Vinyl chloride

C2H3Cl

vinyl chloride

CAS75-01-4
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS04 Gefahrensymbol: Unter Druck stehende Gase – Gasflasche
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
Danger

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Identification

CAS Number
75-01-4
EC Number
200-831-0
UN Number
1086
Index Number
602-002-00-2
PubChem CID
6338

Physical-chemical properties

Molecular Formula
C2H3Cl
Molar Mass
62.50 g/mol
IUPAC Name
vinyl chloride

Chemical Identifiers

InChI
InChI=1S/C2H3Cl/c1-2-3/h2H,1H2
InChI Key
BZHJMEDXRYGGRV-UHFFFAOYSA-N

Overview

Vinyl chloride (CAS 75-01-4) is a colorless flammable gas primarily used as a monomer for polyvinyl chloride (PVC) production in industrial manufacturing processes. This important industrial chemical serves as the fundamental building block for one of the world's most widely used plastics. As a member of the halogenated alkene family, vinyl chloride shares structural similarities with other unsaturated compounds like bromoethene, though its chlorine substitution gives it distinct reactivity patterns crucial for polymerization processes. The compound exists as a pressurized gas under normal conditions, requiring specialized handling and storage systems to maintain its liquid state for transportation and processing. The substance presents significant safety considerations due to its flammable nature and carcinogenic classification. Its flammable gas properties demand strict fire prevention measures, while its pressurized gas characteristics require appropriate containment systems to prevent dangerous releases. Most critically, vinyl chloride is classified as a Category 1A carcinogen, necessitating stringent exposure controls and comprehensive safety protocols in industrial environments. Primary industrial applications center on PVC polymer production, where vinyl chloride undergoes controlled polymerization to create materials for construction, packaging, and automotive industries. The chemical also finds use in specialized organic synthesis processes and as an intermediate in certain pharmaceutical manufacturing pathways. Unlike simpler compounds such as buta-1,3-diene used in rubber production, vinyl chloride's chlorinated structure makes it particularly valuable for creating durable, weather-resistant plastic materials. Due to its hazardous classification and specialized handling requirements, vinyl chloride availability through OYSI is subject to strict regulatory compliance and customer qualification processes for approved industrial applications.

Safety & Classification

Danger
Classification:

Flam. Gas 1; Press. Gas; Carc. 1A

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H220

Extremely flammable gas.

H350

May cause cancer.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Transport (ADR)

UN Number1086
ADR Class2
Tunnel CodeB/D
Proper Shipping NameVinylchlorid, stabilisiert, unter Druck verflüssigt
Marine PollutantNo

Frequently Asked Questions

What is vinyl chloride?

Vinyl chloride is a colorless flammable gas with the chemical formula C2H3Cl and molecular weight of 62.5 g/mol. It is classified as a Class 1A carcinogen and flammable gas under GHS regulations. This organochlorine compound exists as a pressurized gas at room temperature and is primarily used as a monomer in polymer production. Its CAS number is 75-01-4 and it requires careful handling due to its high toxicity and fire hazard potential.

What are the physicochemical properties of vinyl chloride?

Vinyl chloride is a colorless gas at room temperature with a slightly sweet odor at high concentrations. It has a boiling point of -13.4°C and exists under pressure in containers. The compound is slightly soluble in water but readily soluble in organic solvents like ethanol and ether. It polymerizes easily, especially when exposed to light, heat, or catalysts, and forms explosive mixtures with air in concentrations between 3.6% and 33% by volume.

What is vinyl chloride used for?

Vinyl chloride is primarily used as a monomer for producing polyvinyl chloride (PVC), one of the world's most widely used plastics. PVC applications include pipes, fittings, profiles for windows and doors, flooring, cables, medical devices, and packaging materials. Additionally, vinyl chloride serves as an intermediate in the synthesis of other chemicals and as a refrigerant in some specialized applications, though its use is heavily regulated due to carcinogenic properties.

How to handle vinyl chloride safely?

Vinyl chloride requires strict safety measures including use of supplied-air respiratory protection, chemical-resistant gloves, and full protective clothing. Work must be conducted in well-ventilated areas or under local exhaust ventilation systems. Avoid all ignition sources as it forms explosive mixtures with air. Personnel should be trained in emergency procedures and health monitoring programs. Never work alone when handling this substance, and ensure emergency shower and eyewash facilities are readily accessible.

How to store vinyl chloride correctly?

Vinyl chloride must be stored in pressure-resistant containers in cool, well-ventilated areas away from heat, sparks, and incompatible materials. Storage areas should be equipped with gas detection systems and emergency ventilation. Keep containers upright and protect from physical damage. Separate from oxidizing agents, acids, and alkalis. Storage facilities must comply with local fire codes and be designed to prevent vapor accumulation. Regular inspection of containers and safety systems is essential.

What to do in case of contact with vinyl chloride?

Immediate evacuation from the exposure area to fresh air is critical in case of inhalation exposure. Remove contaminated clothing and flush affected skin with plenty of water for at least 15 minutes. For eye contact, irrigate with clean water for 15 minutes while holding eyelids open. Seek immediate medical attention in all cases of exposure. Do not induce vomiting if ingested. Provide oxygen if breathing is difficult and begin CPR if necessary while awaiting emergency medical services.

How to dispose of vinyl chloride properly?

Vinyl chloride disposal must comply with local, national, and international hazardous waste regulations as it is classified as hazardous waste. Thermal destruction in approved high-temperature incineration facilities is the preferred disposal method. Never release to atmosphere, sewers, or groundwater. Small quantities should be allowed to evaporate in well-ventilated areas under controlled conditions. Contact licensed waste disposal companies and obtain proper waste tracking documentation for all disposal activities.

How to transport vinyl chloride?

Vinyl chloride is classified under ADR Class 2 (gases) for transport purposes and must be shipped in UN-approved pressure vessels designed for flammable gases. Transportation requires proper labeling with flammable gas and health hazard symbols, along with appropriate shipping papers and emergency response information. Drivers must hold ADR certification for dangerous goods transport. Vehicles must be equipped with appropriate safety equipment and follow designated routing restrictions for hazardous materials.

Is vinyl chloride subject to specific regulations?

Vinyl chloride is subject to extensive regulations including REACH registration, CLP classification as Carcinogen 1A, and workplace exposure limits under occupational health directives. It requires authorization under REACH for certain uses and is subject to strict emission controls under industrial emissions regulations. Medical surveillance of exposed workers is mandatory, and its production and use are restricted in consumer products. Many countries have specific vinyl chloride regulations beyond standard chemical safety laws.

Where to buy vinyl chloride in Europe?

Vinyl chloride is available through OYSI, a European distributor of technical chemicals, serving industrial customers across Europe. Due to its highly regulated nature and carcinogenic classification, purchases are restricted to qualified industrial users with proper handling facilities and safety systems. Buyers must demonstrate compliance with occupational health requirements and environmental regulations. Contact OYSI's technical sales team for availability, specifications, and regulatory compliance documentation required for your specific application and location.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.