2,2-dibromo-2-nitroethanol

C2H3Br2NO3

CAS69094-18-4
GHS01 Gefahrensymbol: Explosionsgefährlich – Explodierende Bombe
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
69094-18-4
EC Number
412-380-9
UN Number
Index Number
609-056-00-6
PubChem CID
93395

Physical-chemical properties

Molecular Formula
C2H3Br2NO3
Molar Mass
248.86 g/mol
IUPAC Name
2,2-dibromo-2-nitroethanol

Chemical Identifiers

InChI
InChI=1S/C2H3Br2NO3/c3-2(4,1-6)5(7)8/h6H,1H2
InChI Key
FMNZAHDAULEOSO-UHFFFAOYSA-N

Overview

2,2-dibromo-2-nitroethanol (CAS 69094-18-4) is a halogenated nitroalcohol compound with significant explosive and corrosive properties. This specialized chemical substance belongs to the family of nitroalcohols and represents a highly reactive intermediate used in various industrial chemical processes. With its molecular formula C2H3Br2NO3 and molecular weight of 248.86 g/mol, 2,2-dibromo-2-nitroethanol exhibits unique properties due to the presence of both bromine atoms and a nitro functional group attached to the ethanol backbone. The compound carries the EC number 412-380-9 and is classified under multiple hazard categories including explosive (Expl. 1.1), carcinogenic (Carc. 2), and skin corrosive (Skin Corr. 1A) properties. The substance requires extremely careful handling due to its explosive nature and potential health hazards. Its classification under GHS pictograms including GHS01 (explosive), GHS08 (health hazard), GHS07 (harmful), GHS05 (corrosive), and GHS09 (environmental hazard) indicates the comprehensive safety measures required during storage, transportation, and use. The compound shows corrosive effects on skin and may cause sensitization reactions. Primary industrial applications include its use as a chemical intermediate in pharmaceutical synthesis, specialty chemical manufacturing, and as a precursor in the production of other nitro compounds. Unlike simpler compounds such as 4-nitrosophenol, this dibromo derivative offers enhanced reactivity for specific synthetic pathways. The substance also finds application in research and development of advanced materials and specialized organic synthesis processes. OYSI maintains availability of 2,2-dibromo-2-nitroethanol for qualified industrial customers with appropriate safety certifications and handling capabilities.

Safety & Classification

Danger
Classification:

Expl. 1.1; Carc. 2; Acute Tox. 4 *; STOT RE 2 *; Skin Corr. 1A; Skin Sens. 1; Aquatic Acute 1; Aq...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H201

Explosive; mass explosion hazard.

H351

Suspected of causing cancer.

H302

Harmful if swallowed.

H373

May cause damage to organs through prolonged or repeated exposure.

H314

Causes severe skin burns and eye damage.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Frequently Asked Questions

What is 2,2-dibromo-2-nitroethanol?

2,2-dibromo-2-nitroethanol is an organohalogen compound with the molecular formula C2H3Br2NO3 and CAS number 69094-18-4. This chemical substance contains both bromine and nitro functional groups attached to an ethanol backbone, giving it a molecular weight of 248.86 g/mol. It is classified as a highly hazardous material due to its explosive, carcinogenic, and corrosive properties, requiring specialized handling and safety measures in industrial applications.

What are the physicochemical properties of 2,2-dibromo-2-nitroethanol?

2,2-dibromo-2-nitroethanol is a dense organic compound containing two bromine atoms and one nitro group attached to an ethanol molecule. The presence of multiple halogen atoms and the nitro group significantly increases its molecular weight to 248.86 g/mol compared to simple ethanol. Its polarity is influenced by both the hydroxyl group and the electron-withdrawing nitro group, affecting its solubility characteristics and chemical reactivity in various solvents.

What is 2,2-dibromo-2-nitroethanol used for?

2,2-dibromo-2-nitroethanol serves as a specialized chemical intermediate in organic synthesis and pharmaceutical manufacturing. Its unique combination of bromine atoms and nitro functionality makes it valuable for creating complex molecular structures in research and industrial chemistry. The compound may also be used in the development of specialized materials or as a building block for other organohalogen compounds, though its hazardous nature limits its applications to controlled professional environments.

How to handle 2,2-dibromo-2-nitroethanol safely?

2,2-dibromo-2-nitroethanol requires extreme caution during handling due to its explosive, carcinogenic, and corrosive properties. Personnel must wear full chemical-resistant protective equipment including acid-resistant gloves, eye protection, and respiratory protection. Work must be conducted in well-ventilated areas or under fume hoods, away from heat sources and incompatible materials. Only trained professionals should handle this substance, following strict protocols to prevent skin contact, inhalation, or accidental detonation.

How to store 2,2-dibromo-2-nitroethanol correctly?

2,2-dibromo-2-nitroethanol must be stored in explosion-proof facilities away from heat, sparks, and incompatible materials due to its explosive classification (Expl. 1.1). Storage areas should be cool, dry, and well-ventilated with appropriate fire suppression systems. The compound should be kept in original containers, properly labeled, and segregated from oxidizers, acids, and organic materials. Access must be restricted to authorized personnel only, with emergency procedures readily available.

What to do in case of contact with 2,2-dibromo-2-nitroethanol?

2,2-dibromo-2-nitroethanol contact requires immediate emergency response due to its corrosive and toxic nature. For skin contact, immediately flush with copious amounts of water for at least 15 minutes and remove contaminated clothing. In case of eye contact, rinse continuously with water and seek immediate medical attention. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek emergency medical care. Always contact poison control and provide safety data sheet information to medical personnel.

How to dispose of 2,2-dibromo-2-nitroethanol appropriately?

2,2-dibromo-2-nitroethanol disposal requires specialized hazardous waste procedures due to its explosive, carcinogenic, and environmentally hazardous properties. The compound must be handled by licensed hazardous waste disposal companies equipped for explosive materials. It cannot be disposed of through normal waste streams or sewage systems due to its aquatic toxicity classification. Disposal must comply with local and European waste regulations, including proper documentation, packaging, and transportation to authorized treatment facilities.

How to transport 2,2-dibromo-2-nitroethanol?

2,2-dibromo-2-nitroethanol transportation requires compliance with ADR dangerous goods regulations due to its hazardous properties. The compound must be packaged in approved containers with proper hazard labels including the relevant GHS pictogrammes (GHS01, GHS08, GHS07, GHS05, GHS09). Transportation should only be performed by certified dangerous goods carriers with appropriate emergency response equipment. Special precautions must be taken to prevent shock, friction, and temperature extremes during transit to avoid accidental detonation.

Is 2,2-dibromo-2-nitroethanol subject to specific regulations?

2,2-dibromo-2-nitroethanol is subject to extensive European chemical regulations including REACH registration and CLP classification requirements. Its multiple hazard classifications (explosive, carcinogenic, corrosive, sensitizing, and aquatic toxic) trigger strict regulatory controls for manufacturing, import, and use. The compound requires safety data sheets, proper labeling with danger signal words, and may be subject to authorization or restriction procedures. Workplace exposure limits and specialized handling requirements apply under occupational health regulations.

Where to buy 2,2-dibromo-2-nitroethanol in Europe?

2,2-dibromo-2-nitroethanol is available through OYSI, a specialized European distributor of technical chemicals with expertise in hazardous materials. Due to the compound's explosive and carcinogenic properties, purchase is restricted to qualified industrial users with appropriate licenses and safety infrastructure. OYSI provides proper documentation, safety data sheets, and regulatory compliance support for customers requiring this specialized chemical for legitimate industrial or research applications within the European market.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.