2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine

C8H9O3PS

CAS3811-49-2
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
3811-49-2
EC Number
223-292-3
UN Number
2783
Index Number
015-152-00-3
PubChem CID
19657

Physical-chemical properties

Molecular Formula
C8H9O3PS
Molar Mass
216.20 g/mol
IUPAC Name
2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine

Chemical Identifiers

InChI
InChI=1S/C8H9O3PS/c1-9-12(13)10-6-7-4-2-3-5-8(7)11-12/h2-5H,6H2,1H3
InChI Key
OUNSASXJZHBGAI-UHFFFAOYSA-N

Overview

2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine (CAS 3811-49-2) is an organophosphorus compound with distinctive benzodioxaphosphinine ring structure and methoxy-sulfanylidene functional groups. This specialized organophosphorus compound, with molecular formula C8H9O3PS and molecular weight of 216.2 g/mol, represents a unique class of heterocyclic phosphorus derivatives. The compound features a characteristic benzodioxaphosphinine ring system with methoxy and sulfanylidene substituents, distinguishing it from simpler organophosphorus compounds. Its EC number 223-292-3 reflects its established chemical identity within European regulatory frameworks. The substance exhibits significant toxicological properties requiring careful handling protocols. Classified under multiple acute toxicity categories (Acute Tox. 3) and specific target organ systemic toxicity (STOT SE 1), it demands strict safety measures during industrial applications. The GHS classification includes pictograms GHS06 (skull and crossbones), GHS08 (health hazard), and GHS09 (environmental hazard), indicating its potential risks to human health and aquatic environments. Transport classification under ADR class 6.1 designates it as a toxic substance requiring specialized shipping procedures. Industrial applications typically leverage its unique phosphorus-sulfur chemistry for specialized synthetic processes, particularly in pharmaceutical intermediates and advanced materials development. The compound's distinctive ring structure makes it valuable in research applications requiring specific organophosphorus functionalities. Unlike simpler aromatic compounds such as N-methylaniline, this benzodioxaphosphinine derivative offers unique reactivity patterns suited for specialized chemical transformations. Manufacturing sectors utilizing this compound benefit from its specific chemical properties while maintaining rigorous safety protocols due to its toxicological profile. OYSI provides this technical-grade organophosphorus compound to qualified industrial customers with appropriate handling capabilities and regulatory compliance.

Safety & Classification

Danger
Classification:

Acute Tox. 3 *; Acute Tox. 3 *; STOT SE 1; Aquatic Chronic 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H311

Toxic in contact with skin.

H301

Toxic if swallowed.

H370

Causes damage to organs.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Toxic

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2783
ADR Class6.1
Packing GroupIII
Tunnel CodeE
Proper Shipping NameDioxabenzofos (ISO)
Marine PollutantNo

Frequently Asked Questions

What is 2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine?

2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine is an organophosphorus compound with the molecular formula C8H9O3PS and molecular weight of 216.2 g/mol. This chemical substance contains phosphorus, sulfur, and oxygen atoms arranged in a benzodioxaphosphinine ring structure with a methoxy substituent. It is classified as a hazardous substance under CLP regulation with acute toxicity and specific target organ toxicity properties.

What are the physicochemical properties of 2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine?

2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine is a phosphorus-containing organic compound with a molecular weight of 216.2 g/mol and the formula C8H9O3PS. The specific physical properties such as melting point, boiling point, density, and solubility require consultation of detailed technical data sheets. As an organophosphorus compound, it typically exhibits moderate stability under normal conditions but may be sensitive to moisture and heat.

What is 2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine used for?

2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine is primarily used in specialized chemical synthesis and research applications. As an organophosphorus compound, it may serve as an intermediate in the production of pharmaceutical compounds, agrochemicals, or specialty chemicals. Its specific applications depend on its reactivity profile and the requirements of particular synthetic pathways. Professional use requires appropriate technical expertise and safety measures.

How to handle 2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine safely?

2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine requires careful handling due to its Acute Tox. 3 and STOT SE 1 classifications. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, and respiratory protection. Work must be conducted in well-ventilated areas or under fume extraction. Avoid skin and eye contact, inhalation, and ingestion. Emergency procedures and first aid measures should be readily available before handling begins.

How to store 2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine correctly?

2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine must be stored in a cool, dry, well-ventilated area away from incompatible materials. Containers should be tightly sealed and labeled according to CLP requirements including GHS06, GHS08, and GHS09 pictograms. Storage areas should have appropriate containment measures and restricted access. Keep away from heat sources, oxidizing agents, and moisture. Regular inspection of container integrity is recommended.

What to do in case of contact with 2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine?

Immediate action is required upon contact with 2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine due to its acute toxicity. For skin contact, remove contaminated clothing and rinse affected area with plenty of water. In case of eye contact, flush immediately with water for at least 15 minutes. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult the safety data sheet for specific first aid measures.

How to dispose of 2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine appropriately?

2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine must be disposed of as hazardous waste in accordance with local, national, and EU regulations. The substance cannot be disposed of via normal waste streams due to its toxicity and environmental hazard classification. Disposal should be conducted through licensed hazardous waste management companies using appropriate treatment methods such as high-temperature incineration. Consult local authorities for specific disposal requirements and authorized waste handlers.

How to transport 2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine?

2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine is classified under ADR as Class 6.1 (toxic substances), Packing Group III. Transportation requires appropriate UN-approved packaging, proper labeling with hazard diamonds, and accompanying transport documentation. Vehicles must carry appropriate emergency equipment and drivers need hazardous goods training certification. Segregation requirements must be observed to prevent incompatible materials from being transported together.

Is 2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine subject to specific regulations?

2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine is subject to REACH regulation for registration and authorization in the EU. The substance must be classified and labeled according to CLP regulation with Danger signal word and appropriate GHS pictograms. While not currently listed as SVHC, its acute toxicity properties may trigger additional restrictions. Users must maintain safety data sheets and ensure compliance with occupational exposure limits and environmental protection requirements.

Where to buy 2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine in Europe?

2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine is available through OYSI, a specialized European distributor of chemical products. OYSI provides professional-grade chemicals with proper documentation, safety data sheets, and regulatory compliance support. As a hazardous substance requiring specialized handling, purchase is typically restricted to qualified industrial users, research institutions, and companies with appropriate safety infrastructure and expertise in chemical handling.

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2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine is a dangerous good. We support you with labeling, packaging, and transport documentation.

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Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.