Lithium hydroxide

HLiO

lithium hydroxide

CAS1310-65-2

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Identification

CAS Number
1310-65-2
EC Number
215-183-4
UN Number
2680
PubChem CID
3939

Physical-chemical properties

Molecular Formula
HLiO
Molar Mass
24.00 g/mol
IUPAC Name
lithium hydroxide

Chemical Identifiers

InChI
InChI=1S/Li.H2O/h;1H2/q+1;/p-1
InChI Key
WMFOQBRAJBCJND-UHFFFAOYSA-M

Overview

Lithium hydroxide (CAS 1310-65-2) is an inorganic alkali compound with strong basic properties and high solubility in water. This white crystalline solid represents one of the most important lithium compounds in industrial chemistry, serving as a fundamental building block for numerous manufacturing processes. As a member of the alkali metal hydroxide family, lithium hydroxide exhibits characteristic basic behavior while offering unique properties that distinguish it from other hydroxides. The compound typically appears as a monohydrate (LiOH·H2O) under normal conditions, though anhydrous forms are also commercially available. Its molecular structure consists of lithium cations bonded to hydroxide anions, creating a highly polar compound that readily dissolves in polar solvents. The compound demonstrates excellent thermal stability and maintains its chemical integrity across a wide temperature range. Its strong alkaline nature makes it an effective neutralizing agent for acids, while its lithium content provides specific electrochemical properties valuable in energy storage applications. Unlike heavier alkali metal hydroxides or more complex compounds such as 4-methoxybenzoyl chloride, lithium hydroxide offers a combination of reactivity and selectivity that proves particularly useful in specialized chemical processes. Key industrial applications include battery manufacturing, particularly for lithium-ion batteries where it serves as a precursor for cathode materials, pharmaceutical synthesis as a reagent, and specialized chemical processing where controlled alkalinity is required. The compound also finds use in lubricant production and as a carbon dioxide absorbent in confined spaces. OYSI maintains reliable supply chains for lithium hydroxide to support diverse industrial requirements across European markets.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number2680
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping NameLithiumhydroxid, fest
Marine PollutantNo

Frequently Asked Questions

What is lithium hydroxide?

Lithium hydroxide is an inorganic chemical compound with the formula HLiO and CAS number 1310-65-2. This alkali metal hydroxide has a molecular weight of 24 g/mol and appears as a white crystalline solid. It is highly soluble in water and exhibits strong basic properties. Lithium hydroxide is commonly available in both anhydrous and monohydrate forms, with the latter being more stable under normal conditions.

What are the physicochemical properties of lithium hydroxide?

Lithium hydroxide is a white crystalline solid that is odorless and highly hygroscopic. It readily dissolves in water, forming a strongly alkaline solution with a pH above 12. The compound has a relatively low molecular weight of 24 g/mol and melts at approximately 462°C. It demonstrates excellent thermal stability and is non-volatile at room temperature, making it suitable for various industrial applications.

What is lithium hydroxide used for?

Lithium hydroxide is primarily used in lithium-ion battery production as a cathode material precursor, particularly for electric vehicle batteries. It serves as a key raw material in manufacturing lithium carbonate and other lithium compounds. Additional applications include CO2 absorption systems in submarines and spacecraft, ceramic and glass manufacturing, and as a catalyst in certain chemical processes. The growing electric vehicle market has significantly increased demand for this compound.

How to handle lithium hydroxide safely?

Lithium hydroxide requires careful handling due to its corrosive alkaline nature. Personnel should wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Ensure adequate ventilation in work areas and avoid generating dust. In case of spills, neutralize with dilute acid and clean thoroughly. Store handling equipment separately from incompatible materials and maintain emergency shower facilities nearby.

How to store lithium hydroxide correctly?

Lithium hydroxide should be stored in tightly sealed containers in a cool, dry environment away from moisture and humidity. Keep containers in well-ventilated areas and protect from direct sunlight and heat sources. Store separately from acids, organic materials, and aluminum to prevent dangerous reactions. Use moisture-proof packaging and consider desiccant materials to maintain product quality and prevent caking or degradation.

What to do in case of contact with lithium hydroxide?

Lithium hydroxide contact requires immediate action due to its corrosive properties. For skin contact, immediately flush the affected area with plenty of water for at least 15 minutes and remove contaminated clothing. In case of eye contact, rinse continuously with clean water and seek medical attention immediately. If inhaled, move the person to fresh air and provide respiratory support if needed. Always consult medical professionals for proper treatment.

How to dispose of lithium hydroxide appropriately?

Lithium hydroxide disposal must comply with local and national waste regulations as it is classified as hazardous waste. Neutralize small quantities carefully with dilute acid under controlled conditions before disposal. Large quantities should be handled by licensed waste management companies. Never dispose of lithium hydroxide in regular trash or pour down drains, as it can cause environmental damage and infrastructure corrosion.

How to transport lithium hydroxide?

Lithium hydroxide is classified under ADR Class 8 (corrosive substances) with Packing Group II, indicating moderate danger level. Transport requires appropriate UN-specification packaging designed for corrosive materials. Vehicles must display proper hazard labels and carry required documentation including safety data sheets. Drivers need ADR certification for dangerous goods transport. Ensure packages are properly sealed and protected from moisture during transit.

Is lithium hydroxide subject to specific regulations?

Lithium hydroxide is regulated under various European chemical legislation including REACH registration requirements and CLP classification standards. It is not currently listed as a Substance of Very High Concern (SVHC). Transport regulations classify it as a dangerous good under ADR Class 8. Users must comply with workplace safety regulations and maintain proper safety data sheets for occupational health and safety compliance.

Where to buy lithium hydroxide in Europe?

Lithium hydroxide is available through OYSI, a leading European distributor of technical chemicals serving industrial customers across Europe. OYSI provides reliable supply chains and technical support for various grades and quantities of lithium hydroxide. As a specialized chemical distributor, OYSI ensures proper handling, storage, and transportation compliance while offering competitive pricing and delivery services throughout European markets.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.