Chloromethane

CH3Cl

chloromethane

CAS74-87-3
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS04 Gefahrensymbol: Unter Druck stehende Gase – Gasflasche
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
Danger

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Identification

CAS Number
74-87-3
EC Number
200-817-4
UN Number
1063
Index Number
602-001-00-7
PubChem CID
6327

Physical-chemical properties

Molecular Formula
CH3Cl
Molar Mass
50.49 g/mol
IUPAC Name
chloromethane

Chemical Identifiers

InChI
InChI=1S/CH3Cl/c1-2/h1H3
InChI Key
NEHMKBQYUWJMIP-UHFFFAOYSA-N

Overview

Chloromethane (CAS 74-87-3) is a halogenated hydrocarbon gas with high flammability and significant industrial applications in chemical synthesis. This single-carbon halomethane, also known by its IUPAC name chloromethane, represents one of the simplest organochlorine compounds with the molecular formula CH3Cl and a molecular mass of 50.49 g/mol. As a colorless gas at room temperature, chloromethane exhibits properties typical of light alkyl halides, sharing certain characteristics with other simple halogenated compounds used in industrial processes. The substance presents significant safety considerations due to its classification as a flammable gas (Category 1), pressurized gas, suspected carcinogen (Category 2), and specific target organ toxicant with repeated exposure (Category 2). The danger signal word and associated GHS pictograms GHS02, GHS04, and GHS08 reflect these hazardous properties, requiring appropriate handling protocols and safety measures during storage, transport, and use. Its ADR classification as Class 2 dangerous goods further emphasizes the need for specialized logistics considerations. In industrial applications, chloromethane serves primarily as a methylating agent in organic synthesis, facilitating the introduction of methyl groups into various chemical structures. The compound finds significant use in the production of silicone polymers and as an intermediate in pharmaceutical manufacturing. Additionally, it functions as a solvent in specialized chemical processes, though its use has become more restricted due to environmental and health concerns. Like carbon monoxide, chloromethane requires careful handling due to its toxic properties, making proper ventilation and detection systems essential in industrial settings. OYSI maintains availability of chloromethane for qualified industrial customers with appropriate handling capabilities and regulatory compliance.

Safety & Classification

Danger
Classification:

Flam. Gas 1; Press. Gas; Carc. 2; STOT RE 2 *

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H220

Extremely flammable gas.

H351

Suspected of causing cancer.

H373

May cause damage to organs through prolonged or repeated exposure.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Transport (ADR)

UN Number1063
ADR Class2
Packing Group
Tunnel CodeB/D
Proper Shipping NameMethylchlorid, unter Druck verflüssigt
Marine PollutantNo

Frequently Asked Questions

What is chloromethane?

Chloromethane is a halogenated hydrocarbon with the molecular formula CH3Cl and CAS number 74-87-3. This chemical compound has a molecular weight of 50.49 g/mol and exists as a flammable gas under normal conditions. It belongs to the methyl halide family and is classified as a pressurized gas with significant safety considerations including flammability and potential carcinogenic properties.

What are the physicochemical properties of chloromethane?

Chloromethane is a colorless gas at room temperature with a faintly sweet odor. It has a boiling point of -24°C and is moderately soluble in water. The compound is highly flammable and exists as a pressurized gas under standard storage conditions. Its vapor density is higher than air, causing it to accumulate in low-lying areas when released.

What is chloromethane used for?

Chloromethane serves primarily as a methylating agent in organic synthesis and as an intermediate in the production of silicones, methyl cellulose, and quaternary ammonium compounds. It is also used in the manufacture of butyl rubber, agricultural chemicals, and foam blowing agents. Additionally, it finds applications in the electronics industry for specialized cleaning processes and as a solvent in certain industrial applications.

How to handle chloromethane safely?

Chloromethane requires strict safety protocols including use of appropriate respiratory protection, gas-tight chemical protective clothing, and safety goggles. Work should be conducted in well-ventilated areas or under fume extraction systems to prevent accumulation. Eliminate all ignition sources as the substance is highly flammable. Personnel should be trained in gas leak detection and emergency response procedures due to its pressurized gas nature.

How to store chloromethane correctly?

Chloromethane must be stored in pressurized gas cylinders designed for flammable gases, kept in cool, dry, well-ventilated areas away from heat sources and ignition. Storage areas should be equipped with gas detection systems and appropriate fire suppression equipment. Keep containers upright and secured, avoiding storage near incompatible materials such as strong oxidizers, metals, and alkaline substances.

What to do in case of contact with chloromethane?

Chloromethane exposure requires immediate evacuation from the contaminated area to fresh air and removal of contaminated clothing. For inhalation exposure, provide artificial respiration if breathing has stopped and seek immediate medical attention. In case of skin or eye contact, flush with plenty of water for at least 15 minutes. Due to its potential carcinogenic properties, all exposures should be reported and medically evaluated promptly.

How to dispose of chloromethane appropriately?

Chloromethane disposal must comply with local and national hazardous waste regulations as it is classified as dangerous waste. The substance should be collected in appropriate pressure-resistant containers and handed over to licensed hazardous waste disposal companies. Incineration at high temperatures in specialized facilities is typically required. Empty cylinders must be properly degassed and handled according to manufacturer specifications before disposal.

How to transport chloromethane?

Chloromethane is classified under ADR Class 2 (Gases) for transportation purposes. It must be transported in DOT-approved pressure cylinders with proper labeling including flammable gas and health hazard markings. Transport vehicles require appropriate placarding, emergency response information, and compliance with routing restrictions. Drivers must hold valid hazardous materials transportation certifications and carry emergency response documentation.

Is chloromethane subject to specific regulations?

Chloromethane is regulated under multiple frameworks including REACH registration requirements, CLP classification as Flammable Gas Category 1, Carcinogen Category 2, and STOT RE Category 2. It is subject to workplace exposure limits, emissions controls, and may require special authorizations for certain uses. The substance requires safety data sheets, risk assessments, and compliance with industrial emissions directives in European operations.

Where to buy chloromethane in Europe?

Chloromethane is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across the continent. As a regulated substance requiring proper handling expertise, procurement should only be through qualified chemical distributors who can provide appropriate documentation, safety data sheets, and technical support. Professional buyers must demonstrate proper storage facilities and handling capabilities for pressurized flammable gases.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.