Trichloroalumane

AlCl3

trichloroalumane

CAS7446-70-0
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
7446-70-0
EC Number
231-208-1
UN Number
1726
Index Number
013-003-00-7
PubChem CID
24012

Physical-chemical properties

Molecular Formula
AlCl3
Molar Mass
133.34 g/mol
IUPAC Name
trichloroalumane

Chemical Identifiers

InChI
InChI=1S/Al.3ClH/h;3*1H/q+3;;;/p-3
InChI Key
VSCWAEJMTAWNJL-UHFFFAOYSA-K

Overview

Trichloroalumane (CAS 7446-70-0) is an inorganic aluminum halide compound with strong Lewis acid properties and high reactivity with moisture. This aluminum chloride compound, also known by its IUPAC name trichloroalumane, represents one of the most important aluminum-based chemicals in industrial applications. With the molecular formula AlCl3 and a molecular weight of 133.34 g/mol, this white to pale yellow crystalline solid exhibits exceptional catalytic properties that make it indispensable across various chemical processes. The compound's strong Lewis acid character stems from aluminum's electron-deficient nature, allowing it to readily accept electron pairs from donor molecules. From a safety perspective, trichloroalumane is classified as Skin Corr. 1B under GHS regulations, requiring the "Danger" signal word and GHS05 corrosion pictogram. Its ADR class 8 designation reflects its corrosive nature, as the compound reacts violently with water to produce hydrogen chloride gas and aluminum hydroxide. Proper handling requires specialized storage conditions away from moisture and appropriate personal protective equipment. Industrial applications primarily focus on organic synthesis catalysis, particularly in Friedel-Crafts reactions where trichloroalumane facilitates alkylation and acylation processes. The petrochemical industry extensively utilizes this compound for hydrocarbon cracking and isomerization reactions. Additionally, it serves as a critical component in aluminum production and metal treatment processes, contrasting with simpler organic compounds like butanoic acid or heptanoic acid which serve different industrial roles. OYSI maintains reliable supplies of technical-grade trichloroalumane to support diverse European industrial requirements, ensuring consistent quality and regulatory compliance for our chemical processing customers.

Safety & Classification

Danger
Classification:

Skin Corr. 1B

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1726
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping NameAluminiumchlorid, wasserfrei, fest
Marine PollutantNo

Frequently Asked Questions

What is trichloroalumane?

Trichloroalumane is an inorganic aluminum compound with the chemical formula AlCl3 and CAS number 7446-70-0. It has a molecular weight of 133.34 g/mol and is classified as a corrosive substance (Skin Corr. 1B) under the GHS system. This aluminum halide is a highly reactive chemical that readily absorbs moisture from air and forms acidic solutions. It appears as a white to pale yellow crystalline solid that sublimes at elevated temperatures and is widely used in industrial chemical processes.

What are the physicochemical properties of trichloroalumane?

Trichloroalumane appears as white to pale yellow crystalline solid at room temperature with a characteristic sharp, acrid odor. It has a melting point of approximately 192°C and sublimes readily upon heating. The compound is highly hygroscopic, meaning it absorbs moisture from air rapidly, and is highly soluble in water, producing an exothermic reaction and forming acidic solutions. It also dissolves in polar organic solvents like ethanol and ether, making it versatile for various chemical applications.

What is trichloroalumane used for?

Trichloroalumane serves as a powerful Lewis acid catalyst in organic synthesis, particularly in Friedel-Crafts reactions for alkylation and acylation of aromatic compounds. It is extensively used in the petroleum industry for hydrocarbon cracking and isomerization processes. Other applications include metal production, particularly in aluminum refining, pharmaceutical synthesis, dye manufacturing, and as a catalyst in polymerization reactions. Its strong acidic properties make it valuable in various industrial chemical transformations and manufacturing processes.

How to handle trichloroalumane safely?

Trichloroalumane requires strict safety measures due to its corrosive nature (Skin Corr. 1B classification). Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, face shield, and protective clothing. Work in well-ventilated areas or under fume hoods to avoid inhalation of vapors. Handle containers carefully to prevent spills and avoid contact with moisture, as the reaction can be violent. Keep emergency eyewash stations and safety showers accessible, and ensure proper training before handling this corrosive substance.

How to store trichloroalumane correctly?

Trichloroalumane must be stored in tightly sealed, moisture-proof containers in a cool, dry, and well-ventilated area away from heat sources and incompatible materials. Keep containers away from water, alcohols, and strong bases, as these can cause violent reactions. Store in areas with appropriate corrosion-resistant flooring and secondary containment systems. Maintain storage temperatures below 25°C when possible, and ensure storage areas are equipped with appropriate fire suppression systems and spill containment materials for emergency situations.

What to do in case of contact with trichloroalumane?

Skin contact with trichloroalumane requires immediate removal of contaminated clothing and thorough rinsing with large amounts of water for at least 15 minutes. For eye contact, flush immediately with clean water for at least 15 minutes while holding eyelids open. If inhaled, move the person to fresh air immediately. For ingestion, do not induce vomiting; rinse mouth with water if conscious. Seek immediate medical attention in all cases of exposure, as this substance can cause severe chemical burns and tissue damage.

How to dispose of trichloroalumane appropriately?

Trichloroalumane disposal must comply with local, national, and EU waste regulations as it is classified as hazardous waste. Small quantities can be carefully neutralized by trained personnel using appropriate bases under controlled conditions, but this should only be done with proper safety equipment and expertise. Large quantities require disposal through licensed hazardous waste contractors. Never dispose of this substance in regular trash, drains, or sewers. Contaminated containers must also be treated as hazardous waste and disposed of through appropriate channels.

How to transport trichloroalumane?

Trichloroalumane is classified as dangerous goods under ADR regulations with Class 8 (corrosive substances) and Packing Group II designation. Transportation requires appropriate UN-specification packaging, proper labeling with GHS05 corrosive pictograms, and transport documents. Vehicles must carry appropriate emergency equipment and drivers need ADR training certification. Packages must be properly secured to prevent damage during transport, and emergency response information must be readily available. Always use authorized carriers experienced in handling corrosive chemical substances.

Is trichloroalumane subject to particular regulations?

Trichloroalumane is subject to various European regulations including REACH registration requirements for importers and manufacturers. Under CLP regulation, it must be classified and labeled as Skin Corr. 1B with appropriate hazard statements and precautionary measures. It is not currently listed as an SVHC (Substance of Very High Concern). Industrial users must comply with occupational exposure limits, waste regulations, and transport requirements. Some applications may require specific permits or notifications depending on quantities and intended use within EU member states.

Where to buy trichloroalumane in Europe?

Trichloroalumane is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across the continent. OYSI provides high-quality aluminum chloride with proper documentation, safety data sheets, and regulatory compliance for professional applications. As a regulated corrosive substance, purchases typically require verification of legitimate industrial use and proper handling capabilities. Contact OYSI directly for availability, specifications, and delivery options to your location within Europe, ensuring compliance with all applicable transportation and handling requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.