1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane

C10H8Cl8

CAS8001-35-2
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
8001-35-2
EC Number
232-283-3
UN Number
2761
Index Number
602-044-00-1
PubChem CID
5284469

Physical-chemical properties

Molecular Formula
C10H8Cl8
Molar Mass
411.80 g/mol
IUPAC Name
1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane

Chemical Identifiers

InChI
InChI=1S/C10H8Cl8/c1-4-7(2-11,3-12)9(16)6(14)5(13)8(4,15)10(9,17)18/h5-6H,1-3H2
InChI Key
OEJNXTAZZBRGDN-UHFFFAOYSA-N

Overview

1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane (CAS 8001-35-2) is a highly chlorinated bicyclic organic compound with significant industrial applications and notable safety considerations. This complex organochlorine compound, with molecular formula C10H8Cl8 and molecular weight 411.8 g/mol, represents one of the most heavily chlorinated bicycloheptane derivatives used in industrial chemistry. The substance features a characteristic norbornane backbone extensively substituted with chlorine atoms and chloromethyl groups, resulting in unique chemical properties that make it valuable for specialized technical applications. The compound exhibits significant safety considerations, classified under multiple hazard categories including carcinogenicity (Category 2), acute toxicity, skin irritation, and environmental hazards. Its classification under ADR Class 6.1 reflects its toxic nature, requiring careful handling protocols and specialized storage conditions. The GHS pictograms GHS08, GHS06, and GHS09 indicate health hazards, acute toxicity, and environmental dangers respectively. Key industrial applications include use as an intermediate in organic synthesis, flame retardant formulations, and specialized polymer additives. The compound's high chlorine content and stable bicyclic structure make it particularly effective in applications requiring thermal stability and fire resistance. Unlike simpler aromatic compounds such as N-methylaniline, this highly chlorinated structure provides enhanced chemical resistance and thermal properties. Safety protocols are essential when handling this material, given its potential carcinogenic properties and environmental impact classification as Aquatic Acute 1 and Aquatic Chronic hazard. Professional users must implement appropriate personal protective equipment and waste management procedures. OYSI maintains technical-grade supplies of this specialized compound for qualified industrial customers across Europe.

Safety & Classification

Danger
Classification:

Carc. 2; Acute Tox. 4 *; Acute Tox. 3 *; STOT SE 3; Skin Irrit. 2; Aquatic Acute 1; Aquatic Chron...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H351

Suspected of causing cancer.

H312

Harmful in contact with skin.

H301

Toxic if swallowed.

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2761
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameCamphechlor (ISO)
Marine PollutantNo

Frequently Asked Questions

What is 1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane?

1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane is a highly chlorinated organic compound with the molecular formula C10H8Cl8 and a molecular weight of 411.8 g/mol. This bicyclic structure contains eight chlorine atoms, making it a heavily halogenated hydrocarbon. The compound is classified as a hazardous substance with carcinogenic properties and acute toxicity, requiring careful handling and specialized safety measures in industrial applications.

What are the physicochemical properties of 1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane?

1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane is a solid compound at room temperature due to its high molecular weight and extensive chlorination. The eight chlorine atoms contribute to its high density and low volatility. As a heavily halogenated hydrocarbon, it exhibits poor water solubility but good solubility in organic solvents. The compound's stability is enhanced by its saturated bicyclic structure, though the multiple chlorine substituents make it environmentally persistent.

What is 1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane used for?

1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane is primarily used in specialized industrial applications where its unique chlorinated structure provides specific chemical properties. Its applications may include use as a chemical intermediate in synthetic processes, as an additive in certain industrial formulations, or in research and development activities. Due to its carcinogenic classification and high toxicity, its use is strictly regulated and limited to professional industrial settings with appropriate safety controls.

How to handle 1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane safely?

1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane requires maximum safety precautions due to its carcinogenic and toxic properties. Personnel must wear complete personal protective equipment including chemical-resistant gloves, protective clothing, and respiratory protection. Work must be conducted in well-ventilated areas or under fume hoods. Avoid skin contact, inhalation, and ingestion. Regular health monitoring of exposed workers is essential, and only trained personnel should handle this substance.

How to store 1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane correctly?

1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane must be stored in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Use tightly sealed, chemically resistant containers to prevent contamination and release. Storage areas should be equipped with appropriate containment systems and emergency response equipment. Access must be restricted to authorized personnel only. Regular container inspections are necessary to ensure integrity and prevent environmental release.

What to do in case of contact with 1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane?

Immediate medical attention is required for any contact with 1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane. For skin contact, remove contaminated clothing and wash affected area thoroughly with soap and water for at least 15 minutes. If inhaled, move to fresh air immediately. In case of eye contact, flush with clean water for at least 15 minutes. Never induce vomiting if ingested. Contact emergency services and provide the safety data sheet to medical personnel.

How to dispose of 1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane appropriately?

1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane must be disposed of as hazardous waste through licensed waste management facilities specialized in handling carcinogenic and toxic substances. High-temperature incineration under controlled conditions is typically required. Never dispose of in regular waste streams, sewers, or the environment. All disposal activities must comply with local, national, and European waste regulations. Maintain detailed documentation of all disposal activities for regulatory compliance and traceability.

How to transport 1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane?

1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane is classified under ADR Class 6.1 (Toxic substances), Packing Group II, indicating significant toxicity requiring special transport precautions. Shipments must use UN-approved packaging and be properly labeled with appropriate hazard diamonds. Transport vehicles must carry emergency response information and appropriate containment materials. Only certified carriers experienced in hazardous materials transport should handle shipments. All transport documentation must comply with ADR/RID regulations for toxic substances.

Is 1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane subject to special regulations?

1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane is subject to extensive European chemical regulations including REACH registration requirements and CLP classification obligations. Its carcinogenic classification (Category 2) triggers specific workplace exposure limits and health surveillance requirements. The substance may be subject to authorization procedures or restrictions under REACH. Companies must maintain detailed safety data sheets, conduct chemical safety assessments, and implement appropriate risk management measures throughout the supply chain.

Where to buy 1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane in Europe?

1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane is available through OYSI, a specialized European distributor of chemical products with expertise in hazardous substances. As a professional chemical supplier, OYSI ensures full regulatory compliance, proper documentation, and safe packaging for this highly regulated substance. Due to its carcinogenic properties and strict regulations, purchases are limited to qualified industrial users with appropriate safety facilities and trained personnel. Contact OYSI directly for availability, technical specifications, and regulatory documentation.

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1,4,5,6,7,7-hexachloro-2,2-bis(chloromethyl)-3-methylidenebicyclo[2.2.1]heptane is a dangerous good. We support you with labeling, packaging, and transport documentation.

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Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.