Bromoethane

C2H5Br

bromoethane

CAS74-96-4
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

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Identification

CAS Number
74-96-4
EC Number
200-825-8
UN Number
1891
Index Number
602-055-00-1
PubChem CID
6332

Physical-chemical properties

Molecular Formula
C2H5Br
Molar Mass
108.97 g/mol
IUPAC Name
bromoethane

Chemical Identifiers

InChI
InChI=1S/C2H5Br/c1-2-3/h2H2,1H3
InChI Key
RDHPKYGYEGBMSE-UHFFFAOYSA-N

Overview

Bromoethane (CAS 74-96-4) is an organohalogen compound with flammable properties and significant toxicological concerns requiring careful handling protocols. This volatile organic compound, also known by its IUPAC name bromoethane, represents a fundamental alkyl halide in industrial chemistry applications. With its molecular formula C2H5Br and molecular weight of 108.97 g/mol, bromoethane exhibits characteristics typical of short-chain haloalkanes while presenting unique reactivity patterns that make it valuable in specialized chemical processes. The compound's classification under multiple hazard categories reflects its complex risk profile. As a Category 2 flammable liquid (Flam. Liq. 2), bromoethane requires storage and handling under controlled temperature conditions to prevent ignition risks. More critically, its Category 2 carcinogen classification (Carc. 2) and dual Category 4 acute toxicity ratings demand comprehensive safety protocols including appropriate ventilation systems, personal protective equipment, and regular exposure monitoring. Transportation regulations classify bromoethane under ADR Class 3, necessitating specialized logistics considerations for safe distribution. The compound's vapor pressure and volatility characteristics require sealed containment systems to minimize environmental release and worker exposure risks. Industrial applications leverage bromoethane's reactivity as an alkylating agent in pharmaceutical intermediate synthesis and as a methylating reagent in organic chemistry processes. Unlike related compounds such as ethylbenzene or styrene, which find extensive use in polymer applications, bromoethane serves primarily in specialized synthetic chemistry applications where its unique reactivity profile proves essential. Contemporary industrial usage emphasizes controlled reaction environments where bromoethane's properties can be utilized while maintaining strict safety parameters. OYSI provides bromoethane to qualified industrial customers with comprehensive safety documentation and technical support for proper handling procedures.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; Carc. 2; Acute Tox. 4 *; Acute Tox. 4 *

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H351

Suspected of causing cancer.

H332

Harmful if inhaled.

H302

Harmful if swallowed.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1891
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameEthylbromid, rein
Marine PollutantNo

Frequently Asked Questions

What is bromoethane?

Bromoethane is an organohalogen compound with the molecular formula C2H5Br and CAS number 74-96-4. This chemical substance has a molecular weight of 108.97 g/mol and belongs to the alkyl bromide family. Bromoethane is classified as a flammable liquid with carcinogenic properties and acute toxicity potential. It requires careful handling due to its hazardous nature, as indicated by its Danger signal word and multiple GHS pictograms including flammability, health hazard, and exclamation mark symbols.

What are the physicochemical properties of bromoethane?

Bromoethane is a colorless liquid at room temperature with a characteristic sweet, chloroform-like odor. It has a boiling point of approximately 38.4°C and is denser than water. The compound is sparingly soluble in water but miscible with most organic solvents including alcohols, ethers, and hydrocarbons. Bromoethane is highly volatile and can readily evaporate at ambient temperatures, forming vapors that are heavier than air and can accumulate in low-lying areas.

What is bromoethane used for?

Bromoethane is primarily used as an alkylating agent in organic synthesis and pharmaceutical intermediate production. It serves as a methylating reagent in chemical laboratories and industrial processes. The compound is also employed in the synthesis of various organic compounds, including pharmaceuticals, agrochemicals, and specialty chemicals. Additionally, bromoethane finds application in analytical chemistry as a derivatization agent for gas chromatography analysis and in research applications requiring ethyl group introduction into molecular structures.

How to handle bromoethane safely?

Bromoethane requires strict safety protocols due to its flammable, carcinogenic, and toxic properties. Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection in well-ventilated areas. Work in a fume hood to prevent vapor inhalation and keep away from ignition sources, heat, and open flames. Ensure emergency eyewash stations and safety showers are accessible. Ground all equipment to prevent static electricity buildup and use explosion-proof electrical equipment in work areas.

How to store bromoethane correctly?

Bromoethane must be stored in a cool, dry, well-ventilated area away from heat sources, ignition sources, and direct sunlight. Use appropriate secondary containment and store in original containers with tight-fitting lids. Keep separated from oxidizing agents, strong bases, and incompatible materials. Storage areas should be equipped with fire suppression systems and maintained below 25°C. Ensure proper grounding of storage containers and implement regular inspection procedures to detect any leaks or container degradation.

What to do in case of contact with bromoethane?

Bromoethane exposure requires immediate emergency response measures. For skin contact, immediately remove contaminated clothing and wash affected area with soap and water for at least 15 minutes. In case of eye contact, flush with clean water for 15 minutes while holding eyelids open. If inhaled, move victim to fresh air immediately and provide artificial respiration if breathing has stopped. For ingestion, do not induce vomiting and seek immediate medical attention. Always contact poison control center and emergency medical services promptly.

How to dispose of bromoethane properly?

Bromoethane disposal must comply with local, national, and international hazardous waste regulations. This substance cannot be disposed of through regular waste streams due to its toxic and carcinogenic properties. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small laboratory quantities may be neutralized through controlled chemical destruction methods. Prevent release to sewers, waterways, or soil. Maintain detailed disposal records and ensure transporters have appropriate ADR certification for hazardous materials.

How to transport bromoethane?

Bromoethane is classified under ADR Class 3 (flammable liquids), Packing Group II, requiring specialized transport procedures. Packages must bear appropriate hazard labels including flammable liquid and health hazard markings. Use UN-approved containers and ensure proper documentation including transport documents and emergency response information. Vehicles must be equipped with appropriate fire extinguishers and emergency equipment. Drivers require ADR certification for dangerous goods transport, and routes should avoid populated areas where possible.

Is bromoethane subject to specific regulations?

Bromoethane is subject to comprehensive European chemical regulations including REACH registration requirements and CLP classification obligations. As a Category 2 carcinogen, it faces strict workplace exposure limits and requires health surveillance programs. The substance must comply with industrial emissions directives and may be subject to authorization procedures under REACH. Import/export may require permits, and users must maintain safety data sheets and implement risk management measures according to regulatory requirements.

Where to buy bromoethane in Europe?

Bromoethane is available through OYSI, a leading European distributor of technical chemicals serving industrial and research customers across Europe. OYSI provides high-quality bromoethane with complete documentation including safety data sheets and certificates of analysis. As a specialized chemical distributor, OYSI ensures regulatory compliance and proper handling procedures throughout the supply chain. Contact OYSI directly for pricing, availability, and technical support regarding bromoethane procurement for your specific industrial or research applications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.