Benzaldehyde
C7H6O
benzaldehyde
Consulting for Benzaldehyde
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Identification
- CAS Number
- 100-52-7
- EC Number
- 202-860-4
- UN Number
- 1990
- Index Number
- 605-012-00-5
- PubChem CID
- 240
Physical-chemical properties
- Molecular Formula
- C7H6O
- Molar Mass
- 106.12 g/mol
- IUPAC Name
- benzaldehyde
Chemical Identifiers
- InChI
- InChI=1S/C7H6O/c8-6-7-4-2-1-3-5-7/h1-6H
- InChI Key
- HUMNYLRZRPPJDN-UHFFFAOYSA-N
Overview
Benzaldehyde (CAS 100-52-7) is an aromatic aldehyde compound with a characteristic sweet almond-like odor and versatile industrial applications. This colorless to pale yellow liquid represents one of the most important aromatic aldehydes in industrial chemistry, serving as a fundamental building block for numerous synthetic processes. With its molecular formula C7H6O and molar mass of 106.12 g/mol, benzaldehyde features a benzene ring directly attached to an aldehyde functional group, making it highly reactive and valuable for various chemical transformations. The compound naturally occurs in bitter almonds, cherries, and other stone fruits, though industrial production typically relies on synthetic routes for consistent quality and supply. Benzaldehyde exhibits moderate toxicity, classified under Acute Tox. 4 with GHS07 pictogram and "Warning" signal word, requiring standard laboratory safety precautions during handling. Its ADR class 9 classification indicates miscellaneous dangerous goods status for transportation purposes. The compound demonstrates good solubility in organic solvents while showing limited water solubility, typical for aromatic compounds. Unlike simpler alcohols such as hexan-1-ol, benzaldehyde's aromatic structure provides enhanced stability and distinct reactivity patterns essential for specialty chemical synthesis. Primary industrial applications include fragrance and flavor manufacturing, where benzaldehyde serves as a key ingredient in almond flavoring and perfumery compositions. The pharmaceutical industry utilizes this compound as an intermediate for various drug syntheses, while the chemical industry employs it in the production of dyes, resins, and other specialty chemicals. Its aldehyde functionality makes it particularly valuable for condensation reactions and oxidation processes. OYSI maintains reliable stocks of technical-grade benzaldehyde to support European industrial customers across these diverse application sectors.
Safety & Classification
Acute Tox. 4 *
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Harmful if swallowed.
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 1990 |
| ADR Class | 9 |
| Packing Group | III |
| Tunnel Code | E |
| Proper Shipping Name | Benzaldehyd |
| Marine Pollutant | No |
Frequently Asked Questions
What is benzaldehyde?
Benzaldehyde is an organic chemical compound with the molecular formula C7H6O and CAS number 100-52-7. It is the simplest aromatic aldehyde, consisting of a benzene ring with an aldehyde functional group attached. With a molecular weight of 106.12 g/mol, benzaldehyde is classified as Acute Tox. 4 under GHS classification, indicating moderate toxicity. It is widely used in chemical synthesis and various industrial applications due to its reactive aldehyde group and pleasant almond-like fragrance.
What are the physicochemical properties of benzaldehyde?
Benzaldehyde is a colorless to pale yellow liquid at room temperature with a characteristic bitter almond odor. It has a boiling point of 179°C and is slightly soluble in water but readily soluble in organic solvents like ethanol, ether, and benzene. The compound is lighter than water with a density of approximately 1.04 g/cm³. It is sensitive to air and light, which can cause oxidation to benzoic acid over time.
What is benzaldehyde used for?
Benzaldehyde serves primarily as an intermediate in chemical synthesis and as a flavoring agent. It is extensively used in the production of dyes, pharmaceuticals, and perfumes. In the food industry, it provides almond flavoring for baked goods and confectionery. Industrial applications include manufacturing of benzoic acid, benzyl alcohol, and various organic compounds. It also functions as a solvent and is used in the production of plastic additives and photographic chemicals.
How to handle benzaldehyde safely?
Benzaldehyde requires careful handling due to its Acute Tox. 4 classification and GHS07 pictogram indicating harmful properties. Use appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Ensure adequate ventilation to prevent vapor accumulation. Avoid direct skin contact and inhalation of vapors. Handle in well-ventilated areas away from heat sources, sparks, and open flames. Keep containers tightly closed when not in use and wash hands thoroughly after handling.
How to store benzaldehyde correctly?
Benzaldehyde should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from direct sunlight and heat sources. Keep away from oxidizing agents, strong bases, and acids to prevent unwanted reactions. Storage temperature should be maintained below 25°C to prevent degradation. Use amber glass containers or other light-resistant packaging to minimize photochemical oxidation. Ensure storage areas are equipped with appropriate fire safety measures and spill containment systems.
What to do in case of contact with benzaldehyde?
Benzaldehyde exposure requires immediate action depending on the route of contact. For skin contact, remove contaminated clothing and wash affected area thoroughly with soap and water for at least 15 minutes. If inhaled, move to fresh air immediately and seek medical attention if breathing difficulties occur. In case of eye contact, rinse immediately with plenty of water for at least 15 minutes and remove contact lenses if present. If ingested, do not induce vomiting and seek immediate medical attention.
How to dispose of benzaldehyde properly?
Benzaldehyde disposal must comply with local and European waste regulations as it is classified as hazardous waste. Contact licensed waste disposal companies specialized in chemical waste management. Small quantities can be neutralized through controlled oxidation to benzoic acid under professional supervision. Never dispose of benzaldehyde down drains, toilets, or into soil. Use appropriate waste codes according to the European Waste Catalogue and maintain proper documentation for disposal tracking and regulatory compliance.
How to transport benzaldehyde?
Benzaldehyde is classified as ADR Class 9 (Miscellaneous dangerous substances), Packing Group III, indicating it poses relatively low transport risk. Use UN-approved packaging suitable for liquid chemicals and ensure proper labeling with hazard identification numbers. Vehicles must carry appropriate safety equipment and documentation including transport documents and emergency instructions. Drivers require ADR certification for dangerous goods transport. Avoid transport during extreme weather conditions and ensure compliance with routing restrictions in populated areas.
Is benzaldehyde subject to specific regulations?
Benzaldehyde is regulated under European REACH regulation and must be registered for commercial use above one tonne per year. It is classified under CLP regulation with Acute Tox. 4 classification requiring appropriate labeling and safety data sheets. However, it is not listed as a Substance of Very High Concern (SVHC). Users must comply with occupational exposure limits and workplace safety regulations. Industrial users may need to implement risk management measures and report usage under chemical safety assessments.
Where to buy benzaldehyde in Europe?
Benzaldehyde is available through OYSI, a trusted European distributor of technical chemicals serving industrial customers across Europe. OYSI provides high-quality benzaldehyde with complete documentation including certificates of analysis and safety data sheets. As a specialized chemical distributor, OYSI ensures regulatory compliance and proper handling throughout the supply chain. Contact OYSI directly for pricing, availability, and technical specifications to meet your specific industrial requirements and delivery locations within Europe.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.