Dichloro(2-methylpropyl)alumane

C4H9AlCl2

dichloro(2-methylpropyl)alumane

CAS1888-87-5

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Identification

CAS Number
1888-87-5
EC Number
217-563-5
UN Number
3394
PubChem CID
74679

Physical-chemical properties

Molecular Formula
C4H9AlCl2
Molar Mass
155.00 g/mol
IUPAC Name
dichloro(2-methylpropyl)alumane

Chemical Identifiers

InChI
InChI=1S/C4H9.Al.2ClH/c1-4(2)3;;;/h4H,1H2,2-3H3;;2*1H/q;+2;;/p-2
InChI Key
NMVXHZSPDTXJSJ-UHFFFAOYSA-L

Overview

Dichloro(2-methylpropyl)alumane (CAS 1888-87-5) is an organoaluminum compound with pyrophoric properties and high reactivity toward moisture and oxygen. This specialized organoaluminum reagent belongs to the family of alkylaluminum dichlorides, featuring a branched isobutyl group attached to an aluminum center along with two chlorine atoms. The compound exhibits the characteristic high reactivity of organoaluminum species, making it spontaneously combustible in air and violently reactive with water. Its molecular structure, containing the sterically hindered 2-methylpropyl group, influences both its reactivity profile and synthetic utility compared to linear alkyl derivatives. As an important intermediate in organometallic chemistry, dichloro(2-methylpropyl)alumane serves as a valuable alkylating agent and catalyst precursor. The compound's unique reactivity stems from the polarized aluminum-carbon bond and the Lewis acidic nature of the aluminum center. Like other members of the organoaluminum family such as tris(2-methylpropyl)alumane, it requires careful handling under inert atmosphere conditions due to its extreme air and moisture sensitivity. The compound finds application in specialized organic synthesis as an alkylating reagent, particularly in reactions requiring controlled introduction of isobutyl groups. It also serves as a precursor for preparing other organoaluminum compounds and as a co-catalyst component in polymerization processes. Additionally, dichloro(2-methylpropyl)alumane is utilized in the synthesis of aluminum-containing materials and as a reducing agent in selective organic transformations. OYSI provides dichloro(2-methylpropyl)alumane to research institutions and industrial clients requiring high-purity organoaluminum reagents for advanced chemical applications.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number3394
ADR Class4.2
Packing GroupI
Tunnel CodeB/E
Proper Shipping NameIsobutylaluminiumdichlorid, flüssig, pyrophor
Marine PollutantNo

Frequently Asked Questions

What is dichloro(2-methylpropyl)alumane?

Dichloro(2-methylpropyl)alumane is an organoaluminum compound with the molecular formula C4H9AlCl2 and CAS number 1888-87-5. This chemical features an aluminum atom bonded to two chlorine atoms and a 2-methylpropyl group (isobutyl group). With a molecular weight of 155 g/mol, it belongs to the family of alkylaluminum chlorides used primarily as catalysts and intermediates in organic synthesis.

What are the physicochemical properties of dichloro(2-methylpropyl)alumane?

Dichloro(2-methylpropyl)alumane is typically a colorless to pale yellow liquid at room temperature with a characteristic sharp, pungent odor. As an organoaluminum compound, it is highly reactive with moisture and air, readily hydrolyzing in the presence of water to form aluminum hydroxide and hydrochloric acid. It is soluble in non-polar organic solvents but reacts violently with protic solvents.

What is dichloro(2-methylpropyl)alumane used for?

Dichloro(2-methylpropyl)alumane is primarily used as a catalyst in polymerization reactions, particularly in the production of polyolefins and other synthetic polymers. It serves as an alkylating agent in organic synthesis and as an intermediate in the preparation of other organoaluminum compounds. The compound is also utilized in specialty chemical manufacturing processes requiring selective aluminum-based catalysis.

How to handle dichloro(2-methylpropyl)alumane safely?

Dichloro(2-methylpropyl)alumane must be handled under strict inert atmosphere conditions using appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods due to its reactive nature. Avoid contact with moisture, air, and incompatible materials. Emergency eyewash and safety shower facilities should be readily accessible.

How to store dichloro(2-methylpropyl)alumane correctly?

Dichloro(2-methylpropyl)alumane must be stored in tightly sealed containers under inert gas atmosphere (nitrogen or argon) to prevent hydrolysis and oxidation. Storage areas should be cool, dry, and well-ventilated, away from sources of moisture, heat, and ignition. The compound should be kept separate from water, alcohols, acids, and oxidizing agents to prevent dangerous reactions.

What to do in case of contact with dichloro(2-methylpropyl)alumane?

In case of skin contact with dichloro(2-methylpropyl)alumane, immediately remove contaminated clothing and flush the affected area with copious amounts of water for at least 15 minutes. For eye contact, rinse immediately with water and seek medical attention. If inhaled, move the person to fresh air and seek medical help. Never use water directly on spills due to violent reaction potential.

How to dispose of dichloro(2-methylpropyl)alumane properly?

Dichloro(2-methylpropyl)alumane must be disposed of according to local and national hazardous waste regulations as a reactive chemical waste. The compound should be carefully neutralized by trained professionals using appropriate inert solvents before disposal. Contact licensed hazardous waste disposal companies for proper treatment. Never dispose of this material down drains or with regular waste due to its reactive properties.

How to transport dichloro(2-methylpropyl)alumane?

Dichloro(2-methylpropyl)alumane is classified under ADR Class 4.2 (substances liable to spontaneous combustion) with Packing Group I, indicating high danger. Transportation requires special packaging that prevents contact with air and moisture, proper labeling with Class 4.2 hazard labels, and compliance with dangerous goods transport regulations. Only qualified carriers experienced with pyrophoric materials should handle transportation.

Is dichloro(2-methylpropyl)alumane subject to specific regulations?

Dichloro(2-methylpropyl)alumane is subject to various chemical regulations including REACH registration requirements in Europe for commercial use. While not classified as an SVHC (Substance of Very High Concern), it falls under general chemical safety regulations due to its reactive nature. Users must comply with workplace safety standards, transportation regulations (ADR Class 4.2), and local environmental protection requirements.

Where to buy dichloro(2-methylpropyl)alumane in Europe?

Dichloro(2-methylpropyl)alumane is available through OYSI, a specialized European distributor of technical chemicals and organoaluminum compounds. As experts in handling reactive chemicals, OYSI provides proper packaging, documentation, and technical support for safe delivery across Europe. Contact OYSI directly to discuss specific requirements, quantities, and delivery options for this specialized organoaluminum compound.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.