Calcium dioxido(dioxo)chromium
CaCrO4
calcium dioxido(dioxo)chromium
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Identification
- CAS Number
- 13765-19-0
- EC Number
- 237-366-8
- UN Number
- 3077
- Index Number
- 024-008-00-9
- PubChem CID
- 26264
Physical-chemical properties
- Molecular Formula
- CaCrO4
- Molar Mass
- 156.07 g/mol
- IUPAC Name
- calcium dioxido(dioxo)chromium
Chemical Identifiers
- InChI
- InChI=1S/Ca.Cr.4O/q+2;;;;2*-1
- InChI Key
- RFAFBXGYHBOUMV-UHFFFAOYSA-N
Overview
Calcium dioxido(dioxo)chromium (CAS 13765-19-0) is an inorganic chromate compound with strong oxidizing properties and significant toxicological concerns. This calcium chromate compound, with the molecular formula CaCrO4 and a molecular weight of 156.07 g/mol, represents a critical chemical intermediate in various industrial processes. The substance belongs to the hexavalent chromium family, which is characterized by high reactivity and environmental persistence. Its classification as a Category 1B carcinogen under the CLP Regulation reflects the serious health hazards associated with chromium(VI) compounds, requiring stringent handling protocols and specialized safety measures. The compound exhibits typical chromate characteristics, including moderate water solubility and distinctive yellow coloration. Its oxidizing nature makes it particularly useful in industrial applications but also contributes to its toxicological profile. The GHS08 pictogram indicates serious health hazards, while GHS07 and GHS09 symbols highlight acute toxicity and environmental dangers respectively. Unlike organic compounds such as 4-[(4-amino-3-chlorophenyl)methyl]-2-chloroaniline, calcium chromate poses primarily inorganic toxicity concerns related to heavy metal exposure. Primary industrial applications include specialized pigment production, corrosion inhibition in specific metal treatment processes, and as an analytical reagent in laboratory settings. The compound's ADR Class 9 classification as a miscellaneous dangerous substance requires appropriate transportation protocols and documentation. Due to its carcinogenic classification and environmental impact, calcium dioxido(dioxo)chromium is subject to REACH authorization requirements and extensive regulatory oversight. OYSI provides this specialized chromate compound to qualified industrial customers with comprehensive safety documentation and regulatory compliance support.
Safety & Classification
Carc. 1B; Acute Tox. 4 *; Aquatic Acute 1; Aquatic Chronic 1
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 3077 |
| ADR Class | 9 |
| Packing Group | III |
| Tunnel Code | - |
| Proper Shipping Name | Calciumchromat |
| Marine Pollutant | No |
Frequently Asked Questions
What is calcium dioxido(dioxo)chromium?
Calcium dioxido(dioxo)chromium is an inorganic compound with the chemical formula CaCrO4 and molecular weight of 156.07 g/mol. This calcium chromate salt contains hexavalent chromium and is classified as a Category 1B carcinogen. The substance appears as a yellow crystalline solid and is highly regulated due to its significant health and environmental hazards, requiring strict handling protocols in industrial applications.
What are the physicochemical properties of calcium dioxido(dioxo)chromium?
Calcium dioxido(dioxo)chromium is a yellow crystalline solid at room temperature with the molecular formula CaCrO4. The compound is moderately soluble in water and exhibits typical ionic compound characteristics. Its molecular weight is 156.07 g/mol, and it contains hexavalent chromium, which contributes to its oxidizing properties and high toxicity profile.
What is calcium dioxido(dioxo)chromium used for?
Calcium dioxido(dioxo)chromium is primarily used as a corrosion inhibitor in industrial applications, particularly in metal treatment and surface protection processes. It serves as an oxidizing agent in chemical synthesis and is utilized in specialized industrial processes requiring chromium compounds. Due to its carcinogenic properties, its use is heavily restricted and limited to essential industrial applications with appropriate safety measures.
How to handle calcium dioxido(dioxo)chromium safely?
Calcium dioxido(dioxo)chromium requires strict safety protocols including respiratory protection, chemical-resistant gloves, and protective clothing due to its carcinogenic and acute toxic properties. Work must be conducted in well-ventilated areas or under fume hoods to prevent inhalation. Eye protection is mandatory, and direct skin contact must be avoided at all costs. Regular health monitoring of exposed workers is essential.
How to store calcium dioxido(dioxo)chromium correctly?
Calcium dioxido(dioxo)chromium must be stored in a cool, dry, well-ventilated area away from incompatible materials such as reducing agents and organic compounds. Containers should be tightly sealed and labeled according to GHS requirements. Storage areas must be secure with restricted access due to the carcinogenic nature of the substance, and emergency procedures should be readily available.
What to do in case of contact with calcium dioxido(dioxo)chromium?
Immediate action is required for any contact with calcium dioxido(dioxo)chromium. For skin contact, remove contaminated clothing and flush with copious amounts of water for at least 15 minutes. If inhaled, move to fresh air immediately and seek medical attention. For eye contact, rinse thoroughly with water and remove contact lenses if present. Seek immediate medical attention for all exposure incidents.
How to dispose of calcium dioxido(dioxo)chromium appropriately?
Calcium dioxido(dioxo)chromium must be disposed of as hazardous waste through licensed waste management companies specializing in carcinogenic materials. The substance cannot be disposed of in regular waste streams due to its environmental toxicity and carcinogenic properties. All disposal must comply with local and European waste regulations, including proper documentation and tracking throughout the disposal process.
How to transport calcium dioxido(dioxo)chromium?
Calcium dioxido(dioxo)chromium is classified as ADR Class 9 (miscellaneous dangerous goods), Packing Group III for transport purposes. Proper packaging, labeling with GHS pictograms (GHS07, GHS08, GHS09), and documentation are required. Transport must comply with dangerous goods regulations, and vehicles must carry appropriate emergency response information and safety equipment for handling potential incidents during transit.
Is calcium dioxido(dioxo)chromium subject to specific regulations?
Calcium dioxido(dioxo)chromium is subject to extensive European regulations including REACH registration requirements and CLP classification as a Category 1B carcinogen. The substance carries GHS pictograms for health hazards and environmental dangers, requiring comprehensive safety data sheets and worker protection measures. Its use may be restricted under various national and European chemical safety regulations due to its carcinogenic properties.
Where to buy calcium dioxido(dioxo)chromium in Europe?
Calcium dioxido(dioxo)chromium is available through OYSI, a European distributor of specialty chemicals with expertise in handling regulated substances. As a specialized chemical distributor, OYSI provides proper documentation, safety data sheets, and regulatory compliance support for this highly regulated carcinogenic compound. Contact OYSI directly for availability, technical specifications, and regulatory guidance for your specific application requirements.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.