Copper;methanesulfonic acid

CH4CuO3S

copper;methanesulfonic acid

CAS54253-62-2
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
54253-62-2
EC Number
405-400-2
UN Number
3077
Index Number
029-008-00-2
PubChem CID
3085058

Physical-chemical properties

Molecular Formula
CH4CuO3S
Molar Mass
159.65 g/mol
IUPAC Name
copper;methanesulfonic acid

Chemical Identifiers

InChI
InChI=1S/CH4O3S.Cu/c1-5(2,3)4;/h1H3,(H,2,3,4);
InChI Key
SDFNZYMSEOUVIF-UHFFFAOYSA-N

Overview

Copper methanesulfonate (CAS 54253-62-2) is an organometallic copper salt compound with high solubility and electroplating applications. This specialized copper compound represents a significant advancement in metal salt chemistry, combining the conductive properties of copper with the stability and solubility characteristics of methanesulfonic acid. The molecular structure CH4CuO3S creates a highly efficient copper source that dissolves readily in aqueous solutions, making it particularly valuable for industrial electrochemical processes. With a molecular weight of 159.65 g/mol, copper methanesulfonate offers superior performance compared to traditional copper sulfates in many applications requiring precise copper deposition and controlled ion release. The compound exhibits notable safety considerations, classified under multiple hazard categories including acute toxicity (Category 4), serious eye damage, and significant aquatic toxicity for both acute and chronic exposure. These classifications necessitate proper handling protocols and environmental containment measures during industrial use. The presence of GHS pictograms GHS07, GHS05, and GHS09 indicates requirements for personal protective equipment and specialized storage conditions. Its ADR Class 9 designation reflects its status as a miscellaneous dangerous substance requiring careful transportation protocols. Primary industrial applications include advanced electroplating operations, where copper methanesulfonate provides superior throwing power and deposit quality compared to conventional copper sources. The compound also serves critical roles in printed circuit board manufacturing and specialized metal finishing processes. Unlike related compounds such as zinc sulfate, copper methanesulfonate offers enhanced bath stability and improved current efficiency in electrochemical applications. OYSI maintains reliable supply chains for copper methanesulfonate, supporting European industrial customers with consistent quality and technical expertise.

Safety & Classification

Danger
Classification:

Acute Tox. 4 *; Eye Dam. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H302

Harmful if swallowed.

H318

Causes serious eye damage.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameKupfer(II)-methansulfonat
Marine PollutantNo

Frequently Asked Questions

What is copper methanesulfonic acid?

Copper methanesulfonic acid is an organometallic chemical compound with the molecular formula CH4CuO3S and CAS number 54253-62-2. This substance has a molecular weight of 159.65 g/mol and consists of copper complexed with methanesulfonic acid. It is classified as a hazardous substance under GHS regulations with acute toxicity, eye damage, and aquatic toxicity properties. The compound is primarily used in industrial applications requiring copper-based chemistry and electroplating processes.

What are the physicochemical properties of copper methanesulfonic acid?

Copper methanesulfonic acid is typically a crystalline solid at room temperature with characteristic copper-based coloration. The compound has a molecular weight of 159.65 g/mol and contains one copper atom per molecule. It generally exhibits good water solubility due to the presence of the methanesulfonic acid moiety. The substance is stable under normal conditions but requires careful handling due to its corrosive nature and potential to cause severe eye damage.

What is copper methanesulfonic acid used for?

Copper methanesulfonic acid is primarily used in electroplating applications for depositing copper coatings on various substrates. It serves as an electrolyte in copper plating baths, providing excellent throwing power and bright deposits. The compound is also utilized in electronic manufacturing for printed circuit board production and in metal finishing industries. Additionally, it finds applications in catalysis and as a precursor for other copper-containing compounds in specialized chemical processes.

How to handle copper methanesulfonic acid safely?

Copper methanesulfonic acid requires careful handling with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Workers must wear face protection due to the substance's eye damage classification (GHS05 pictogram). Ensure adequate ventilation to prevent inhalation exposure, as it carries acute toxicity warnings. Always work in well-ventilated areas or fume hoods, avoid skin and eye contact, and have emergency eyewash stations readily available in the work area.

How to store copper methanesulfonic acid correctly?

Copper methanesulfonic acid should be stored in tightly sealed, corrosion-resistant containers in a cool, dry, and well-ventilated area. Keep containers away from incompatible materials and heat sources. Due to its aquatic toxicity classification, prevent environmental release during storage. Store in original labeled containers with proper secondary containment to prevent spills. Maintain storage areas with appropriate temperature control and ensure containers are regularly inspected for signs of corrosion or damage.

What to do in case of contact with copper methanesulfonic acid?

Copper methanesulfonic acid contact requires immediate action due to its corrosive properties and eye damage potential. For eye contact, rinse immediately with plenty of water for at least 15 minutes and seek medical attention urgently. For skin contact, remove contaminated clothing and wash affected area thoroughly with soap and water. If ingested, rinse mouth and seek immediate medical attention - do not induce vomiting. In case of inhalation, move to fresh air and seek medical advice if respiratory irritation occurs.

How to dispose of copper methanesulfonic acid properly?

Copper methanesulfonic acid disposal must comply with local and national hazardous waste regulations due to its toxicity and environmental impact. The substance cannot be disposed of in regular waste streams due to its aquatic toxicity classification. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Neutralization may be required before disposal, but this should only be performed by qualified personnel. Always consult local environmental authorities for specific disposal requirements and approved disposal facilities.

How to transport copper methanesulfonic acid?

Copper methanesulfonic acid is classified as ADR Class 9 (Miscellaneous dangerous goods), Packing Group III for transportation purposes. This classification requires specific packaging, labeling, and documentation during transport. Packages must display appropriate hazard labels and UN identification numbers. Transport vehicles need proper placarding and drivers require ADR certification. The substance must be packaged in approved containers that prevent leakage and comply with packaging group III requirements for safe transportation.

Is copper methanesulfonic acid subject to specific regulations?

Copper methanesulfonic acid is subject to various chemical safety regulations including REACH registration requirements in Europe and CLP classification obligations. The substance is not identified as a Substance of Very High Concern (SVHC) under REACH. However, its hazard classifications require compliance with occupational safety regulations, environmental protection laws, and transportation regulations. Users must maintain safety data sheets, implement risk management measures, and comply with notification requirements for industrial use and environmental release prevention.

Where to buy copper methanesulfonic acid in Europe?

Copper methanesulfonic acid is available through OYSI, a European distributor specializing in technical chemical products. OYSI provides reliable supply chains across European markets with proper documentation, safety data sheets, and regulatory compliance support. As a professional chemical distributor, OYSI ensures product quality, appropriate packaging, and adherence to transportation regulations. Contact OYSI directly for availability, technical specifications, and delivery options to your specific European location while ensuring all regulatory requirements are met.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.