1-methyl-2,4-dinitrobenzene

C7H6N2O4

CAS121-14-2
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

Consulting for 1-methyl-2,4-dinitrobenzene

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Identification

CAS Number
121-14-2
EC Number
204-450-0
UN Number
3454
Index Number
609-007-00-9
PubChem CID
8461

Physical-chemical properties

Molecular Formula
C7H6N2O4
Molar Mass
182.13 g/mol
IUPAC Name
1-methyl-2,4-dinitrobenzene

Chemical Identifiers

InChI
InChI=1S/C7H6N2O4/c1-5-2-3-6(8(10)11)4-7(5)9(12)13/h2-4H,1H3
InChI Key
RMBFBMJGBANMMK-UHFFFAOYSA-N

Overview

1-Methyl-2,4-dinitrobenzene (CAS 121-14-2) is a nitroaromatic compound with significant toxicological properties and industrial applications. This chemical substance, also known by its IUPAC name 1-methyl-2,4-dinitrobenzene, represents an important member of the dinitrotoluene family with the molecular formula C7H6N2O4 and a molecular weight of 182.13 g/mol. The compound features a benzene ring substituted with a methyl group and two nitro groups in specific positions, creating a structure that exhibits distinct chemical and physical properties. The safety profile of 1-methyl-2,4-dinitrobenzene requires careful attention due to its classification under multiple hazard categories. It carries a Category 1B carcinogenicity classification, along with mutagenicity and reproductive toxicity concerns (Categories 2). The substance also presents acute toxicity risks across multiple exposure routes and potential for specific target organ toxicity following repeated exposure. These characteristics necessitate strict handling protocols and appropriate personal protective equipment during industrial use. From a regulatory perspective, this compound falls under ADR Class 6.1, reflecting its toxic nature during transport. The associated GHS pictograms (GHS08, GHS06, GHS09) clearly communicate the health hazards and environmental risks to handlers and users. Industrial applications of 1-methyl-2,4-dinitrobenzene primarily focus on its role as a chemical intermediate in organic synthesis processes. The compound serves as a precursor in the manufacture of dyes, pigments, and other aromatic compounds. Additionally, it finds use in specialized chemical research and development applications where its specific nitroaromatic structure provides valuable synthetic pathways. Within the dinitrotoluene family, this compound shares structural similarities with related substances such as 1-methyl-2,3-dinitrobenzene and 2-methyl-1,4-dinitrobenzene, each offering distinct reactivity patterns for specific industrial processes. OYSI maintains availability of 1-methyl-2,4-dinitrobenzene for qualified industrial customers requiring this specialized chemical intermediate.

Safety & Classification

Danger
Classification:

Carc. 1B; Muta. 2; Repr. 2; Acute Tox. 3 *; Acute Tox. 3 *; Acute Tox. 3 *; STOT RE 2 *; Aquatic ...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H350

May cause cancer.

H341

Suspected of causing genetic defects.

H331

Toxic if inhaled.

H311

Toxic in contact with skin.

H301

Toxic if swallowed.

H373

May cause damage to organs through prolonged or repeated exposure.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Toxic

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3454
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping Name2,4-Dinitrotoluen, fest
Marine PollutantNo

Frequently Asked Questions

What is 1-methyl-2,4-dinitrobenzene?

1-methyl-2,4-dinitrobenzene is an aromatic organic compound with the molecular formula C7H6N2O4 and CAS number 121-14-2. This chemical belongs to the dinitrotoluene family and features a benzene ring substituted with one methyl group and two nitro groups at specific positions. With a molecular weight of 182.13 g/mol, it is classified as a highly hazardous substance due to its carcinogenic, mutagenic, and reproductive toxicity properties.

What are the physicochemical properties of 1-methyl-2,4-dinitrobenzene?

1-methyl-2,4-dinitrobenzene typically appears as a yellow to orange crystalline solid at room temperature. The compound has limited water solubility but dissolves well in organic solvents such as ethanol, acetone, and benzene. It exhibits a characteristic aromatic odor and has a relatively high melting point due to its aromatic structure and nitro substituents. The presence of electron-withdrawing nitro groups significantly affects its chemical reactivity and physical properties.

What is 1-methyl-2,4-dinitrobenzene used for?

1-methyl-2,4-dinitrobenzene serves primarily as an intermediate in chemical synthesis, particularly in the production of dyes, pigments, and other aromatic compounds. It is used in the manufacture of explosives and as a precursor for various nitroaromatic derivatives. The compound also finds application in research laboratories for synthetic organic chemistry. Due to its high toxicity, its use is strictly regulated and limited to industrial processes with appropriate safety measures.

How to handle 1-methyl-2,4-dinitrobenzene safely?

1-methyl-2,4-dinitrobenzene requires extreme caution during handling due to its carcinogenic and toxic properties. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, and respiratory protection. Work must be conducted in a well-ventilated area or under fume hood conditions. Avoid skin contact, inhalation, and ingestion at all costs. Personnel should be trained in hazardous material handling procedures and emergency response protocols before working with this substance.

How to store 1-methyl-2,4-dinitrobenzene correctly?

1-methyl-2,4-dinitrobenzene must be stored in a cool, dry, well-ventilated area away from heat sources and incompatible materials. The substance should be kept in tightly sealed, chemically resistant containers, preferably in a designated hazardous materials storage area. Avoid storage near oxidizing agents, reducing agents, and strong acids. Temperature control is important to prevent decomposition. Access should be restricted to authorized personnel only, with appropriate safety signage and inventory controls.

What to do in case of contact with 1-methyl-2,4-dinitrobenzene?

Immediate action is required upon contact with 1-methyl-2,4-dinitrobenzene. For skin contact, remove contaminated clothing and wash thoroughly with soap and water for at least 15 minutes. If inhaled, move to fresh air immediately. For eye contact, flush with clean water for at least 15 minutes. In case of ingestion, do not induce vomiting and seek immediate medical attention. Always inform medical personnel about the specific chemical involved and provide safety data sheet information.

How to dispose of 1-methyl-2,4-dinitrobenzene properly?

1-methyl-2,4-dinitrobenzene disposal must comply with local, national, and international hazardous waste regulations. The substance cannot be disposed of through normal waste streams due to its toxic and potentially carcinogenic properties. Licensed hazardous waste disposal companies must handle the waste, typically through high-temperature incineration or other approved treatment methods. All disposal activities must be documented and tracked according to regulatory requirements. Empty containers also require special handling as hazardous waste.

How to transport 1-methyl-2,4-dinitrobenzene?

1-methyl-2,4-dinitrobenzene is classified as ADR Class 6.1 (toxic substances), Packing Group II, indicating significant transport hazards. Transportation requires compliance with dangerous goods regulations including proper packaging, labeling with GHS pictograms (GHS06, GHS08, GHS09), and documentation. Vehicles must carry appropriate emergency equipment and drivers need hazardous materials certification. The substance must be segregated from incompatible materials during transport and emergency response information must be readily available.

Is 1-methyl-2,4-dinitrobenzene subject to specific regulations?

1-methyl-2,4-dinitrobenzene is subject to extensive regulatory oversight under multiple frameworks including REACH registration requirements, CLP classification as Category 1B carcinogen, and various national chemical control laws. The substance requires proper classification with danger signal word and multiple hazard statements covering carcinogenicity, mutagenicity, and reproductive toxicity. Users must implement risk management measures, provide safety training, and maintain detailed exposure records. Import/export may require special permits depending on jurisdiction.

Where to buy 1-methyl-2,4-dinitrobenzene in Europe?

1-methyl-2,4-dinitrobenzene is available through specialized chemical distributors in Europe, including OYSI, which serves as a reliable supplier for industrial and research applications. Due to the substance's hazardous classification, purchases typically require verification of legitimate use, appropriate handling facilities, and compliance with regulatory requirements. Buyers must demonstrate proper safety infrastructure and trained personnel. Contact OYSI for availability, technical specifications, and regulatory documentation to ensure compliant procurement of this controlled substance.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.