2,4-dimethyl-1,3,5-trinitrobenzene

C8H7N3O6

CAS632-92-8
GHS01 Gefahrensymbol: Explosionsgefährlich – Explodierende Bombe
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
Danger

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Identification

CAS Number
632-92-8
EC Number
211-187-5
UN Number
Index Number
609-013-00-1
PubChem CID
69442

Physical-chemical properties

Molecular Formula
C8H7N3O6
Molar Mass
241.16 g/mol
IUPAC Name
2,4-dimethyl-1,3,5-trinitrobenzene

Chemical Identifiers

InChI
InChI=1S/C8H7N3O6/c1-4-6(9(12)13)3-7(10(14)15)5(2)8(4)11(16)17/h3H,1-2H3
InChI Key
GGGVOOMKPJYWDF-UHFFFAOYSA-N

Overview

2,4-dimethyl-1,3,5-trinitrobenzene (CAS 632-92-8) is a nitroaromatic explosive compound with high sensitivity and significant industrial applications. This highly energetic nitroaromatic compound belongs to the family of trinitrobenzene derivatives, characterized by three nitro groups (-NO2) attached to a benzene ring substituted with two methyl groups. With a molecular formula of C8H7N3O6 and molecular weight of 241.16 g/mol, this crystalline substance exhibits the typical properties of nitroaromatic explosives, including shock sensitivity and thermal instability. The compound is classified under GHS as an explosive material (Expl. 1.1) with acute toxicity properties, requiring stringent safety protocols during handling and storage. The presence of multiple nitro groups makes 2,4-dimethyl-1,3,5-trinitrobenzene highly reactive and potentially dangerous, similar to other explosive compounds in this chemical family such as 2,4,6-trinitrobenzene-1,3-diolate derivatives. Its explosive classification necessitates specialized transportation and storage conditions, with handlers requiring appropriate safety equipment and training. The compound's toxicity profile includes potential acute effects through multiple exposure routes, emphasizing the need for comprehensive risk management procedures. Primary industrial applications include use as an explosive component in specialized demolition operations, mining applications where controlled detonation is required, and as an intermediate in the synthesis of other energetic materials. The compound also finds application in research and development of advanced explosive formulations where specific performance characteristics are needed. OYSI provides 2,4-dimethyl-1,3,5-trinitrobenzene to qualified industrial customers with appropriate handling capabilities and regulatory compliance, ensuring safe delivery and comprehensive technical support for specialized applications.

Safety & Classification

Danger
Classification:

Expl. 1.1; Acute Tox. 4 *; Acute Tox. 4 *; Acute Tox. 4 *; STOT RE 2 *

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H201

Explosive; mass explosion hazard.

H332

Harmful if inhaled.

H312

Harmful in contact with skin.

H302

Harmful if swallowed.

H373

May cause damage to organs through prolonged or repeated exposure.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Frequently Asked Questions

What is 2,4-dimethyl-1,3,5-trinitrobenzene?

2,4-dimethyl-1,3,5-trinitrobenzene is an explosive organic compound with the molecular formula C8H7N3O6 and CAS number 632-92-8. This aromatic nitro compound features a benzene ring substituted with two methyl groups and three nitro groups, giving it a molecular weight of 241.16 g/mol. It is classified as a Class 1.1 explosive material and poses significant safety risks due to its highly energetic nature and acute toxicity properties.

What are the physicochemical properties of 2,4-dimethyl-1,3,5-trinitrobenzene?

2,4-dimethyl-1,3,5-trinitrobenzene is a crystalline solid at room temperature with characteristic properties of nitroaromatic compounds. The substance exhibits limited water solubility due to its aromatic structure, while showing better solubility in organic solvents. As a trinitrobenzene derivative, it displays typical explosive properties with high sensitivity to impact, friction, and heat. The compound's stability and physical characteristics make proper handling and storage conditions essential for safe use.

What is 2,4-dimethyl-1,3,5-trinitrobenzene used for?

2,4-dimethyl-1,3,5-trinitrobenzene is primarily used in specialized explosive applications and as an intermediate in chemical synthesis. Its applications include use in military ordnance, mining operations, and controlled demolition where its explosive properties are required. The compound may also serve as a precursor in the manufacture of other energetic materials or as a research chemical for studies involving explosive compounds and their behavior under various conditions.

How to handle 2,4-dimethyl-1,3,5-trinitrobenzene safely?

Safe handling of 2,4-dimethyl-1,3,5-trinitrobenzene requires specialized explosive safety protocols and appropriate personal protective equipment. Workers must wear protective clothing, safety glasses, and respiratory protection to prevent inhalation and skin contact. The compound should be handled in small quantities, away from sources of ignition, impact, or friction. Only trained personnel familiar with explosive materials should handle this substance, and all operations should be conducted in designated areas with proper safety equipment and emergency procedures in place.

How to store 2,4-dimethyl-1,3,5-trinitrobenzene correctly?

2,4-dimethyl-1,3,5-trinitrobenzene must be stored in specialized explosive storage facilities that comply with local regulations for Class 1.1 explosives. The storage area should be cool, dry, and well-ventilated, protected from heat sources, direct sunlight, and mechanical shock. The compound should be kept in appropriate containers designed for explosive materials and separated from incompatible substances such as strong oxidizers, reducing agents, and metals. Access should be strictly controlled and limited to authorized personnel only.

What to do in case of contact with 2,4-dimethyl-1,3,5-trinitrobenzene?

Immediate action is required in case of contact with 2,4-dimethyl-1,3,5-trinitrobenzene due to its acute toxicity. For skin contact, remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush immediately with clean water for 15 minutes. If inhaled, move the person to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult emergency services and provide them with the safety data sheet.

How to dispose of 2,4-dimethyl-1,3,5-trinitrobenzene properly?

Disposal of 2,4-dimethyl-1,3,5-trinitrobenzene must be conducted by licensed hazardous waste disposal companies specialized in explosive materials. The compound cannot be disposed of through normal waste streams due to its explosive classification and toxicity. Disposal typically involves controlled detonation or specialized treatment processes under strict regulatory oversight. All disposal activities must comply with local, national, and international regulations governing explosive and hazardous waste management, including proper documentation and tracking procedures.

How to transport 2,4-dimethyl-1,3,5-trinitrobenzene?

Transportation of 2,4-dimethyl-1,3,5-trinitrobenzene requires compliance with ADR/UN regulations for dangerous goods transport. As an explosive material, it must be packaged in UN-approved containers suitable for explosive substances and labeled with appropriate hazard labels including GHS01, GHS07, and GHS08 pictograms. Transport must be conducted by licensed carriers with specialized equipment and trained personnel. All shipping documentation must clearly identify the material's explosive classification and hazardous properties.

Is 2,4-dimethyl-1,3,5-trinitrobenzene subject to special regulations?

2,4-dimethyl-1,3,5-trinitrobenzene is subject to extensive regulatory control under multiple frameworks including REACH, CLP, and explosive materials regulations. As a Class 1.1 explosive with acute toxicity properties, it requires special licensing for manufacture, storage, transport, and use. The compound is not classified as a SVHC under REACH, but its explosive nature subjects it to strict national and international controls governing explosive materials, including permits for possession and use in most jurisdictions.

Where to buy 2,4-dimethyl-1,3,5-trinitrobenzene in Europe?

2,4-dimethyl-1,3,5-trinitrobenzene can be sourced through OYSI, a specialized European distributor of technical chemicals with expertise in handling regulated substances. Due to the explosive classification and regulatory requirements of this compound, purchases require proper licensing and compliance with local explosive materials regulations. OYSI provides technical support and ensures proper documentation for legitimate industrial and research applications. Contact OYSI directly to discuss specific requirements, quantities, and regulatory compliance for your application.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.