Bromoethane

C2H5Br

bromoethane

CAS74-96-4
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

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Identification

CAS Number
74-96-4
EC Number
200-825-8
UN Number
1891
Index Number
602-055-00-1
PubChem CID
6332

Physical-chemical properties

Molecular Formula
C2H5Br
Molar Mass
108.97 g/mol
IUPAC Name
bromoethane

Chemical Identifiers

InChI
InChI=1S/C2H5Br/c1-2-3/h2H2,1H3
InChI Key
RDHPKYGYEGBMSE-UHFFFAOYSA-N

Overview

Bromoethane (CAS 74-96-4) is an organohalogen compound featuring a bromine atom attached to an ethyl group, commonly used as an alkylating agent in organic synthesis. This colorless liquid represents one of the most important ethyl halides in industrial chemistry, serving as a versatile building block for numerous chemical transformations. With its molecular formula C2H5Br and molecular weight of 108.97 g/mol, bromoethane exhibits typical properties of alkyl halides while maintaining relatively high reactivity due to the presence of the carbon-bromine bond. The compound's volatility and moderate boiling point make it particularly suitable for gas-phase reactions and as a methylating agent alternative. From a safety perspective, bromoethane requires careful handling due to its classification as a flammable liquid (Category 2) and suspected carcinogen (Category 2). The substance displays acute toxicity properties and must be stored in appropriate conditions away from ignition sources. Professional users should implement proper ventilation systems and personal protective equipment when working with this material. Industrial applications of bromoethane span across pharmaceutical intermediate synthesis, where it serves as an ethylating agent for the production of various drug compounds. The chemical industry also utilizes it in the manufacture of quaternary ammonium compounds and as a fumigant in specialized applications. Unlike related compounds such as ethylbenzene or styrene which are primarily used in polymer production, bromoethane's reactivity makes it particularly valuable in fine chemical synthesis. OYSI provides high-quality bromoethane to meet the demanding requirements of European industrial customers, ensuring consistent supply and technical support for specialized applications.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; Carc. 2; Acute Tox. 4 *; Acute Tox. 4 *

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H351

Suspected of causing cancer.

H332

Harmful if inhaled.

H302

Harmful if swallowed.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1891
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameEthylbromid, rein
Marine PollutantNo

Frequently Asked Questions

What is bromoethane?

Bromoethane is an organohalogen compound with the molecular formula C2H5Br and CAS number 74-96-4. This chemical substance has a molecular weight of 108.97 g/mol and belongs to the alkyl halide family. It is classified as a flammable liquid with carcinogenic properties and acute toxicity potential. Bromoethane is commonly used as an intermediate in organic synthesis and industrial applications requiring halogenated compounds.

What are the physicochemical properties of bromoethane?

Bromoethane is a colorless liquid at room temperature with a characteristic sweet, ether-like odor. It has a boiling point of approximately 38.4°C and is denser than water. The compound is moderately soluble in water but highly soluble in organic solvents such as ethanol and diethyl ether. It exhibits high volatility due to its low boiling point and can easily form flammable vapor mixtures with air.

What is bromoethane used for?

Bromoethane is primarily used as an alkylating agent in organic synthesis for pharmaceutical and chemical manufacturing. It serves as an intermediate in the production of various chemicals, including quaternary ammonium compounds, surfactants, and pharmaceutical active ingredients. The compound is also utilized in research laboratories for methylation reactions and as a solvent in specific analytical procedures. Its reactivity makes it valuable for creating carbon-carbon and carbon-heteroatom bonds.

How to handle bromoethane safely?

Bromoethane requires careful handling due to its flammable, carcinogenic, and toxic properties. Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and lab coats. Work in well-ventilated areas or under fume hoods to prevent vapor inhalation. Eliminate ignition sources as the substance is highly flammable. Use grounding and bonding procedures when transferring the liquid to prevent static electricity buildup and potential fire hazards.

How to store bromoethane correctly?

Bromoethane must be stored in a cool, dry, well-ventilated area away from heat sources, sparks, and open flames. Keep containers tightly sealed in their original packaging and store below 25°C to minimize vapor formation. Separate from oxidizing agents, strong bases, and reactive metals. Storage areas should have appropriate fire suppression systems and spill containment measures. Regularly inspect containers for leaks or deterioration due to the compound's volatile nature.

What to do in case of contact with bromoethane?

Bromoethane exposure requires immediate first aid measures. For skin contact, remove contaminated clothing and rinse affected areas with plenty of water for at least 15 minutes. If inhaled, move the person to fresh air and seek medical attention immediately due to potential toxicity. For eye contact, flush thoroughly with water and remove contact lenses if present. In all cases of exposure, seek professional medical advice promptly, especially given the substance's carcinogenic classification.

How to dispose of bromoethane appropriately?

Bromoethane disposal must comply with local and European waste regulations as it is classified as hazardous waste. Never pour down drains or dispose of in regular trash due to its toxic and carcinogenic properties. Contact licensed hazardous waste disposal companies for proper collection and treatment. Small quantities can be neutralized through controlled incineration at authorized facilities. Always consult with waste management specialists and follow REACH regulation requirements for disposal documentation.

How to transport bromoethane?

Bromoethane is classified under ADR Class 3 (flammable liquids), Packing Group II, requiring specific transport regulations. Use UN-approved packaging and ensure proper labeling with GHS02, GHS07, and GHS08 pictograms plus 'Danger' signal word. Transport vehicles must comply with ADR requirements including appropriate placarding and emergency equipment. Drivers need ADR certification for dangerous goods transport. Avoid transport during extreme temperatures and ensure proper documentation accompanies all shipments.

Is bromoethane subject to particular regulations?

Bromoethane is subject to comprehensive European regulations under REACH and CLP classifications. It carries multiple hazard classifications including Flam. Liq. 2, Carc. 2, and Acute Tox. 4, requiring specific safety data sheets and risk assessments. While not currently listed as an SVHC (Substance of Very High Concern), its carcinogenic classification means strict workplace exposure limits apply. Users must comply with occupational health regulations and may require permits for industrial use.

Where to buy bromoethane in Europe?

Bromoethane is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides high-quality bromoethane with proper documentation, safety data sheets, and regulatory compliance for industrial and research applications. As a professional chemical distributor, OYSI ensures proper packaging, labeling, and transport according to ADR regulations. Contact OYSI directly for availability, specifications, and delivery options across European markets while ensuring all regulatory requirements are met.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.