Dichloro(difluoro)methane

CCl2F2

dichloro(difluoro)methane

CAS75-71-8

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Identification

CAS Number
75-71-8
EC Number
200-893-9
UN Number
1028
PubChem CID
6391

Physical-chemical properties

Molecular Formula
CCl2F2
Molar Mass
120.91 g/mol
IUPAC Name
dichloro(difluoro)methane

Chemical Identifiers

InChI
InChI=1S/CCl2F2/c2-1(3,4)5
InChI Key
PXBRQCKWGAHEHS-UHFFFAOYSA-N

Overview

Dichloro(difluoro)methane (CAS 75-71-8) is a chlorofluorocarbon refrigerant with excellent thermodynamic properties and chemical stability under normal conditions. This halogenated hydrocarbon, commonly known as CFC-12 or Freon-12, belongs to the family of chlorofluorocarbons that revolutionized refrigeration technology in the mid-20th century. With its molecular formula CCl2F2 and molecular weight of 120.91 g/mol, dichloro(difluoro)methane exhibits unique physical and chemical characteristics that made it highly valuable in various industrial applications. The compound appears as a colorless gas at ambient temperature and pressure, with a boiling point of approximately -29.8°C, making it ideal for refrigeration cycles. As a Class 2 substance under ADR regulations, dichloro(difluoro)methane is classified as a compressed gas and requires appropriate handling procedures during transportation and storage. Unlike more reactive gases such as nitrous oxide, this compound demonstrates remarkable chemical inertness under normal operating conditions, contributing to its historical widespread use. The substance is non-flammable and exhibits low acute toxicity, though proper ventilation is essential due to its potential to displace oxygen in confined spaces. Industrially, dichloro(difluoro)methane has been primarily utilized as a refrigerant in commercial and residential cooling systems, as a propellant in aerosol applications, and as a blowing agent in foam manufacturing. However, due to its ozone depletion potential, its production and use have been significantly restricted under the Montreal Protocol, leading to phase-out programs in favor of more environmentally friendly alternatives. OYSI maintains technical expertise in handling regulated chemical substances and can provide guidance on appropriate alternatives and compliance requirements for customers requiring chlorofluorocarbon-related solutions.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number1028
ADR Class2
Packing Group
Tunnel CodeC/E
Proper Shipping NameDichlordifluormethan, unter Druck verflüssigt
Marine PollutantNo

Frequently Asked Questions

What is dichloro(difluoro)methane?

Dichloro(difluoro)methane is a chlorofluorocarbon (CFC) compound with the chemical formula CCl2F2 and CAS number 75-71-8. Also known as CFC-12 or Freon-12, this synthetic halogenated hydrocarbon has a molecular weight of 120.91 g/mol. It belongs to the family of refrigerants and was historically widely used in various industrial applications before environmental regulations limited its use due to ozone depletion concerns.

What are the physicochemical properties of dichloro(difluoro)methane?

Dichloro(difluoro)methane is a colorless gas at room temperature with a faint, sweet odor. It has excellent chemical stability and low reactivity under normal conditions. The compound is practically insoluble in water but soluble in organic solvents. It exhibits low toxicity, is non-flammable, and has a boiling point of approximately -29.8°C. These properties made it particularly suitable for refrigeration applications and aerosol propellants in the past.

What is dichloro(difluoro)methane used for?

Dichloro(difluoro)methane is primarily used as a refrigerant in industrial cooling systems and older air conditioning units. It serves as a blowing agent for foam production, particularly in insulation materials. The compound is also utilized as a cleaning solvent for precision equipment and in specialized laboratory applications. However, due to environmental regulations restricting ozone-depleting substances, its use has been significantly reduced and replaced by more environmentally friendly alternatives in most applications.

How to handle dichloro(difluoro)methane safely?

Dichloro(difluoro)methane should be handled in well-ventilated areas or under fume extraction systems to prevent inhalation. Wear appropriate personal protective equipment including safety goggles, chemical-resistant gloves, and protective clothing. Avoid skin and eye contact, and prevent vapor accumulation in confined spaces. Use proper lifting techniques when handling containers, and ensure all equipment is suitable for pressurized gases. Keep ignition sources away and follow established procedures for compressed gas handling.

How to store dichloro(difluoro)methane correctly?

Dichloro(difluoro)methane should be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers upright and secure to prevent falling or damage. Store away from incompatible materials such as strong oxidizing agents and alkali metals. Ensure storage areas have appropriate ventilation systems and gas detection equipment. Regularly inspect containers for signs of damage or leakage, and maintain storage temperatures within recommended ranges to prevent excessive pressure buildup.

What to do in case of contact with dichloro(difluoro)methane?

In case of skin contact with dichloro(difluoro)methane, immediately remove contaminated clothing and flush the affected area with plenty of water for at least 15 minutes. For eye contact, rinse thoroughly with clean water and seek medical attention. If inhaled, move the person to fresh air immediately and monitor breathing. In case of high-concentration exposure causing symptoms like dizziness or difficulty breathing, seek immediate medical attention. Remove the person from the exposure area and provide supportive care as needed.

How to dispose of dichloro(difluoro)methane appropriately?

Dichloro(difluoro)methane must be disposed of as hazardous waste through authorized waste management companies specializing in CFC recovery and destruction. Due to its ozone-depleting potential, it cannot be released into the atmosphere and requires specialized treatment facilities. Contact certified waste disposal contractors who can safely collect, transport, and destroy the material according to environmental regulations. Always follow local and national waste disposal regulations and maintain proper documentation of disposal activities.

How to transport dichloro(difluoro)methane?

Dichloro(difluoro)methane is classified under ADR Class 2 for transport as a compressed gas. It must be transported in appropriate pressure vessels designed for gas transport, properly labeled and documented according to dangerous goods regulations. Use authorized carriers experienced in hazardous materials transport. Ensure proper vehicle ventilation, appropriate emergency equipment, and trained personnel. Follow all ADR requirements for packaging, marking, labeling, and documentation during transport operations.

Is dichloro(difluoro)methane subject to specific regulations?

Dichloro(difluoro)methane is subject to strict environmental regulations as an ozone-depleting substance under the Montreal Protocol and EU regulations. It falls under REACH registration requirements and is heavily restricted in the European Union. The substance is prohibited for most new applications and can only be used for essential purposes with specific authorizations. Companies must comply with CLP classification requirements and follow strict controls on production, import, export, and use of this controlled substance.

Where to buy dichloro(difluoro)methane in Europe?

Dichloro(difluoro)methane is available through OYSI, a specialized European distributor of technical chemicals. As a controlled substance, it requires proper licensing and documentation for purchase and use. OYSI can provide guidance on regulatory compliance and ensure proper handling procedures. Due to strict environmental regulations, availability may be limited to essential applications only. Contact OYSI directly to discuss your specific requirements and verify current availability and regulatory compliance for your intended application.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.