Dimethyl carbonate

C3H6O3

dimethyl carbonate

CAS616-38-6
GHS02 Gefahrensymbol: Entzündbar – Flamme
Danger

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Identification

CAS Number
616-38-6
EC Number
210-478-4
UN Number
1161
Index Number
607-013-00-6
PubChem CID
12021

Physical-chemical properties

Molecular Formula
C3H6O3
Molar Mass
90.08 g/mol
IUPAC Name
dimethyl carbonate

Chemical Identifiers

InChI
InChI=1S/C3H6O3/c1-5-3(4)6-2/h1-2H3
InChI Key
IEJIGPNLZYLLBP-UHFFFAOYSA-N

Overview

Dimethyl carbonate (CAS 616-38-6) is an organic carbonate ester with excellent solvent properties and low toxicity profile. This versatile chemical compound, with the molecular formula C3H6O3 and molar mass of 90.08 g/mol, serves as both a high-performance solvent and valuable chemical intermediate in various industrial applications. Dimethyl carbonate represents a more environmentally friendly alternative to traditional solvents, offering reduced toxicity compared to many conventional organic solvents while maintaining excellent dissolving capabilities for a wide range of substances. The compound exhibits favorable physical properties including good thermal stability and miscibility with numerous organic solvents. As a flammable liquid classified under GHS02 pictogram with the signal word "Danger" and ADR class 3, dimethyl carbonate requires appropriate handling procedures and storage conditions to ensure workplace safety. Despite its flammable nature, it presents significantly lower health risks compared to many traditional carbonate compounds and chlorinated solvents. In industrial applications, dimethyl carbonate finds extensive use as a solvent in paint and coating formulations, where it provides excellent film-forming properties without the environmental concerns associated with more hazardous alternatives. It serves as an important methylating agent in pharmaceutical synthesis and acts as an electrolyte component in lithium-ion battery manufacturing. The compound also functions effectively in polymer processing applications, offering advantages over substances like ethyl propanoate in certain specialized formulations due to its unique carbonate structure. Like 2-methylpropyl acetate, dimethyl carbonate demonstrates excellent compatibility with various polymer systems, making it valuable in advanced materials processing. OYSI provides high-quality dimethyl carbonate to meet diverse industrial requirements across European markets.

Safety & Classification

Danger
Classification:

Flam. Liq. 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Transport (ADR)

UN Number1161
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameDimethylcarbonat
Marine PollutantNo

Frequently Asked Questions

What is dimethyl carbonate?

Dimethyl carbonate is an organic carbonate ester with the molecular formula C3H6O3 and CAS number 616-38-6. This chemical compound has a molecular weight of 90.08 g/mol and appears as a colorless, flammable liquid with a mild odor. It is classified as a flammable liquid category 2 under GHS regulations, making it an important industrial solvent and chemical intermediate used in various manufacturing processes.

What are the physicochemical properties of dimethyl carbonate?

Dimethyl carbonate is a colorless liquid at room temperature with a characteristic mild, pleasant odor. It has excellent solvent properties and is miscible with most organic solvents including alcohols, ethers, and hydrocarbons. The compound exhibits low toxicity compared to other carbonate esters and has a relatively low boiling point, making it volatile under normal conditions. Its molecular structure allows for good chemical stability under proper storage conditions.

What is dimethyl carbonate used for?

Dimethyl carbonate serves as a versatile chemical intermediate and green solvent in various industrial applications. It is primarily used in the production of polycarbonates, pharmaceuticals, and agrochemicals. The compound also functions as a methylating agent in organic synthesis, replacing more hazardous chemicals like methyl iodide. Additionally, it finds application in lithium battery electrolytes and as an environmentally friendly solvent in paint and coating formulations.

How to handle dimethyl carbonate safely?

Dimethyl carbonate requires careful handling due to its flammable nature (Flam. Liq. 2 classification). Workers must wear appropriate personal protective equipment including safety goggles, chemical-resistant gloves, and flame-resistant clothing. Work areas should have adequate ventilation and be free from ignition sources. Emergency eyewash stations and fire suppression equipment should be readily accessible. All handling procedures must follow the safety data sheet recommendations and local safety regulations.

How to store dimethyl carbonate correctly?

Dimethyl carbonate must be stored in a cool, dry, well-ventilated area away from heat sources, sparks, and open flames. Containers should be tightly sealed and made of compatible materials to prevent contamination. Storage areas must comply with flammable liquid storage regulations and be equipped with appropriate fire suppression systems. The product should be kept away from strong oxidizing agents and stored at temperatures below its flash point to minimize fire risks.

What to do in case of contact with dimethyl carbonate?

Immediate action is required following exposure to dimethyl carbonate. For skin contact, remove contaminated clothing and wash the affected area thoroughly with soap and water. In case of eye contact, flush immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move the person to fresh air and provide respiratory support if needed. For ingestion, do not induce vomiting and seek immediate medical attention while providing supportive care.

How to dispose of dimethyl carbonate properly?

Dimethyl carbonate disposal must comply with local and European waste regulations as it is classified as hazardous waste due to its flammable properties. The material should be collected in appropriate containers and disposed of through licensed hazardous waste contractors. Incineration at authorized facilities capable of handling flammable organic compounds is typically the preferred disposal method. Empty containers must also be handled as hazardous waste and properly decontaminated before disposal.

How to transport dimethyl carbonate?

Dimethyl carbonate is classified under ADR as Class 3 (flammable liquids), Packing Group II, requiring specific transport regulations compliance. Packages must bear appropriate hazard labels including the GHS02 flame pictogram and 'Danger' signal word. Vehicles transporting this material must carry proper documentation, emergency equipment, and be operated by trained personnel. Shipping containers must meet UN specification standards and be properly sealed to prevent leakage during transport.

Is dimethyl carbonate subject to specific regulations?

Dimethyl carbonate is subject to various European chemical regulations including REACH registration requirements and CLP classification standards. It must be labeled with appropriate hazard pictograms (GHS02) and safety information. The substance is not currently listed as a Substance of Very High Concern (SVHC) under REACH. Companies handling this chemical must comply with workplace safety directives and maintain proper safety data sheets for employee protection and regulatory compliance.

Where to buy dimethyl carbonate in Europe?

Dimethyl carbonate is available through OYSI, a trusted European distributor of industrial chemicals serving various industries across the continent. OYSI provides high-quality dimethyl carbonate with proper documentation, safety data sheets, and regulatory compliance certificates. As a specialized chemical distributor, OYSI ensures reliable supply chains and technical support for customers requiring this versatile organic carbonate ester for their industrial applications and manufacturing processes.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.