Dilithium;peroxide
Li2O2
dilithium;peroxide
Consulting for Dilithium;peroxide
Our experts support you with application, dosage, and compliance.
Identification
- CAS Number
- 12031-80-0
- EC Number
- 234-758-0
- UN Number
- 1472
- PubChem CID
- 25489
Physical-chemical properties
- Molecular Formula
- Li2O2
- Molar Mass
- 45.90 g/mol
- IUPAC Name
- dilithium;peroxide
Chemical Identifiers
- InChI
- InChI=1S/2Li.O2/c;;1-2/q2*+1;-2
- InChI Key
- HPGPEWYJWRWDTP-UHFFFAOYSA-N
Overview
Dilithium peroxide (CAS 12031-80-0) is an inorganic lithium compound with strong oxidizing properties and high reactivity toward moisture. This white crystalline solid, with the molecular formula Li2O2 and molecular weight of 45.9 g/mol, represents an important member of the alkali metal peroxides family. Unlike simple oxides, dilithium peroxide contains the characteristic peroxide ion (O2²⁻), which gives it distinctive chemical properties and makes it a valuable oxidizing agent in various industrial processes. The compound is classified under ADR Class 5.1 as an oxidizing substance, reflecting its ability to support combustion and potentially intensify fires. Dilithium peroxide exhibits exceptional reactivity with water, decomposing to form lithium hydroxide and oxygen gas. This reaction makes the compound highly moisture-sensitive and requires careful handling under dry conditions. The material demonstrates thermal stability at moderate temperatures but decomposes upon heating to release oxygen, a property that underlies many of its applications. Its oxidizing strength is comparable to other inorganic peroxides, though generally less aggressive than compounds like magnesium diperchlorate or barium(2+) dinitrate. Primary industrial applications include its use as an oxygen source in specialized breathing apparatus and emergency oxygen generation systems, where controlled decomposition provides reliable oxygen supply. The compound also serves as an oxidizing agent in organic synthesis reactions and finds application in certain pyrotechnic formulations where controlled oxygen release is required. OYSI maintains stock availability of dilithium peroxide for European customers requiring this specialized oxidizing compound for technical applications.
Safety & Classification
No Hazard Classification
This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.
Transport (ADR)
| UN Number | 1472 |
| ADR Class | 5.1 |
| Packing Group | II |
| Tunnel Code | E |
| Proper Shipping Name | Lithiumperoxid |
| Marine Pollutant | No |
Frequently Asked Questions
What is dilithium peroxide?
Dilithium peroxide is an inorganic chemical compound with the molecular formula Li2O2 and CAS number 12031-80-0. This lithium-based peroxide has a molecular weight of 45.9 g/mol and belongs to the class of alkali metal peroxides. It serves as an important chemical intermediate in various industrial applications, particularly in lithium chemistry and specialized manufacturing processes requiring controlled oxidizing properties.
What are the physicochemical properties of dilithium peroxide?
Dilithium peroxide is typically a white to off-white crystalline solid at room temperature. As an alkali metal peroxide, it exhibits strong oxidizing properties and is highly reactive with water, acids, and organic materials. The compound is hygroscopic, meaning it readily absorbs moisture from air. It has limited solubility in water but reacts vigorously upon contact, decomposing to form lithium hydroxide and oxygen gas.
What is dilithium peroxide used for?
Dilithium peroxide is primarily used as an oxidizing agent in specialized chemical synthesis and research applications. It serves as a precursor in lithium compound manufacturing and is utilized in advanced battery research, particularly for lithium-air battery technologies. The compound also finds applications in organic synthesis as a selective oxidizing reagent and in specialized industrial processes requiring controlled oxygen release under specific conditions.
How to handle dilithium peroxide safely?
Dilithium peroxide requires careful handling due to its strong oxidizing properties. Always wear appropriate personal protective equipment including safety goggles, chemical-resistant gloves, and protective clothing. Work in well-ventilated areas or under fume hoods to avoid inhalation of dust particles. Keep the substance away from heat sources, combustible materials, and reducing agents. Use non-sparking tools and avoid friction or impact during handling to prevent decomposition reactions.
How to store dilithium peroxide correctly?
Dilithium peroxide must be stored in tightly sealed containers in a cool, dry place away from direct sunlight and heat sources. Keep containers in secondary containment to prevent contamination from moisture. Store separately from incompatible materials including organic compounds, acids, reducing agents, and flammable substances. Ensure storage areas have adequate ventilation and temperature control. Regular inspection of containers for signs of deterioration or moisture ingress is recommended.
What to do in case of contact with dilithium peroxide?
In case of skin contact with dilithium peroxide, immediately remove contaminated clothing and flush the affected area with copious amounts of water for at least 15 minutes. For eye contact, rinse thoroughly with clean water and seek immediate medical attention. If inhaled, move the person to fresh air immediately. In case of ingestion, do not induce vomiting and seek immediate medical assistance. Always consult safety data sheets and contact emergency services when necessary.
How to dispose of dilithium peroxide properly?
Dilithium peroxide disposal must comply with local, national, and European waste regulations. The compound should be treated as hazardous chemical waste and disposed of through licensed hazardous waste contractors. Small quantities can be carefully neutralized by controlled reaction with water under professional supervision, but this should only be performed by trained personnel. Never dispose of dilithium peroxide through regular waste streams or drain systems.
How to transport dilithium peroxide?
Dilithium peroxide is classified under ADR transport regulations as Class 5.1 (Oxidizing substances), Group II. This classification requires specific packaging, labeling, and documentation for road transport within Europe. Packages must bear appropriate hazard labels and be constructed to prevent leakage and contamination. Transportation must be performed by certified carriers familiar with dangerous goods regulations, using appropriate vehicle equipment and emergency procedures.
Is dilithium peroxide subject to particular regulations?
Dilithium peroxide is subject to European chemical regulations including REACH (Registration, Evaluation, Authorization of Chemicals) and CLP (Classification, Labelling and Packaging) regulations. While not currently listed as a Substance of Very High Concern (SVHC), users must comply with standard chemical safety requirements including proper risk assessment, safety data sheet management, and worker protection measures as outlined in applicable European legislation.
Where to buy dilithium peroxide in Europe?
Dilithium peroxide is available through specialized chemical distributors in Europe, including OYSI, a trusted European distributor of technical chemicals. OYSI provides high-quality dilithium peroxide with proper documentation, safety data sheets, and regulatory compliance support. As a professional chemical supplier, OYSI ensures appropriate packaging, handling, and delivery procedures for this oxidizing compound throughout the European market.
Services for Dilithium;peroxide
Order Dilithium;peroxide
Fast delivery across Europe
SDS Service
Request Safety Data Sheet for Dilithium;peroxide
Technical Consulting
Application advice for Dilithium;peroxide
REACH Safety Data Sheet
REACH Compliance Service
Digital Product Passport
EU-compliant product documentation
ADR Consulting for Dilithium;peroxide
Dilithium;peroxide is a dangerous good. We support you with labeling, packaging, and transport documentation.
Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.