Butanal

C4H8O

butanal

CAS123-72-8
GHS02 Gefahrensymbol: Entzündbar – Flamme
Danger

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Identification

CAS Number
123-72-8
EC Number
204-646-6
UN Number
1129
Index Number
605-006-00-2
PubChem CID
261

Physical-chemical properties

Molecular Formula
C4H8O
Molar Mass
72.11 g/mol
IUPAC Name
butanal

Chemical Identifiers

InChI
InChI=1S/C4H8O/c1-2-3-4-5/h4H,2-3H2,1H3
InChI Key
ZTQSAGDEMFDKMZ-UHFFFAOYSA-N

Overview

Butanal (CAS 123-72-8) is a saturated aliphatic aldehyde with four carbon atoms and characteristic aldehyde reactivity properties. This straight-chain aldehyde represents an important intermediate in organic synthesis and industrial chemistry. As a member of the aldehyde family, butanal exhibits the typical carbonyl functionality that makes it highly reactive and valuable for numerous chemical transformations. The compound appears as a colorless liquid with a pungent, somewhat fruity odor that becomes more pleasant when highly diluted. From a safety perspective, butanal is classified as a flammable liquid category 2 under GHS regulations, requiring careful handling procedures and appropriate fire prevention measures. The compound carries the danger signal word and GHS02 flame pictogram, indicating its significant fire hazard potential. Its ADR class 3 classification further emphasizes the need for proper storage and transportation protocols in industrial settings. The chemical properties of butanal make it particularly useful in the production of various organic compounds. Its primary industrial applications include serving as an intermediate in the synthesis of pharmaceuticals, where its aldehyde group enables condensation and addition reactions. The compound also finds use in the manufacture of plasticizers and specialty chemicals, where it contributes to the formation of more complex molecular structures. Additionally, butanal serves as a precursor in the production of certain flavoring agents and fragrance compounds, though in much smaller quantities compared to related compounds like 1-chlorobutane or 2-methylpropyl acetate, which serve different industrial purposes. OYSI maintains reliable supply chains for butanal to support European industrial customers requiring this essential aldehyde intermediate for their manufacturing processes.

Safety & Classification

Danger
Classification:

Flam. Liq. 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Transport (ADR)

UN Number1129
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameButyraldehyd
Marine PollutantNo

Frequently Asked Questions

What is butanal?

Butanal is an organic aldehyde with the molecular formula C4H8O and CAS number 123-72-8. It has a molecular weight of 72.11 g/mol and belongs to the family of saturated aliphatic aldehydes. This chemical compound is classified as a flammable liquid (Flam. Liq. 2) under GHS regulations, requiring careful handling due to its fire hazard properties. Butanal appears as a colorless liquid with a characteristic aldehyde odor and is commonly used in various industrial applications.

What are the physicochemical properties of butanal?

Butanal is a colorless liquid with a pungent, characteristic aldehyde odor at room temperature. It has a molecular formula of C4H8O and a molecular weight of 72.11 g/mol. The compound is moderately soluble in water and miscible with most organic solvents including alcohols and ethers. Butanal has a relatively low boiling point and high volatility, contributing to its classification as a flammable liquid. Its aldehyde functional group makes it reactive toward nucleophiles and oxidizing agents.

What is butanal used for?

Butanal is primarily used as an intermediate in organic synthesis and chemical manufacturing processes. It serves as a precursor for the production of various chemicals including butanoic acid, alcohols, and other aldehydes through oxidation or reduction reactions. The compound is utilized in the pharmaceutical industry for synthesizing active ingredients and in the production of fragrances and flavoring agents. Additionally, butanal finds applications in polymer chemistry and as a solvent in specialized industrial processes.

How to handle butanal safely?

Butanal requires careful handling due to its flammable nature (Flam. Liq. 2, Danger signal word). Always wear appropriate personal protective equipment including safety goggles, chemical-resistant gloves, and protective clothing. Work in well-ventilated areas or under fume hoods to prevent vapor accumulation. Eliminate all ignition sources including open flames, hot surfaces, and electrical equipment that could generate sparks. Use explosion-proof equipment when transferring or processing the material. Ensure emergency shower and eyewash stations are readily accessible.

How to store butanal correctly?

Butanal must be stored in a cool, dry, well-ventilated area away from heat sources, ignition sources, and direct sunlight. Use appropriate containers made of compatible materials and ensure they are properly sealed to prevent vapor escape. Store separately from strong oxidizing agents, acids, and bases to avoid incompatible reactions. Maintain storage temperatures below the compound's flash point and implement proper fire prevention measures including appropriate fire suppression systems. Follow local fire codes and chemical storage regulations.

What to do in case of contact with butanal?

Butanal contact requires immediate first aid measures depending on the exposure route. For skin contact, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush eyes with clean water for at least 15 minutes and seek medical attention. If inhaled, move the person to fresh air immediately and monitor for respiratory distress. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult safety data sheets for specific guidance.

How to dispose of butanal properly?

Butanal disposal must comply with local, national, and international waste regulations due to its flammable classification. The compound should be treated as hazardous waste and disposed of through licensed waste management facilities capable of handling flammable liquids. Small quantities may be incinerated in appropriate high-temperature facilities with proper emission controls. Never dispose of butanal down drains or in regular waste streams. Contact certified waste disposal companies for proper collection and treatment. Maintain disposal records as required by regulations.

How to transport butanal?

Butanal is classified under ADR regulations as Class 3 (flammable liquids), Packing Group II, requiring specific transport protocols. The compound must be packaged in UN-approved containers suitable for flammable liquids and properly labeled with appropriate hazard markings. Transport vehicles must comply with ADR requirements for Class 3 substances including proper ventilation, fire extinguishing equipment, and driver certification. Shipping documentation must include proper shipping names, hazard classifications, and emergency response information. Only use authorized carriers experienced in hazardous materials transport.

Is butanal subject to specific regulations?

Butanal is subject to various chemical regulations including REACH registration requirements in the European Union and CLP classification as Flam. Liq. 2 with GHS02 pictogram and Danger signal word. The compound is not currently listed as a Substance of Very High Concern (SVHC) under REACH. Users must comply with workplace safety regulations, environmental protection laws, and transport regulations (ADR Class 3). Industrial users may need to implement risk management measures and maintain safety data sheets. Always verify current regulatory status before use.

Where to buy butanal in Europe?

Butanal is available through OYSI, a specialized European distributor of industrial chemicals serving customers across the European market. OYSI provides high-quality butanal with proper documentation including certificates of analysis and safety data sheets. As an established chemical distributor, OYSI ensures compliance with European regulations including REACH and CLP requirements. The company offers reliable supply chains and technical support for industrial customers requiring butanal for various applications. Contact OYSI directly for availability, specifications, and pricing information.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.