Triphenyl phosphite

C18H15O3P

triphenyl phosphite

CAS101-02-0
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
101-02-0
EC Number
202-908-4
UN Number
3077
Index Number
015-105-00-7
PubChem CID
7540

Physical-chemical properties

Molecular Formula
C18H15O3P
Molar Mass
310.30 g/mol
IUPAC Name
triphenyl phosphite

Chemical Identifiers

InChI
InChI=1S/C18H15O3P/c1-4-10-16(11-5-1)19-22(20-17-12-6-2-7-13-17)21-18-14-8-3-9-15-18/h1-15H
InChI Key
HVLLSGMXQDNUAL-UHFFFAOYSA-N

Overview

Triphenyl phosphite (CAS 101-02-0) is an organophosphorus compound with antioxidant and stabilizing properties used in polymer processing and chemical synthesis. This colorless to pale yellow liquid serves as a versatile chemical intermediate and processing aid in various industrial applications. With the molecular formula C18H15O3P and a molecular weight of 310.3 g/mol, triphenyl phosphite belongs to the phosphite ester family, characterized by its phosphorus atom bonded to three phenyl groups through oxygen linkages. The compound demonstrates excellent thermal stability and acts as an effective secondary antioxidant, particularly in combination with primary antioxidants. From a safety perspective, triphenyl phosphite requires careful handling due to its classification as a skin and eye irritant (Skin Irrit. 2; Eye Irrit. 2) and its potential environmental impact, being classified as acutely and chronically toxic to aquatic life (Aquatic Acute 1; Aquatic Chronic 1). The compound displays GHS07 and GHS09 pictograms with a "Warning" signal word, and is classified under ADR Class 9 for transport purposes. Proper personal protective equipment and environmental containment measures are essential during handling and storage. Industrial applications of triphenyl phosphite include its use as a processing stabilizer in polymer manufacturing, where it prevents degradation during high-temperature processing of plastics and elastomers. It also functions as an intermediate in the synthesis of organophosphorus compounds and serves as a ligand in catalytic systems. Unlike more complex compounds such as 4,6-dichloro-N-(2-chlorophenyl)-1,3,5-triazin-2-amine used in specialized applications, triphenyl phosphite offers broad compatibility across multiple polymer systems. OYSI provides reliable access to high-quality triphenyl phosphite for European industrial customers, supporting diverse manufacturing and chemical processing requirements.

Safety & Classification

Warning
Classification:

Skin Irrit. 2; Eye Irrit. 2; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameTriphenylphosphit, fest
Marine PollutantNo

Frequently Asked Questions

What is triphenyl phosphite?

Triphenyl phosphite is an organophosphorus compound with the molecular formula C18H15O3P and CAS number 101-02-0. This chemical substance has a molecular weight of 310.3 g/mol and belongs to the phosphite ester family. It is classified as a hazardous substance with skin and eye irritation properties, as well as aquatic toxicity. The compound requires careful handling due to its irritant nature and environmental impact potential.

What are the physicochemical properties of triphenyl phosphite?

Triphenyl phosphite is typically a colorless to pale yellow liquid or crystalline solid at room temperature. The compound has low water solubility but dissolves well in organic solvents such as alcohols, ethers, and aromatic hydrocarbons. It exhibits moderate volatility and can decompose upon exposure to moisture or heat, forming phosphoric acid derivatives. The substance has a characteristic mild odor and density higher than water.

What is triphenyl phosphite used for?

Triphenyl phosphite is primarily used as an antioxidant and stabilizer in polymer processing, particularly for PVC and other plastics. It serves as a processing aid to prevent degradation during high-temperature manufacturing processes. The compound is also utilized as an intermediate in organic synthesis and pharmaceutical manufacturing. Additionally, it functions as a flame retardant additive in certain plastic formulations and finds applications in the production of specialty chemicals.

How to handle triphenyl phosphite safely?

Triphenyl phosphite requires protective equipment including chemical-resistant gloves, safety goggles, and protective clothing to prevent skin and eye contact. Work in well-ventilated areas or use local exhaust ventilation to minimize inhalation exposure. Avoid contact with water or moisture as the compound can hydrolyze. Ensure proper grounding when transferring the material to prevent static electricity buildup. Keep away from heat sources and incompatible materials during handling operations.

How to store triphenyl phosphite correctly?

Triphenyl phosphite should be stored in tightly sealed containers in a cool, dry place away from direct sunlight and heat sources. Keep the substance away from moisture, water, and incompatible materials such as strong oxidizers and acids. Storage areas must be well-ventilated and equipped with appropriate spill containment measures. Maintain storage temperatures below 25°C when possible and ensure containers are properly labeled according to GHS requirements with Warning signal word and appropriate pictograms.

What to do in case of contact with triphenyl phosphite?

In case of skin contact with triphenyl phosphite, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. For eye contact, rinse immediately with clean water for 15-20 minutes and seek medical attention. If inhaled, move the person to fresh air and seek medical advice if respiratory irritation occurs. In case of ingestion, do not induce vomiting and seek immediate medical attention.

How to dispose of triphenyl phosphite appropriately?

Triphenyl phosphite must be disposed of as hazardous waste according to local and national environmental regulations. The substance cannot be discharged into sewers, waterways, or soil due to its aquatic toxicity classification. Contact licensed waste disposal companies for proper treatment and disposal. Small quantities can be incinerated at high temperatures in approved facilities. Always consult local environmental authorities for specific disposal requirements and obtain proper waste classification codes before disposal.

How to transport triphenyl phosphite?

Triphenyl phosphite is classified as ADR Class 9 (Miscellaneous dangerous substances), Packing Group III for transportation purposes. The substance requires appropriate dangerous goods packaging and labeling according to ADR regulations. Transport vehicles must carry proper documentation including safety data sheets and emergency response information. Packages should be secured to prevent damage during transit and marked with the correct UN number and hazard labels. Professional transport companies experienced in chemical logistics should handle shipments.

Is triphenyl phosphite subject to specific regulations?

Triphenyl phosphite is subject to REACH regulation requiring registration for import/manufacture above 1 tonne annually in the EU. The substance must be classified and labeled according to CLP regulation with GHS07 and GHS09 pictograms and Warning signal word. It is not currently listed as an SVHC (Substance of Very High Concern). Companies must comply with occupational exposure limits and environmental discharge restrictions. Safety data sheets must be provided to downstream users in accordance with REACH requirements.

Where to buy triphenyl phosphite in Europe?

Triphenyl phosphite is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across Europe. OYSI provides comprehensive technical support, regulatory documentation, and reliable supply chain management for this specialty chemical. The company ensures full compliance with European regulations including REACH registration and CLP labeling requirements. Contact OYSI directly for pricing, availability, and technical specifications tailored to your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.