4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol

C25H18O2

CAS3236-71-3
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
3236-71-3
EC Number
406-950-6
UN Number
3077
Index Number
604-060-00-4
PubChem CID
76716

Physical-chemical properties

Molecular Formula
C25H18O2
Molar Mass
350.40 g/mol
IUPAC Name
4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol

Chemical Identifiers

InChI
InChI=1S/C25H18O2/c26-19-13-9-17(10-14-19)25(18-11-15-20(27)16-12-18)23-7-3-1-5-21(23)22-6-2-4-8-24(22)25/h1-16,26-27H
InChI Key
YWFPGFJLYRKYJZ-UHFFFAOYSA-N

Overview

4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol (CAS 3236-71-3) is an organic compound featuring a fluorene backbone with two hydroxyphenyl substituents, exhibiting notable thermal stability and chemical resistance properties. This specialized chemical compound, also identified by EC number 406-950-6, belongs to the family of fluorene derivatives with a molecular formula of C25H18O2 and molecular weight of 350.4 g/mol. The structure consists of a central fluorene unit substituted at the 9-position with two 4-hydroxyphenyl groups, creating a symmetrical molecule with enhanced thermal and mechanical properties. This unique molecular architecture makes it particularly valuable in high-performance applications where stability under demanding conditions is essential. From a safety perspective, 4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol is classified with warning-level hazards including skin and eye irritation (Skin Irrit. 2, Eye Irrit. 2), along with acute and chronic aquatic toxicity classifications (Aquatic Acute 1, Aquatic Chronic 1). The compound displays GHS07 and GHS09 pictograms and falls under ADR Class 9 for transportation purposes, requiring appropriate handling protocols and environmental precautions during storage and use. Industrial applications primarily focus on advanced polymer chemistry, where this fluorene derivative serves as a high-performance monomer or additive in specialty resins and engineering plastics. It finds particular use in electronics applications requiring exceptional thermal stability and optical clarity. The compound also functions as an intermediate in pharmaceutical synthesis, where its rigid fluorene backbone provides structural advantages. Unlike simpler compounds such as triphenyl phosphite, this fluorene derivative offers superior thermal performance in demanding applications. OYSI maintains reliable supply chains for 4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol to support European industrial customers requiring this specialized chemical intermediate.

Safety & Classification

Warning
Classification:

Skin Irrit. 2; Eye Irrit. 2; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping Name9,9-Bis(4-hydroxyphenyl)fluoren
Marine PollutantNo

Frequently Asked Questions

What is 4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol?

4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol is an organic chemical compound with the molecular formula C25H18O2 and CAS number 3236-71-3. This substance has a molecular weight of 350.4 g/mol and belongs to the fluorene derivative family. It is characterized by its biphenolic structure with a central fluorene core, making it a specialty chemical with specific industrial applications.

What are the physicochemical properties of 4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol?

4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol is a solid organic compound at room temperature with a molecular weight of 350.4 g/mol. The substance contains two phenolic hydroxyl groups and a fluorene backbone, which influences its solubility characteristics. Its chemical structure suggests limited water solubility but better solubility in organic solvents. The compound's stability and reactivity are typical of phenolic compounds.

What is 4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol used for?

4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol is primarily used as a specialty chemical intermediate in various industrial applications. Its biphenolic structure and fluorene core make it valuable in polymer chemistry, particularly as a building block for high-performance materials. The compound may also find applications in research and development, specialty coatings, and advanced material synthesis where its unique structural properties are required.

How to handle 4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol safely?

4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol requires careful handling due to its skin and eye irritant properties (Skin Irrit. 2; Eye Irrit. 2). Always wear appropriate personal protective equipment including safety goggles, protective gloves, and laboratory coats. Work in well-ventilated areas or under fume hoods to minimize exposure. Avoid direct contact with skin and eyes, and wash hands thoroughly after handling.

How to store 4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol correctly?

4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol should be stored in a cool, dry, and well-ventilated area away from heat sources and direct sunlight. Keep containers tightly closed and properly labeled. Store separately from incompatible materials and ensure proper containment to prevent environmental release, considering its aquatic toxicity classification (Aquatic Acute 1; Aquatic Chronic 1). Follow local regulations for chemical storage.

What to do in case of contact with 4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol?

In case of skin contact with 4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol, immediately wash the affected area with plenty of soap and water for at least 15 minutes. For eye contact, rinse immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move to fresh air. Remove contaminated clothing and wash before reuse. Seek medical advice if irritation persists.

How to dispose of 4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol properly?

4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol must be disposed of according to local and national hazardous waste regulations due to its environmental hazard classification. Contact licensed waste disposal companies for proper treatment and disposal. Never discharge into drains, waterways, or soil due to its aquatic toxicity (Aquatic Acute 1; Aquatic Chronic 1). Incineration at authorized facilities may be an appropriate disposal method.

How to transport 4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol?

4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol is classified as ADR Class 9 (Miscellaneous dangerous goods), Packing Group III for transportation purposes. This classification requires appropriate packaging, labeling, and documentation according to ADR regulations. Use UN-approved packaging and ensure proper shipping papers accompany the shipment. Transport vehicles must comply with ADR requirements for Class 9 substances.

Is 4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol subject to specific regulations?

4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol is subject to CLP regulation with Warning signal word and GHS07/GHS09 pictograms due to its irritant and environmental hazard properties. The substance is regulated under REACH but is not currently listed as SVHC (Substance of Very High Concern). Users must comply with safety data sheet requirements and appropriate risk management measures according to European chemical legislation.

Where to buy 4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol in Europe?

4-[9-(4-hydroxyphenyl)fluoren-9-yl]phenol is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this specialty chemical compound to industrial customers across Europe with appropriate documentation including safety data sheets and certificates of analysis. Contact OYSI directly for availability, specifications, and ordering information for your specific requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.