Triphenyl phosphite
C18H15O3P
triphenyl phosphite
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Identification
- CAS Number
- 101-02-0
- EC Number
- 202-908-4
- UN Number
- 3077
- Index Number
- 015-105-00-7
- PubChem CID
- 7540
Physical-chemical properties
- Molecular Formula
- C18H15O3P
- Molar Mass
- 310.30 g/mol
- IUPAC Name
- triphenyl phosphite
Chemical Identifiers
- InChI
- InChI=1S/C18H15O3P/c1-4-10-16(11-5-1)19-22(20-17-12-6-2-7-13-17)21-18-14-8-3-9-15-18/h1-15H
- InChI Key
- HVLLSGMXQDNUAL-UHFFFAOYSA-N
Overview
Triphenyl phosphite (CAS 101-02-0) is an organophosphorus compound with antioxidant and stabilizing properties widely used in polymer applications. This versatile phosphite ester serves as a crucial industrial chemical in various manufacturing processes, particularly in the plastics and polymer industry. With its molecular formula C18H15O3P and molecular weight of 310.3 g/mol, triphenyl phosphite functions primarily as a processing stabilizer and secondary antioxidant, helping to prevent degradation during high-temperature polymer processing. The compound appears as a colorless to pale yellow liquid or crystalline solid, depending on temperature and purity grade. From a safety perspective, triphenyl phosphite requires careful handling due to its classification as a skin and eye irritant. The compound carries Warning signal word with GHS07 and GHS09 pictograms, indicating both health hazards and environmental concerns. It demonstrates acute and chronic aquatic toxicity, necessitating proper environmental protection measures during storage and use. Transportation falls under ADR Class 9 (miscellaneous dangerous substances), requiring appropriate packaging and documentation for shipment. Industrial applications include its use as a stabilizer in PVC processing, where it prevents thermal degradation and discoloration. The chemical also finds application in polyolefin stabilization and as an intermediate in organophosphorus synthesis. Unlike more complex stabilizer systems that might incorporate compounds such as 2,3,5,6-tetrachlorocyclohexa-2,5-diene-1,4-dione for specific applications, triphenyl phosphite offers broad compatibility across polymer types. OYSI maintains reliable supply chains for triphenyl phosphite, ensuring consistent availability for European industrial customers requiring this essential polymer additive.
Safety & Classification
Skin Irrit. 2; Eye Irrit. 2; Aquatic Acute 1; Aquatic Chronic 1
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 3077 |
| ADR Class | 9 |
| Packing Group | III |
| Tunnel Code | - |
| Proper Shipping Name | Triphenylphosphit, fest |
| Marine Pollutant | No |
Frequently Asked Questions
What is triphenyl phosphite?
Triphenyl phosphite is an organophosphorus compound with the molecular formula C18H15O3P and CAS number 101-02-0. It appears as a colorless to pale yellow liquid with a molecular weight of 310.3 g/mol. This chemical belongs to the phosphite ester family and is classified as a hazardous substance requiring careful handling due to its irritant properties and environmental toxicity.
What are the physicochemical properties of triphenyl phosphite?
Triphenyl phosphite is a colorless to pale yellow liquid at room temperature with a molecular formula of C18H15O3P and molecular weight of 310.3 g/mol. It has limited water solubility but is soluble in organic solvents. The compound is sensitive to moisture and can hydrolyze in the presence of water, forming phosphorous acid and phenol derivatives.
What is triphenyl phosphite used for?
Triphenyl phosphite is primarily used as an antioxidant and stabilizer in polymer processing, particularly for PVC and other plastics. It serves as a processing stabilizer that prevents degradation during high-temperature manufacturing processes. Additionally, it functions as an intermediate in organic synthesis and as a ligand in organometallic chemistry applications within various industrial processes.
How to handle triphenyl phosphite safely?
Triphenyl phosphite requires careful handling due to its skin and eye irritant properties (Skin Irrit. 2, Eye Irrit. 2). Essential safety equipment includes chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods. Avoid direct skin and eye contact, and ensure immediate access to eyewash stations and emergency showers.
How to store triphenyl phosphite correctly?
Triphenyl phosphite should be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers tightly sealed to prevent moisture ingress, as the compound is sensitive to hydrolysis. Store away from strong oxidizing agents and acids. Ensure storage areas comply with local regulations for hazardous chemicals and maintain appropriate spill containment measures.
What to do in case of contact with triphenyl phosphite?
In case of skin contact with triphenyl phosphite, immediately remove contaminated clothing and rinse affected area with plenty of water for at least 15 minutes. For eye contact, flush immediately with clean water for at least 15 minutes while holding eyelids open. If inhaled, move to fresh air immediately. Seek medical attention if irritation persists or if large amounts were involved.
How to dispose of triphenyl phosphite properly?
Triphenyl phosphite disposal must comply with local and national hazardous waste regulations due to its environmental toxicity classification (Aquatic Acute 1, Aquatic Chronic 1). The substance should never be disposed of down drains or into the environment. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities may require neutralization before disposal following regulatory guidelines.
How to transport triphenyl phosphite?
Triphenyl phosphite is classified as ADR Class 9 (Miscellaneous dangerous goods), Packing Group III for transport purposes. Packages must be properly labeled with appropriate hazard markings and UN identification numbers. Transportation should comply with ADR regulations for dangerous goods, including proper packaging, documentation, and vehicle requirements. Professional logistics companies experienced in chemical transport are recommended.
Is triphenyl phosphite subject to specific regulations?
Triphenyl phosphite is subject to REACH regulation in Europe and must comply with CLP classification requirements, displaying GHS07 and GHS09 pictograms with 'Warning' signal word. It is not currently listed as an SVHC (Substance of Very High Concern). Users must ensure proper safety data sheets are available and follow workplace exposure guidelines and environmental protection measures.
Where to buy triphenyl phosphite in Europe?
Triphenyl phosphite is available through OYSI, a European distributor of technical chemicals serving industrial customers across Europe. OYSI provides this compound with full regulatory compliance, proper documentation, and technical support. Contact OYSI directly for availability, specifications, packaging options, and delivery to your location within Europe for your industrial applications.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.