1,2-dibromoethane

C2H4Br2

CAS106-93-4
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

Consulting for 1,2-dibromoethane

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Identification

CAS Number
106-93-4
EC Number
203-444-5
UN Number
1605
Index Number
602-010-00-6
PubChem CID
7839

Physical-chemical properties

Molecular Formula
C2H4Br2
Molar Mass
187.86 g/mol
IUPAC Name
1,2-dibromoethane

Chemical Identifiers

InChI
InChI=1S/C2H4Br2/c3-1-2-4/h1-2H2
InChI Key
PAAZPARNPHGIKF-UHFFFAOYSA-N

Overview

1,2-dibromoethane (CAS 106-93-4) is an organobromine compound with significant industrial applications despite its serious health hazards. This colorless liquid, also known as ethylene dibromide, represents a critical chemical intermediate in various industrial processes. With the molecular formula C2H4Br2 and a molecular weight of 187.86 g/mol, 1,2-dibromoethane exhibits the characteristic properties of dihalogenated alkanes while presenting unique reactivity due to its bromine substituents. The compound's structure features two bromine atoms attached to adjacent carbon atoms, making it a valuable building block in organic synthesis and specialty chemical manufacturing. The substance carries significant safety considerations, classified as a Category 1B carcinogen with additional acute toxicity warnings across multiple exposure routes. The presence of GHS08, GHS06, and GHS09 pictograms reflects its serious health hazards, acute toxicity, and environmental concerns. Its classification under ADR Class 6.1 emphasizes the need for specialized handling and transportation protocols. Unlike some related compounds such as dichlorocadmium, which primarily poses inorganic toxicity risks, 1,2-dibromoethane's organic nature allows for bioaccumulation and metabolic activation concerns. Primary industrial applications include its use as a chemical intermediate in pharmaceutical synthesis, as a solvent for specialized applications, and in the production of other organobromine compounds. The compound also finds application in analytical chemistry and research settings where its specific reactivity profile is required. OYSI maintains availability of 1,2-dibromoethane for qualified industrial customers, ensuring compliance with all relevant European chemical regulations and providing comprehensive safety documentation for responsible handling and application.

Safety & Classification

Danger
Classification:

Carc. 1B; Acute Tox. 3 *; Acute Tox. 3 *; Acute Tox. 3 *; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2;...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H350

May cause cancer.

H331

Toxic if inhaled.

H311

Toxic in contact with skin.

H301

Toxic if swallowed.

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Toxic

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1605
ADR Class6.1
Packing GroupI
Tunnel CodeC/D
Proper Shipping NameEthylendibromid
Marine PollutantNo

Frequently Asked Questions

What is 1,2-dibromoethane?

1,2-dibromoethane is an organobromine compound with the molecular formula C2H4Br2 and CAS number 106-93-4. This chemical substance has a molecular weight of 187.86 g/mol and belongs to the family of dibromoalkanes. It is classified as a highly hazardous substance with carcinogenic properties (Carc. 1B) and acute toxicity (Acute Tox. 3). The compound requires careful handling due to its significant health risks and environmental concerns.

What are the physicochemical properties of 1,2-dibromoethane?

1,2-dibromoethane is a colorless liquid with a sweet, chloroform-like odor at room temperature. It has a high density and is slightly soluble in water but miscible with most organic solvents including alcohols and ethers. The compound has a relatively low boiling point and high vapor pressure, making it volatile. Its chemical structure consists of two carbon atoms each bonded to a bromine atom, creating a symmetrical dibromoalkane molecule.

What is 1,2-dibromoethane used for?

1,2-dibromoethane is primarily used as an intermediate in chemical synthesis and as a solvent in specialized industrial applications. It serves as a fumigant for soil treatment and grain storage, though this use has been largely restricted due to health concerns. The compound is also utilized in the production of other brominated chemicals and as a scavenging agent in leaded gasoline formulations, although environmental regulations have limited many of these applications.

How to handle 1,2-dibromoethane safely?

1,2-dibromoethane requires strict safety protocols including wearing appropriate personal protective equipment such as chemical-resistant gloves, safety goggles, and respiratory protection. Work must be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Due to its carcinogenic classification (Carc. 1B) and acute toxicity, minimize skin contact and vapor inhalation. Ensure emergency washing facilities are readily available and follow established chemical hygiene procedures at all times.

How to store 1,2-dibromoethane correctly?

1,2-dibromoethane must be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers away from incompatible materials such as strong oxidizers and alkali metals. Storage areas should be equipped with appropriate spill containment measures and emergency equipment. Due to its volatile nature and toxicity, storage should comply with local regulations for hazardous substances and be limited to authorized personnel only.

What to do in case of contact with 1,2-dibromoethane?

1,2-dibromoethane exposure requires immediate action: for skin contact, remove contaminated clothing and wash affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush immediately with clean water for 15 minutes while holding eyelids open. If inhaled, move to fresh air immediately and seek medical attention. For ingestion, do not induce vomiting and seek immediate medical care. Always consult a physician after any exposure incident.

How to dispose of 1,2-dibromoethane appropriately?

1,2-dibromoethane disposal must comply with local and international hazardous waste regulations due to its toxic and carcinogenic properties. The substance cannot be disposed of in regular waste streams and requires treatment by licensed hazardous waste disposal companies. Incineration at high temperatures in specialized facilities is typically the preferred disposal method. Always consult with environmental authorities and waste management professionals to ensure proper disposal procedures and documentation are followed.

How to transport 1,2-dibromoethane?

1,2-dibromoethane is classified under ADR as Class 6.1 (toxic substances) with Packing Group I, indicating high toxicity. Transportation requires proper hazardous goods packaging, labeling with appropriate GHS pictogrammes (GHS08, GHS06, GHS09), and accompanying safety documentation. Vehicles must carry emergency response information and drivers need hazardous materials certification. Shipments must comply with international dangerous goods regulations and use authorized transport companies experienced in handling toxic chemicals.

Is 1,2-dibromoethane subject to specific regulations?

1,2-dibromoethane is subject to extensive regulatory oversight under REACH, CLP, and other chemical safety frameworks due to its carcinogenic classification and environmental concerns. The substance requires registration, authorization procedures, and strict compliance with occupational exposure limits. Many countries have implemented restrictions or bans on certain uses, particularly as a fumigant. Companies handling this chemical must maintain detailed safety data sheets, implement risk management measures, and ensure regulatory compliance.

Where to buy 1,2-dibromoethane in Europe?

1,2-dibromoethane is available through specialized chemical distributors in Europe, including OYSI, which supplies high-quality chemical products to industrial customers across the European market. Due to its hazardous classification and regulatory restrictions, purchase requires proper authorization, compliance documentation, and adherence to safety protocols. Buyers must demonstrate legitimate industrial use and appropriate handling capabilities. Contact OYSI's technical sales team for availability, specifications, and regulatory guidance for your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.