Triethyl phosphate

C6H15O4P

triethyl phosphate

CAS78-40-0
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
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Identification

CAS Number
78-40-0
EC Number
201-114-5
UN Number
3278
Index Number
015-013-00-7
PubChem CID
6535

Physical-chemical properties

Molecular Formula
C6H15O4P
Molar Mass
182.15 g/mol
IUPAC Name
triethyl phosphate

Chemical Identifiers

InChI
InChI=1S/C6H15O4P/c1-4-8-11(7,9-5-2)10-6-3/h4-6H2,1-3H3
InChI Key
DQWPFSLDHJDLRL-UHFFFAOYSA-N

Overview

Triethyl phosphate (CAS 78-40-0) is an organophosphorus compound with flame-retardant properties and moderate toxicity characteristics. This phosphoric acid triester serves as a versatile chemical intermediate in various industrial applications, particularly valued for its flame-retardant and plasticizing properties. With the molecular formula C6H15O4P and a molecular weight of 182.15 g/mol, triethyl phosphate appears as a colorless liquid under standard conditions. The compound is classified under the European CLP regulation with acute toxicity category 4, requiring appropriate safety measures during handling and storage. From a safety perspective, triethyl phosphate carries the GHS07 pictogram and "Warning" signal word, indicating moderate hazard potential. Its ADR classification as class 6.1 substance reflects its toxic nature, necessitating proper transport protocols. Industrial users must implement adequate ventilation systems and personal protective equipment when working with this organophosphorus compound. The primary industrial applications of triethyl phosphate include its use as a flame retardant in polymer formulations, where it enhances fire resistance properties of plastics and textiles. Additionally, it functions as a plasticizer in various polymer systems, improving flexibility and processability. The compound also finds application as a solvent and extraction agent in specialized chemical processes. While structurally different from compounds like benzaldehyde, triethyl phosphate shares similar industrial utility as a chemical intermediate, though with distinct flame-retardant characteristics. Quality-conscious manufacturers across Europe rely on triethyl phosphate for applications requiring consistent performance and regulatory compliance. OYSI provides technical-grade triethyl phosphate to European industrial customers, supporting diverse manufacturing requirements with reliable supply chain management.

Safety & Classification

Warning
Classification:

Acute Tox. 4 *

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H302

Harmful if swallowed.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3278
ADR Class6.1
Packing GroupIII
Tunnel CodeE
Proper Shipping NameTriethylphosphat
Marine PollutantNo

Frequently Asked Questions

What is triethyl phosphate?

Triethyl phosphate is an organophosphorus compound with the molecular formula C6H15O4P and CAS number 78-40-0. This chemical substance has a molecular weight of 182.15 g/mol and appears as a colorless liquid at room temperature. It belongs to the phosphate ester family and is classified under GHS as Acute Tox. 4 with a Warning signal word, indicating moderate toxicity concerns that require proper handling precautions.

What are the physicochemical properties of triethyl phosphate?

Triethyl phosphate is a colorless, oily liquid with a characteristic mild odor at room temperature. It exhibits good solubility in organic solvents and has limited solubility in water. The compound is relatively stable under normal conditions but can hydrolyze slowly in the presence of moisture. Its phosphate ester structure gives it flame-retardant properties, making it valuable in various industrial applications requiring fire resistance.

What is triethyl phosphate used for?

Triethyl phosphate is primarily used as a flame retardant and plasticizer in various industrial applications. It serves as an additive in plastics, resins, and coatings to improve their fire resistance properties. The compound is also utilized as a solvent in chemical processes and as an intermediate in the synthesis of other organophosphorus compounds. Additionally, it finds applications in the production of catalysts and as a component in specialty chemical formulations.

How to handle triethyl phosphate safely?

Triethyl phosphate requires careful handling due to its Acute Tox. 4 classification under GHS07 pictogram. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, and appropriate protective clothing. Work in well-ventilated areas or under fume extraction systems to minimize inhalation exposure. Avoid direct skin and eye contact, and prevent ingestion. Always wash hands thoroughly after handling and ensure emergency shower and eyewash stations are accessible in the work area.

How to store triethyl phosphate correctly?

Triethyl phosphate should be stored in tightly sealed containers in a cool, dry, and well-ventilated area away from heat sources and direct sunlight. Keep containers upright and protected from physical damage. Store away from strong oxidizing agents, acids, and bases to prevent unwanted reactions. Ensure storage areas have appropriate spill containment measures and maintain temperatures within recommended ranges. Regular inspection of containers for leaks or deterioration is essential for safe storage.

What to do in case of contact with triethyl phosphate?

Triethyl phosphate exposure requires immediate first aid measures depending on the contact route. For skin contact, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, rinse immediately with clean water for 15-20 minutes and seek medical attention. If inhaled, move the person to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical assistance.

How to dispose of triethyl phosphate appropriately?

Triethyl phosphate disposal must comply with local, national, and European waste regulations due to its hazardous classification. The substance should be treated as hazardous waste and disposed of through licensed waste management facilities capable of handling toxic chemicals. Never dispose of it down drains, in regular trash, or into the environment. Contact certified waste disposal companies for proper collection and treatment. Maintain documentation of disposal activities for regulatory compliance purposes.

How to transport triethyl phosphate?

Triethyl phosphate is classified under ADR regulations as Class 6.1 (Toxic substances), Packing Group III, indicating moderate danger during transport. Transportation must comply with ADR requirements including proper packaging, labeling, and documentation. Packages must display appropriate hazard labels and markings. Transport vehicles require suitable equipment for spill containment and emergency response. Only trained personnel should handle transportation, and proper shipping papers must accompany all shipments across European borders.

Is triethyl phosphate subject to specific regulations?

Triethyl phosphate is subject to European chemical regulations including REACH and CLP requirements for registration, classification, labeling, and packaging. The substance is not currently listed as a Substance of Very High Concern (SVHC) under REACH. Companies handling quantities above specified thresholds must comply with registration obligations. Safety data sheets must be provided to downstream users, and the GHS classification (Acute Tox. 4, Warning) must be clearly communicated throughout the supply chain.

Where to buy triethyl phosphate in Europe?

Triethyl phosphate is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across the region. OYSI provides reliable supply chains for organophosphorus compounds with proper regulatory compliance and technical support. As a professional chemical distributor, OYSI ensures products meet European quality standards and regulatory requirements. Contact OYSI directly for availability, specifications, and technical assistance regarding triethyl phosphate procurement for your industrial applications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.