers with proper labeling and documentation. Transport vehicles must carry appropriate emergency equipment and drivers require hazardous goods training. Segregation from incompatible materials during transport is mandatory. All shipments must comply with ADR/RID regulations for oxidizing substances and include proper shipping papers and emergency response information.
Is dilithium peroxide subject to particular regulations?
Dilithium peroxide is subject to various chemical regulations including REACH registration requirements in Europe. As an oxidizing substance, it falls under CLP (Classification, Labelling and Packaging) regulations for proper identification and handling. The compound is not currently listed as a Substance of Very High Concern (SVHC). Users must comply with occupational safety regulations and may need to implement risk management measures depending on usage quantities and applications in accordance with chemical safety legislation.
Where to buy dilithium peroxide in Europe?
Dilithium peroxide is available through specialized chemical distributors in Europe, including OYSI, which supplies various chemical products to European markets. When sourcing this oxidizing compound, ensure the supplier provides proper documentation including safety data sheets, certificates of analysis, and regulatory compliance information. Choose suppliers with experience in handling oxidizing substances and who can provide appropriate packaging and transport services in accordance with ADR regulations.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.