Chloric acid

ClHO3

chloric acid

CAS7790-93-4

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Identification

CAS Number
7790-93-4
UN Number
2626
PubChem CID
19654

Physical-chemical properties

Molecular Formula
ClHO3
Molar Mass
84.46 g/mol
IUPAC Name
chloric acid

Chemical Identifiers

InChI
InChI=1S/ClHO3/c2-1(3)4/h(H,2,3,4)
InChI Key
XTEGARKTQYYJKE-UHFFFAOYSA-N

Overview

Chloric acid (CAS 7790-93-4) is a strong inorganic acid with powerful oxidizing properties and high reactivity in aqueous solutions. This highly unstable compound represents one of the most reactive chlorine oxoacids, existing primarily in aqueous solution rather than as a pure substance. Chloric acid demonstrates exceptional oxidizing capabilities, making it both industrially valuable and inherently hazardous to handle. The compound readily decomposes, particularly when concentrated or heated, releasing oxygen and forming various chlorine-containing byproducts. As a Class 5.1 oxidizing substance under ADR transport regulations, chloric acid requires specialized handling protocols and storage conditions. The compound's strong acidic nature, combined with its oxidizing properties, creates significant safety considerations including potential for violent reactions with organic materials, metals, and reducing agents. Proper ventilation, appropriate personal protective equipment, and compatible storage materials are essential when working with this substance. In industrial applications, chloric acid serves primarily as a powerful oxidizing agent in chemical synthesis processes and as an intermediate in the production of chlorates and perchlorates. The compound finds use in specialized analytical chemistry applications where its unique oxidizing characteristics are required. Like other strong oxidizing agents such as magnesium diperchlorate, chloric acid demands careful consideration of compatibility with other chemicals and materials in any process environment. The compound's instability means it is typically generated in situ or used immediately upon preparation, limiting its storage and transport as a commercial product. Safety protocols must account for both its corrosive acidic properties and its potential for supporting combustion of other materials. OYSI provides technical expertise and sourcing capabilities for chloric acid and related oxidizing compounds to qualified industrial customers.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number2626
ADR Class5.1
Packing Group
Tunnel Code
Proper Shipping NameChlorsäure, wässerige Lösung, Konz. > 10 %
Marine PollutantNo

Frequently Asked Questions

What is chloric acid?

Chloric acid is a strong inorganic acid with the chemical formula ClHO3 and molecular weight of 84.46 g/mol. It contains chlorine in the +5 oxidation state and is classified as a powerful oxidizing agent. This compound is highly reactive and unstable in concentrated form, making it primarily useful in specific industrial applications where controlled oxidation is required.

What are the physicochemical properties of chloric acid?

Chloric acid is a colorless liquid that is highly soluble in water and extremely hygroscopic. It has strong acidic properties with a very low pH in aqueous solution. The compound is thermally unstable and can decompose explosively when concentrated or heated. It exhibits powerful oxidizing characteristics due to the chlorine atom in its +5 oxidation state, making it highly reactive with organic materials and reducing agents.

What is chloric acid used for?

Chloric acid is primarily used as a strong oxidizing agent in specialized chemical synthesis and analytical chemistry applications. It serves in the preparation of chlorates and other chlorine compounds, and finds application in certain metallurgical processes where controlled oxidation is required. Due to its instability and hazardous nature, its industrial use is limited to specific processes where its unique oxidizing properties are essential.

How to handle chloric acid safely?

Chloric acid requires extreme caution during handling due to its powerful oxidizing properties and instability. Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or under fume hoods to avoid inhalation of vapors. Keep away from organic materials, reducing agents, and heat sources. Use only in dilute solutions and avoid concentration procedures that could lead to explosive decomposition.

How to store chloric acid correctly?

Chloric acid must be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers tightly closed and made of compatible materials resistant to strong acids. Store separately from organic materials, reducing agents, metals, and combustible substances due to its strong oxidizing properties. Maintain storage temperatures as low as possible to prevent decomposition and ensure containers are clearly labeled with appropriate hazard warnings.

What to do in case of contact with chloric acid?

Chloric acid contact requires immediate action due to its corrosive nature. For skin contact, immediately flush the affected area with copious amounts of water for at least 15 minutes and remove contaminated clothing. In case of eye contact, rinse thoroughly with water and seek immediate medical attention. If inhaled, move the person to fresh air immediately. For ingestion, do not induce vomiting and seek emergency medical care. Always consult a physician after any exposure incident.

How to dispose of chloric acid appropriately?

Chloric acid disposal must comply with local and national hazardous waste regulations due to its corrosive and oxidizing properties. Never dispose of it through regular drainage systems or municipal waste. Contact licensed hazardous waste disposal companies for proper treatment. Small quantities may be carefully neutralized under controlled conditions by qualified personnel, but this should only be done following specific safety protocols and regulatory guidelines. Always consult local environmental authorities for specific disposal requirements.

How to transport chloric acid?

Chloric acid is classified under ADR Class 5.1 as an oxidizing substance, requiring specialized transport procedures. It must be packaged in approved containers suitable for corrosive and oxidizing materials, with appropriate hazard labels and documentation. Transport vehicles must comply with ADR regulations for Class 5.1 substances, including proper segregation from incompatible materials. Only authorized carriers experienced in handling dangerous goods should transport this substance, following all applicable safety protocols.

Is chloric acid subject to particular regulations?

Chloric acid is subject to various chemical regulations including REACH registration requirements in Europe and CLP classification standards. As a corrosive and oxidizing substance, it falls under strict handling and transport regulations. Companies using this chemical must comply with occupational safety standards and may require special permits depending on quantities and applications. It is not classified as an SVHC substance, but users must still maintain safety data sheets and follow proper risk assessment procedures.

Where to buy chloric acid in Europe?

Chloric acid is available through OYSI, a European distributor of technical chemicals serving industrial customers across the continent. As a specialized oxidizing agent, it requires proper handling expertise and regulatory compliance knowledge. OYSI provides technical support and ensures proper packaging and documentation for safe delivery. Due to its hazardous nature and transport restrictions, availability may be subject to specific regional regulations and customer qualification requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.