Dichlorosilane
Cl2H2Si
dichlorosilane
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Identification
- CAS Number
- 4109-96-0
- EC Number
- 223-888-3
- UN Number
- 2189
- PubChem CID
- 61330
Physical-chemical properties
- Molecular Formula
- Cl2H2Si
- Molar Mass
- 101.00 g/mol
- IUPAC Name
- dichlorosilane
Chemical Identifiers
- InChI
- InChI=1S/Cl2H2Si/c1-3-2/h3H2
- InChI Key
- MROCJMGDEKINLD-UHFFFAOYSA-N
Overview
Dichlorosilane (CAS 4109-96-0) is a silicon-based chemical compound with the molecular formula Cl2H2Si, characterized by its reactive chlorosilane properties and industrial applications in silicon chemistry. This colorless, highly reactive gas represents one of the fundamental chlorosilanes used extensively in modern chemical manufacturing and semiconductor industries. With a molecular weight of 101 g/mol, dichlorosilane serves as a crucial intermediate in silicon-based chemical processes, offering unique reactivity patterns that make it valuable for specialized industrial applications. The compound belongs to the broader family of silicon halides, sharing certain reactive characteristics with other halogenated compounds, though its silicon-chlorine bonds provide distinct chemical behavior compared to simpler halides like bromane or iodane. Dichlorosilane exhibits typical chlorosilane properties, including high reactivity with moisture and alcohols, leading to hydrolysis reactions that produce siloxanes and hydrogen chloride. The compound requires careful handling due to its reactive nature, necessitating anhydrous conditions and appropriate safety protocols during storage and processing. Its classification under ADR Class 2 reflects its gaseous nature and associated transportation considerations for industrial users. Primary industrial applications include its use as a precursor in the production of high-purity silicon for semiconductor manufacturing, where precise control of silicon deposition is critical. The compound also serves in the synthesis of specialized silicone polymers and as an intermediate in various organosilicon chemistry processes. Additionally, dichlorosilane finds application in surface modification treatments and as a reagent in chemical vapor deposition processes. OYSI provides dichlorosilane to European industrial customers, supporting semiconductor, specialty chemical, and advanced materials manufacturing sectors with reliable supply chain solutions.
Safety & Classification
No Hazard Classification
This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.
Transport (ADR)
| UN Number | 2189 |
| ADR Class | 2 |
| Packing Group | |
| Tunnel Code | B/D |
| Proper Shipping Name | Dichlorsilan, unter Druck verflüssigt |
| Marine Pollutant | No |
Frequently Asked Questions
What is dichlorosilane?
Dichlorosilane is an organosilicon compound with the chemical formula Cl2H2Si and molecular weight of 101 g/mol. This silicon-based chemical contains two chlorine atoms and two hydrogen atoms bonded to a central silicon atom. It serves as an important intermediate in silicon chemistry and semiconductor manufacturing processes. The compound is classified under CAS number 4109-96-0 and belongs to the family of chlorosilanes, which are essential building blocks in silicone production and various industrial applications.
What are the physicochemical properties of dichlorosilane?
Dichlorosilane is a colorless gas at room temperature with a pungent, acrid odor characteristic of chlorosilanes. The compound is highly reactive with water, undergoing rapid hydrolysis to form silicic acid and hydrogen chloride. It has a boiling point of approximately 8.2°C and is denser than air. The substance is not soluble in water due to its hydrolytic reaction, but it is miscible with organic solvents. Its reactivity makes it sensitive to moisture and atmospheric humidity.
What is dichlorosilane used for?
Dichlorosilane is primarily used as an intermediate in the production of high-purity silicon for semiconductor applications and solar cell manufacturing. It serves as a precursor for chemical vapor deposition (CVD) processes in electronics manufacturing. The compound is also utilized in the synthesis of various silicone polymers, organosilicon compounds, and silane coupling agents. Additionally, it finds applications in surface treatment processes and as a reducing agent in specialized chemical reactions within the semiconductor and materials science industries.
How to handle dichlorosilane safely?
Dichlorosilane requires careful handling due to its reactive nature and potential to release corrosive hydrogen chloride upon contact with moisture. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, and respiratory protection in well-ventilated areas. Handle only in dry, inert atmospheres using appropriate gas-tight equipment. Avoid contact with water, alcohols, and other reactive substances. Work in fume hoods or under inert gas conditions. Ensure emergency shower and eyewash stations are accessible, and have neutralizing agents readily available.
How to store dichlorosilane correctly?
Dichlorosilane must be stored in a cool, dry, well-ventilated area away from moisture and incompatible materials. Keep containers tightly sealed and protected from atmospheric humidity using inert gas blanketing when necessary. Store away from water, alcohols, strong bases, and oxidizing agents to prevent violent reactions. Maintain storage temperatures below 25°C and ensure adequate ventilation to prevent gas accumulation. Use corrosion-resistant containers and regularly inspect storage equipment for signs of degradation or leakage.
What to do in case of contact with dichlorosilane?
Immediate action is required following dichlorosilane exposure due to its corrosive nature when reacting with moisture. For skin contact, immediately remove contaminated clothing and flush affected areas with copious amounts of water for at least 15 minutes. In case of eye contact, rinse thoroughly with water and seek immediate medical attention. If inhaled, move the person to fresh air and provide oxygen if breathing difficulties occur. For ingestion, do not induce vomiting and seek immediate medical care. Always consult medical professionals promptly.
How to dispose of dichlorosilane properly?
Dichlorosilane disposal must comply with local and European waste regulations as a hazardous chemical waste. Small quantities can be carefully neutralized by controlled reaction with water or alcohols in a well-ventilated area, producing less hazardous silicic acid and hydrogen chloride solutions. Larger quantities require professional hazardous waste disposal services. Never dispose of untreated dichlorosilane in regular waste streams or sewers. Contact certified waste management companies specializing in reactive chemical disposal and ensure proper documentation of waste transfer.
How to transport dichlorosilane?
Dichlorosilane is classified as ADR Class 2 dangerous goods, requiring specialized transport procedures for hazardous gases. Transportation must comply with ADR regulations using appropriate gas cylinders or containers designed for reactive chemicals. Vehicles must carry proper placarding, emergency response information, and safety equipment. Drivers require ADR certification for dangerous goods transport. Ensure containers are properly secured, leak-tight, and protected from temperature extremes during transit. Professional logistics companies experienced in chemical transport should handle shipments to ensure regulatory compliance.
Is dichlorosilane subject to specific regulations?
Dichlorosilane is regulated under European REACH regulation requiring registration for commercial use, though it is not classified as a Substance of Very High Concern (SVHC). The compound must comply with CLP regulation for classification, labeling, and packaging requirements. Industrial users must implement appropriate risk management measures and maintain safety data sheets. Transport is governed by ADR dangerous goods regulations. Additionally, workplace exposure limits and industrial emissions may be subject to local environmental and occupational health regulations across European member states.
Where to buy dichlorosilane in Europe?
Dichlorosilane is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across the continent. OYSI provides reliable supply chains for semiconductor-grade and technical-grade dichlorosilane to electronics manufacturers, research institutions, and chemical processing companies. As a professional chemical distributor, OYSI ensures proper handling, documentation, and regulatory compliance for dichlorosilane shipments. Contact OYSI directly for specific product specifications, quantities, and delivery arrangements tailored to your industrial requirements and technical applications.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.