2-hydroxyethyl 2-methylprop-2-enoate

C6H10O3

CAS868-77-9
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
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Identification

CAS Number
868-77-9
EC Number
212-782-2
UN Number
Index Number
607-124-00-X
PubChem CID
13360

Physical-chemical properties

Molecular Formula
C6H10O3
Molar Mass
130.14 g/mol
IUPAC Name
2-hydroxyethyl 2-methylprop-2-enoate

Chemical Identifiers

InChI
InChI=1S/C6H10O3/c1-5(2)6(8)9-4-3-7/h7H,1,3-4H2,2H3
InChI Key
WOBHKFSMXKNTIM-UHFFFAOYSA-N

Overview

2-hydroxyethyl 2-methylprop-2-enoate (CAS 868-77-9) is a methacrylate ester monomer with reactive vinyl functionality and hydroxyl group providing versatile polymerization properties. This chemical compound, also known by its EC number 212-782-2, represents an important member of the methacrylate family with molecular formula C6H10O3 and molecular weight of 130.14 g/mol. The presence of both a methacrylate double bond and a terminal hydroxyl group makes this substance particularly valuable in polymer chemistry and industrial applications requiring crosslinking capabilities. The compound exhibits moderate hazard properties classified under GHS regulations, displaying skin and eye irritation potential (Skin Irrit. 2; Eye Irrit. 2) as well as skin sensitization characteristics (Skin Sens. 1). The GHS07 pictogram and "Warning" signal word indicate the need for appropriate handling precautions during industrial use. These safety considerations are typical for reactive methacrylate compounds and require proper ventilation, protective equipment, and trained personnel for safe handling. Primary industrial applications include UV-curable coatings, adhesives, and specialty polymer formulations where the hydroxyl functionality enables hydrogen bonding and enhanced adhesion properties. The compound serves as a reactive diluent in radiation-curable systems and as a crosslinking agent in thermosetting resins. Unlike simpler compounds such as 4-nitrophenol, this methacrylate offers both reactivity and functionality in a single molecule, making it valuable for advanced material applications. The bifunctional nature of 2-hydroxyethyl 2-methylprop-2-enoate allows for controlled polymerization and network formation, essential in high-performance coating systems and composite materials. OYSI maintains reliable supply chains for this technical grade chemical compound to support European industrial customers' specialized formulation requirements.

Safety & Classification

Warning
Classification:

Skin Irrit. 2; Eye Irrit. 2; Skin Sens. 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H317

May cause an allergic skin reaction.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Frequently Asked Questions

What is 2-hydroxyethyl 2-methylprop-2-enoate?

2-hydroxyethyl 2-methylprop-2-enoate is an organic compound with molecular formula C6H10O3 and CAS number 868-77-9. It belongs to the family of methacrylate esters, characterized by the presence of both hydroxyl and ester functional groups. With a molecular weight of 130.14 g/mol, this chemical is classified as a skin and eye irritant and potential skin sensitizer, requiring careful handling in industrial applications.

What are the physicochemical properties of 2-hydroxyethyl 2-methylprop-2-enoate?

2-hydroxyethyl 2-methylprop-2-enoate is typically a clear to slightly yellow liquid at room temperature. The compound exhibits moderate viscosity and has good solubility in polar organic solvents due to its hydroxyl group. Its methacrylate structure provides reactivity toward polymerization reactions. The presence of both hydrophilic hydroxyl and hydrophobic methacrylate portions gives it amphiphilic characteristics, making it useful in various formulation applications.

What is 2-hydroxyethyl 2-methylprop-2-enoate used for?

2-hydroxyethyl 2-methylprop-2-enoate is primarily used as a monomer in polymer synthesis and as a cross-linking agent in coating formulations. It serves as an intermediate in the production of specialty polymers, adhesives, and UV-curable resins. The compound is valuable in manufacturing dental materials, protective coatings, and various specialty chemical products where controlled polymerization and adhesion properties are required.

How to handle 2-hydroxyethyl 2-methylprop-2-enoate safely?

2-hydroxyethyl 2-methylprop-2-enoate requires careful handling due to its skin and eye irritant properties and skin sensitization potential. Essential protective equipment includes chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or use local exhaust ventilation. Avoid direct skin and eye contact. Wash hands thoroughly after handling and ensure emergency eyewash stations are readily accessible in work areas.

How to store 2-hydroxyethyl 2-methylprop-2-enoate correctly?

2-hydroxyethyl 2-methylprop-2-enoate should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep away from strong oxidizing agents and bases to prevent unwanted reactions. Store at temperatures below 25°C to maintain stability and prevent polymerization. Use appropriate secondary containment and ensure containers are properly labeled with hazard information.

What to do in case of contact with 2-hydroxyethyl 2-methylprop-2-enoate?

Skin contact with 2-hydroxyethyl 2-methylprop-2-enoate requires immediate removal of contaminated clothing and thorough washing with soap and water for at least 15 minutes. For eye contact, flush immediately with clean water for 15-20 minutes and seek medical attention. If inhaled, move to fresh air immediately. Remove from skin promptly as the compound can cause sensitization. Seek medical advice if irritation persists or allergic reactions develop.

How to dispose of 2-hydroxyethyl 2-methylprop-2-enoate appropriately?

2-hydroxyethyl 2-methylprop-2-enoate must be disposed of through licensed hazardous waste management companies in accordance with local, national, and EU waste regulations. Do not discharge into drains, soil, or water bodies. Small quantities may be absorbed onto inert material and collected in suitable containers for professional disposal. Follow waste classification codes and ensure proper documentation for waste tracking as required by regulatory authorities.

How to transport 2-hydroxyethyl 2-methylprop-2-enoate?

2-hydroxyethyl 2-methylprop-2-enoate can be transported as a non-dangerous good under ADR regulations, as it does not fall into specific dangerous goods classifications. However, proper packaging in suitable containers is essential to prevent leakage and contamination. Use appropriate labeling indicating the chemical hazards (GHS07 pictogram with Warning signal word). Ensure transport documentation includes safety data sheets and emergency contact information for incident response.

Is 2-hydroxyethyl 2-methylprop-2-enoate subject to particular regulations?

2-hydroxyethyl 2-methylprop-2-enoate is subject to REACH regulation requiring registration for manufacture or import above specified tonnages in the EU. It must be classified and labeled according to CLP regulation as Skin Irritant Category 2, Eye Irritant Category 2, and Skin Sensitizer Category 1. The substance is not currently listed as SVHC under REACH. Users must comply with occupational exposure limits and provide appropriate safety data sheets.

Where to buy 2-hydroxyethyl 2-methylprop-2-enoate in Europe?

2-hydroxyethyl 2-methylprop-2-enoate is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides reliable supply chains across Europe with proper regulatory compliance and technical support. As a professional chemical distributor, OYSI ensures products meet quality specifications and regulatory requirements including REACH registration and proper safety documentation. Contact OYSI directly for specific grades, packaging options, and availability in your region.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.