1-methyl-2,4-dinitrobenzene
C7H6N2O4
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Identification
- CAS Number
- 121-14-2
- EC Number
- 204-450-0
- UN Number
- 3454
- Index Number
- 609-007-00-9
- PubChem CID
- 8461
Physical-chemical properties
- Molecular Formula
- C7H6N2O4
- Molar Mass
- 182.13 g/mol
- IUPAC Name
- 1-methyl-2,4-dinitrobenzene
Chemical Identifiers
- InChI
- InChI=1S/C7H6N2O4/c1-5-2-3-6(8(10)11)4-7(5)9(12)13/h2-4H,1H3
- InChI Key
- RMBFBMJGBANMMK-UHFFFAOYSA-N
Overview
1-methyl-2,4-dinitrobenzene (CAS 121-14-2) is an aromatic nitro compound with significant industrial applications and notable safety considerations. This dinitrobenzene derivative, also known by its IUPAC designation 1-methyl-2,4-dinitrobenzene, represents an important class of nitroaromatic compounds widely utilized in chemical manufacturing processes. With the molecular formula C7H6N2O4 and a molecular weight of 182.13 g/mol, this compound features a benzene ring substituted with a methyl group and two nitro groups at specific positions, giving it distinct chemical properties that make it valuable for various industrial applications. The substance carries significant safety considerations, classified under multiple hazard categories including carcinogenicity (Category 1B), mutagenicity (Category 2), and reproductive toxicity (Category 2). Its classification as Acute Toxicity Category 3 across multiple exposure routes, combined with GHS pictograms GHS08 (health hazard), GHS06 (toxic), and GHS09 (environmental hazard), underscores the importance of proper handling protocols. The ADR Class 6.1 designation reflects its toxic nature during transportation. In industrial applications, 1-methyl-2,4-dinitrobenzene serves primarily as an intermediate in organic synthesis, particularly in the production of dyes, pigments, and other specialty chemicals. It also finds use in the manufacture of explosives and as a precursor for various pharmaceutical intermediates. The compound shares chemical similarities with related substances such as 1-methyl-2,3-dinitrobenzene and 4-methyl-1,2-dinitrobenzene, which belong to the same family of methyldinitrobenzenes but differ in their substitution patterns. OYSI provides 1-methyl-2,4-dinitrobenzene to qualified industrial customers across Europe, ensuring compliance with all relevant safety and regulatory requirements.
Safety & Classification
Carc. 1B; Muta. 2; Repr. 2; Acute Tox. 3 *; Acute Tox. 3 *; Acute Tox. 3 *; STOT RE 2 *; Aquatic ...
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 3454 |
| ADR Class | 6.1 |
| Packing Group | II |
| Tunnel Code | D/E |
| Proper Shipping Name | 2,4-Dinitrotoluen, fest |
| Marine Pollutant | No |
Frequently Asked Questions
What is 1-methyl-2,4-dinitrobenzene?
1-methyl-2,4-dinitrobenzene is an aromatic nitro compound with the molecular formula C7H6N2O4 and CAS number 121-14-2. This chemical consists of a benzene ring substituted with one methyl group and two nitro groups at specific positions. With a molecular weight of 182.13 g/mol, it belongs to the family of dinitrotoluenes and is classified as a highly hazardous substance with carcinogenic, mutagenic, and reproductive toxicity properties.
What are the physicochemical properties of 1-methyl-2,4-dinitrobenzene?
1-methyl-2,4-dinitrobenzene typically appears as a pale yellow to orange crystalline solid at room temperature. It has a characteristic aromatic odor and exhibits limited solubility in water but dissolves readily in organic solvents such as ethanol, acetone, and benzene. The compound has a relatively high melting point due to its aromatic structure and nitro substituents, making it stable under normal storage conditions but requiring careful handling due to its toxic properties.
What is 1-methyl-2,4-dinitrobenzene used for?
1-methyl-2,4-dinitrobenzene serves primarily as an intermediate in the synthesis of dyes, pigments, and other organic compounds in the chemical industry. It is used in the production of explosives and propellants, and as a precursor for manufacturing various aromatic amines through reduction processes. Due to its high toxicity profile, its use is strictly regulated and limited to specialized industrial applications where proper safety measures and containment systems are in place.
How to handle 1-methyl-2,4-dinitrobenzene safely?
Safe handling of 1-methyl-2,4-dinitrobenzene requires comprehensive personal protective equipment including respiratory protection, chemical-resistant gloves, safety goggles, and protective clothing. Work must be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Given its carcinogenic and mutagenic properties (Carc. 1B, Muta. 2), minimize direct contact and implement strict hygiene procedures. Regular health monitoring of workers and emergency response procedures must be established according to occupational safety regulations.
How to store 1-methyl-2,4-dinitrobenzene properly?
Proper storage of 1-methyl-2,4-dinitrobenzene requires a cool, dry, well-ventilated area away from heat sources, ignition sources, and incompatible materials. Store in tightly sealed original containers in a designated hazardous chemical storage area with appropriate secondary containment. Keep away from strong oxidizing agents, reducing agents, and bases. Implement access control measures due to its high toxicity profile and ensure storage areas are equipped with appropriate fire suppression systems and spill containment materials.
What to do in case of contact with 1-methyl-2,4-dinitrobenzene?
Immediate first aid for 1-methyl-2,4-dinitrobenzene exposure includes removing contaminated clothing and flushing affected skin with copious amounts of water for at least 15 minutes. For eye contact, rinse thoroughly with water and seek immediate medical attention. If inhaled, move the person to fresh air and provide oxygen if breathing is difficult. Never induce vomiting if ingested. Due to its acute toxicity and carcinogenic properties, seek immediate medical attention for any exposure and provide safety data sheet information to medical personnel.
How to dispose of 1-methyl-2,4-dinitrobenzene appropriately?
Disposal of 1-methyl-2,4-dinitrobenzene must comply with local, national, and European waste regulations as hazardous waste. This substance requires specialized disposal through licensed hazardous waste management companies due to its carcinogenic and toxic properties. Incineration at high temperatures in approved facilities is typically the preferred method. Never dispose of this chemical through regular waste streams, sewage systems, or by burial. Maintain detailed records of waste disposal and ensure compliance with REACH and CLP regulations.
How to transport 1-methyl-2,4-dinitrobenzene?
Transportation of 1-methyl-2,4-dinitrobenzene falls under ADR Class 6.1 (Toxic substances), Packing Group II, indicating significant transport hazards. Packaging must meet UN specification standards with appropriate labeling including GHS pictograms GHS06, GHS08, and GHS09. Transport vehicles require proper placarding and documentation including transport emergency cards. Drivers must hold ADR certification for dangerous goods transport, and shipments must comply with routing restrictions and quantity limitations as specified in European transport regulations.
Is 1-methyl-2,4-dinitrobenzene subject to specific regulations?
Yes, 1-methyl-2,4-dinitrobenzene is subject to extensive regulatory oversight under European chemical legislation including REACH registration requirements and CLP classification obligations. Its classification as Carc. 1B, Muta. 2, and Repr. 2 subjects it to strict authorization and restriction procedures. While not currently listed as a Substance of Very High Concern (SVHC), its hazard profile may trigger future regulatory actions. Companies must comply with occupational exposure limits, environmental discharge restrictions, and comprehensive risk assessment requirements.
Where to buy 1-methyl-2,4-dinitrobenzene in Europe?
1-methyl-2,4-dinitrobenzene is available through specialized chemical distributors in Europe, including OYSI, which provides high-quality chemical products with comprehensive regulatory compliance documentation. Due to its hazardous nature and regulatory requirements, procurement is typically restricted to qualified industrial users with appropriate handling facilities and safety credentials. OYSI ensures full REACH compliance and provides technical support, safety documentation, and logistics solutions for this controlled substance throughout the European market.
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1-methyl-2,4-dinitrobenzene is a dangerous good. We support you with labeling, packaging, and transport documentation.
Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.