Dimethyl carbonate
C3H6O3
dimethyl carbonate
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Identification
- CAS Number
- 616-38-6
- EC Number
- 210-478-4
- UN Number
- 1161
- Index Number
- 607-013-00-6
- PubChem CID
- 12021
Physical-chemical properties
- Molecular Formula
- C3H6O3
- Molar Mass
- 90.08 g/mol
- IUPAC Name
- dimethyl carbonate
Chemical Identifiers
- InChI
- InChI=1S/C3H6O3/c1-5-3(4)6-2/h1-2H3
- InChI Key
- IEJIGPNLZYLLBP-UHFFFAOYSA-N
Overview
Dimethyl carbonate (CAS 616-38-6) is an organic carbonate ester with excellent solvent properties and low toxicity profile. This versatile chemical compound serves as both a high-performance solvent and valuable chemical intermediate in numerous industrial applications. With its molecular formula C3H6O3 and molecular weight of 90.08 g/mol, dimethyl carbonate represents an environmentally friendly alternative to traditional organic solvents due to its biodegradable nature and reduced environmental impact. The compound exhibits moderate flammability, classified as Flammable Liquid Category 2 under GHS regulations, requiring appropriate handling precautions in industrial settings. Dimethyl carbonate demonstrates excellent miscibility with many organic solvents and offers superior dissolving capabilities for various polymer systems, making it particularly valuable in coating formulations and adhesive applications. Unlike more hazardous solvents such as 1-chlorobutane, dimethyl carbonate provides a safer working environment while maintaining comparable performance characteristics. Its chemical stability and relatively low vapor pressure contribute to its growing popularity as a green solvent solution. Primary industrial applications include its use as a methylating agent in pharmaceutical synthesis, as a high-performance solvent in lithium battery electrolyte formulations, and as an intermediate in polycarbonate production. The compound also finds application in paint and coating systems where low toxicity solvents are preferred, competing effectively with traditional options like 2-methylpropyl acetate in specific formulations. As a leading European distributor of technical chemicals, OYSI provides reliable access to high-quality dimethyl carbonate for industrial customers across various sectors, supporting sustainable chemical processes and innovative applications.
Safety & Classification
Flam. Liq. 2
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Highly flammable liquid and vapour.
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Transport (ADR)
| UN Number | 1161 |
| ADR Class | 3 |
| Packing Group | II |
| Tunnel Code | D/E |
| Proper Shipping Name | Dimethylcarbonat |
| Marine Pollutant | No |
Frequently Asked Questions
What is dimethyl carbonate?
Dimethyl carbonate is an organic chemical compound with the molecular formula C3H6O3 and CAS number 616-38-6. It belongs to the carbonate ester family and has a molecular weight of 90.08 g/mol. This versatile chemical serves as an environmentally friendly solvent and reagent in various industrial applications. Dimethyl carbonate is classified as a flammable liquid (Flam. Liq. 2) under GHS regulations, requiring appropriate safety precautions during handling and storage.
What are the physicochemical properties of dimethyl carbonate?
Dimethyl carbonate is a colorless liquid at room temperature with a characteristic mild, pleasant odor. It has excellent solubility properties, being miscible with most organic solvents including alcohols, ethers, and hydrocarbons, while having limited solubility in water. The compound exhibits low toxicity compared to traditional solvents and has a relatively low boiling point. Its chemical structure makes it both a good solvent and a reactive intermediate in organic synthesis.
What is dimethyl carbonate used for?
Dimethyl carbonate serves multiple industrial applications as an eco-friendly solvent, chemical intermediate, and fuel additive. It is widely used in pharmaceutical synthesis, polymer production, and as a methylating agent in organic chemistry. The compound also functions as a solvent in paints, coatings, and adhesives, replacing more toxic alternatives. Additionally, dimethyl carbonate is employed in lithium battery electrolytes and as an oxygenate additive in gasoline formulations to improve combustion efficiency.
How to handle dimethyl carbonate safely?
Dimethyl carbonate must be handled with appropriate safety measures due to its flammable liquid classification (Flam. Liq. 2). Always wear suitable personal protective equipment including safety goggles, chemical-resistant gloves, and flame-resistant clothing. Work in well-ventilated areas or under fume hoods to prevent vapor accumulation. Keep away from ignition sources, heat, and open flames. Use non-sparking tools and ensure proper grounding of equipment to prevent static electricity buildup during transfer operations.
How to store dimethyl carbonate correctly?
Dimethyl carbonate should be stored in a cool, dry, well-ventilated area away from heat sources, ignition sources, and direct sunlight. Use appropriate containers made of compatible materials and ensure they are properly sealed to prevent evaporation and contamination. Store separately from strong oxidizing agents, strong acids, and bases to avoid incompatible reactions. Maintain storage temperatures below 25°C when possible and implement proper fire prevention measures in storage areas.
What to do in case of contact with dimethyl carbonate?
Dimethyl carbonate exposure requires immediate response depending on the contact route. For skin contact, remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. If eye contact occurs, rinse immediately with clean water for 15-20 minutes and seek medical attention. For inhalation, move the person to fresh air immediately. If ingestion occurs, do not induce vomiting and seek immediate medical attention while providing the safety data sheet to healthcare providers.
How to dispose of dimethyl carbonate properly?
Dimethyl carbonate waste must be disposed of according to local, national, and international environmental regulations. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Do not discharge into drains, waterways, or soil as this may cause environmental contamination. Small quantities can sometimes be recovered through distillation for reuse. Always consult the safety data sheet and local environmental authorities for specific disposal requirements and approved disposal facilities in your region.
How to transport dimethyl carbonate?
Dimethyl carbonate is classified under ADR transportation regulations as Class 3 (flammable liquids), Packing Group II. This classification requires specific packaging, labeling, and documentation for road transport. Use UN-approved containers with proper marking and hazard labels including the GHS02 flame pictogram. Transport vehicles must comply with ADR requirements including proper ventilation, fire extinguishing equipment, and driver training. Ensure all shipping documents include the correct UN number and hazard classification information.
Is dimethyl carbonate subject to specific regulations?
Dimethyl carbonate is subject to standard chemical regulations including REACH registration in Europe and CLP classification requirements. It is classified as Flam. Liq. 2 with the signal word 'Danger' and requires GHS02 pictogram labeling. The substance is not currently listed as a Substance of Very High Concern (SVHC) under REACH. Manufacturers and importers must comply with registration, evaluation, and authorization requirements. Users must follow workplace safety regulations and provide appropriate safety information to workers.
Where to buy dimethyl carbonate in Europe?
Dimethyl carbonate is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across Europe. OYSI provides reliable supply chains and technical support for dimethyl carbonate procurement. As a professional chemical distributor, OYSI ensures proper handling, documentation, and regulatory compliance for all shipments. Contact OYSI directly for availability, specifications, packaging options, and delivery arrangements to meet your specific industrial requirements throughout European markets.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.