2-methoxy-1,3,5-trinitrobenzene

C7H5N3O7

CAS606-35-9
GHS01 Gefahrensymbol: Explosionsgefährlich – Explodierende Bombe
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
606-35-9
UN Number
0213
Index Number
609-011-00-0
PubChem CID
11817

Physical-chemical properties

Molecular Formula
C7H5N3O7
Molar Mass
243.13 g/mol
IUPAC Name
2-methoxy-1,3,5-trinitrobenzene

Chemical Identifiers

InChI
InChI=1S/C7H5N3O7/c1-17-7-5(9(13)14)2-4(8(11)12)3-6(7)10(15)16/h2-3H,1H3
InChI Key
FMXDVBRYDYFVGS-UHFFFAOYSA-N

Overview

2-methoxy-1,3,5-trinitrobenzene (CAS 606-35-9) is a nitroaromatic explosive compound with high sensitivity and significant toxicity hazards. This polynitrated aromatic compound represents a specialized chemical intermediate within the trinitrobenzene family, characterized by the presence of three nitro groups and one methoxy substituent on the benzene ring. The molecular structure (C7H5N3O7) with a molecular weight of 243.13 g/mol gives this substance its distinctive explosive properties and chemical reactivity profile. As a Class 1.1 explosive material, 2-methoxy-1,3,5-trinitrobenzene requires exceptional handling precautions due to its extreme sensitivity to shock, friction, and heat. The compound exhibits acute toxicity through multiple exposure routes and poses environmental concerns as indicated by its Aquatic Chronic 2 classification. The safety profile demands strict adherence to explosive handling protocols, with transportation regulated under ADR Class 1 requirements. Storage must comply with explosive materials regulations, maintaining controlled temperature conditions and appropriate separation distances. Personal protective equipment including anti-static clothing and grounding procedures are essential when handling this material. The substance shares structural similarities with related compounds such as 2-methyl-1,3,5-trinitrobenzene, though the methoxy substitution significantly influences its reactivity and sensitivity characteristics. Industrial applications include specialized roles in explosive formulations, chemical synthesis intermediates for pharmaceutical compounds, and research applications in energetic materials development. The compound serves as a precursor in the manufacture of specific dyes and pigments where controlled explosive properties are utilized in processing methods. OYSI maintains availability of 2-methoxy-1,3,5-trinitrobenzene for qualified industrial customers with appropriate explosive handling certifications and regulatory compliance.

Safety & Classification

Danger
Classification:

Expl. 1.1; Acute Tox. 4 *; Acute Tox. 4 *; Acute Tox. 4 *; Aquatic Chronic 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H201

Explosive; mass explosion hazard.

H332

Harmful if inhaled.

H312

Harmful in contact with skin.

H302

Harmful if swallowed.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number0213
ADR Class1
Packing Group
Tunnel CodeB1000C
Proper Shipping NameTrinitroanisol, nicht pulverförmig
Marine PollutantNo

Frequently Asked Questions

What is 2-methoxy-1,3,5-trinitrobenzene?

2-methoxy-1,3,5-trinitrobenzene is an explosive nitroaromatic compound with the molecular formula C7H5N3O7 and CAS number 606-35-9. This chemical substance belongs to the family of trinitrobenzene derivatives, featuring three nitro groups (-NO2) and one methoxy group (-OCH3) attached to a benzene ring. With a molecular weight of 243.13 g/mol, it is classified as an explosive material under Class 1.1 hazard classification, making it highly dangerous and requiring specialized handling procedures for safe use in industrial applications.

What are the physicochemical properties of 2-methoxy-1,3,5-trinitrobenzene?

2-methoxy-1,3,5-trinitrobenzene is a solid crystalline compound at room temperature, typically appearing as yellow to pale yellow crystals. As a nitroaromatic explosive, it exhibits high sensitivity to heat, shock, and friction due to its three nitro functional groups. The compound has limited solubility in water but dissolves readily in organic solvents such as acetone, ethanol, and benzene. Its explosive nature makes it thermally unstable, with decomposition occurring at relatively low temperatures, releasing toxic nitrogen oxides.

What is 2-methoxy-1,3,5-trinitrobenzene used for?

2-methoxy-1,3,5-trinitrobenzene is primarily used in specialized explosive applications and as an intermediate in the synthesis of other energetic materials. Its applications are typically limited to military, mining, and controlled demolition industries where high-energy explosive compounds are required. Due to its Class 1.1 explosive classification, its use is strictly regulated and limited to licensed professionals with appropriate safety training and facilities. The compound may also serve as a research chemical in academic and industrial laboratories studying explosive materials and energetic compounds.

How to handle 2-methoxy-1,3,5-trinitrobenzene safely?

2-methoxy-1,3,5-trinitrobenzene requires extreme safety precautions due to its explosive nature and acute toxicity. Personnel must wear appropriate personal protective equipment including anti-static clothing, safety glasses, and respiratory protection. Work areas must be explosion-proof with proper grounding to prevent static electricity buildup. Handle only small quantities at a time, avoid friction, impact, and heat sources. Ensure adequate ventilation and emergency procedures are in place. Only trained and authorized personnel should handle this material in properly equipped facilities with appropriate safety systems and emergency response capabilities.

How to store 2-methoxy-1,3,5-trinitrobenzene correctly?

2-methoxy-1,3,5-trinitrobenzene must be stored in specialized explosive storage facilities that comply with local regulations for Class 1 explosives. Storage areas should be cool, dry, well-ventilated, and away from heat sources, ignition sources, and incompatible materials. The compound should be kept in original containers, protected from physical shock and static electricity. Storage facilities must have appropriate fire suppression systems and limited access controls. Quantities should be minimized, and inventory rotation should follow first-in-first-out principles to prevent degradation over time.

What to do in case of contact with 2-methoxy-1,3,5-trinitrobenzene?

Immediate action is required if contact with 2-methoxy-1,3,5-trinitrobenzene occurs due to its acute toxicity. For skin contact, remove contaminated clothing immediately and wash the affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move the person to fresh air immediately and provide artificial respiration if necessary. For ingestion, do not induce vomiting and seek immediate medical attention. Always contact emergency services and provide the safety data sheet to medical personnel.

How to dispose of 2-methoxy-1,3,5-trinitrobenzene appropriately?

2-methoxy-1,3,5-trinitrobenzene disposal must be conducted by licensed hazardous waste disposal companies specialized in explosive materials. The compound cannot be disposed of through normal waste streams due to its explosive classification and environmental toxicity. Disposal typically involves controlled detonation or specialized chemical treatment processes under strict regulatory oversight. All disposal activities must comply with local, national, and international regulations for explosive waste management. Generator responsibilities include proper classification, packaging, labeling, and documentation according to hazardous waste regulations before transfer to authorized disposal facilities.

How to transport 2-methoxy-1,3,5-trinitrobenzene?

2-methoxy-1,3,5-trinitrobenzene is classified as ADR Class 1 dangerous goods, requiring specialized transport procedures for explosive materials. Transportation must be conducted by carriers licensed for explosive materials transport, using approved packaging and labeling systems. Vehicles must meet specific technical requirements for explosive transport, including appropriate placarding and emergency equipment. Transport documentation must include proper shipping names, hazard classifications, and emergency response information. Routing restrictions may apply, avoiding populated areas and following designated explosive transport routes as required by local transportation authorities.

Is 2-methoxy-1,3,5-trinitrobenzene subject to special regulations?

2-methoxy-1,3,5-trinitrobenzene is subject to extensive regulatory oversight due to its explosive classification and acute toxicity. Under European CLP regulation, it requires specific hazard labeling with GHS01, GHS07, and GHS09 pictograms. REACH registration requirements apply for commercial use. The compound is regulated under explosive licensing laws, requiring permits for possession, use, and distribution. Additional restrictions may apply under counter-terrorism legislation and dual-use export controls. Users must comply with workplace safety regulations, environmental protection laws, and industry-specific standards for explosive materials handling and storage.

Where to buy 2-methoxy-1,3,5-trinitrobenzene in Europe?

2-methoxy-1,3,5-trinitrobenzene is available through specialized chemical distributors like OYSI, which supplies industrial chemicals across Europe. Due to its explosive classification and regulatory restrictions, purchase requires appropriate licenses and permits for handling Class 1 explosive materials. Buyers must demonstrate legitimate use, proper storage facilities, and compliance with safety regulations. OYSI can provide technical support, safety documentation, and regulatory guidance for qualified customers. Contact OYSI's technical team to discuss specific requirements, availability, and regulatory compliance procedures for this controlled explosive material.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.