1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate

C14H20N2O8S2

CAS2074-50-2
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
2074-50-2
EC Number
218-196-3
UN Number
2781
Index Number
613-090-00-7
PubChem CID
62422

Physical-chemical properties

Molecular Formula
C14H20N2O8S2
Molar Mass
408.50 g/mol
IUPAC Name
1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate

Chemical Identifiers

InChI
InChI=1S/C12H14N2.2CH4O4S/c1-13-7-3-11(4-8-13)12-5-9-14(2)10-6-12;2*1-5-6(2,3)4/h3-10H,1-2H3;2*1H3,(H,2,3,4)/q+2;;/p-2
InChI Key
WXJYKXOIFICRPR-UHFFFAOYSA-L

Overview

1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate (CAS 2074-50-2) is a bipyridinium quaternary ammonium compound with high toxicity and redox activity. This specialized chemical compound, also known by its EC number 218-196-3, belongs to the family of bipyridinium salts characterized by two methylated pyridine rings connected through ionic bonding with methyl sulfate counterions. With a molecular formula of C14H20N2O8S2 and molecular weight of 408.5 g/mol, this quaternary ammonium compound exhibits distinctive electrochemical properties that make it valuable in various technical applications. The compound presents significant safety considerations, classified under multiple acute toxicity categories (Acute Tox. 2 and 3) with additional classifications for specific target organ toxicity (STOT SE 3, STOT RE 1), skin irritation (Skin Irrit. 2), and eye irritation (Eye Irrit. 2). The GHS pictograms GHS06, GHS08, and GHS09 indicate its toxic nature, health hazards, and environmental concerns respectively. Transportation falls under ADR class 6.1, reflecting its toxic properties. Unlike simpler aromatic amines such as N-methylaniline, this bipyridinium structure provides enhanced stability and specific redox characteristics. Industrial applications primarily include electrochemical research, specialized analytical chemistry procedures, and advanced materials synthesis where controlled redox behavior is essential. The compound serves in electroplating solutions and as an intermediate in pharmaceutical research, similar to how other nitrogen-containing aromatics like phenylhydrazine function in synthetic pathways, though with distinctly different reactivity profiles. OYSI maintains technical-grade supplies of this specialized compound for qualified industrial customers across Europe.

Safety & Classification

Danger
Classification:

Acute Tox. 2 *; Acute Tox. 3 *; Acute Tox. 3 *; STOT SE 3; STOT RE 1; Skin Irrit. 2; Eye Irrit. 2...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H330

Fatal if inhaled.

H311

Toxic in contact with skin.

H301

Toxic if swallowed.

H335

May cause respiratory irritation.

H372

Causes damage to organs through prolonged or repeated exposure.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Toxic

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2781
ADR Class6.1
Packing GroupIII
Tunnel CodeE
Proper Shipping NameParaquatdimethylsulfat
Marine PollutantNo

Frequently Asked Questions

What is 1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate?

1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate is a bis-quaternary ammonium compound with CAS number 2074-50-2 and molecular formula C14H20N2O8S2. This chemical substance has a molecular weight of 408.5 g/mol and belongs to the pyridinium salt family. It is classified as a highly hazardous substance with multiple toxicity concerns, requiring careful handling and specialized safety measures in industrial applications.

What are the physicochemical properties of 1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate?

1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate is a quaternary ammonium salt that typically appears as a crystalline solid at room temperature. As a methylsulfate salt of a bipyridinium compound, it generally exhibits good water solubility due to its ionic nature. The compound's exact physical appearance, odor characteristics, and specific solubility parameters depend on purity and crystalline form, requiring consultation of detailed technical specifications for precise values.

What is 1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate used for?

1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate is primarily used as a specialized chemical intermediate in research and industrial applications. Bipyridinium compounds like this are commonly employed in electrochemical applications, analytical chemistry, and as precursors for advanced materials synthesis. Due to its high toxicity classification, its use is typically restricted to professional and industrial settings where appropriate safety controls and expertise are available.

How to handle 1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate safely?

1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate requires extensive safety precautions due to its Acute Tox. 2 classification and multiple hazard classes. Personnel must wear full protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection. Work should be conducted in well-ventilated areas or under fume hoods. Avoid skin and eye contact, inhalation, and ingestion. Emergency procedures and first aid measures must be readily accessible before handling.

How to store 1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate correctly?

1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate must be stored in a secure, cool, dry place away from heat sources and incompatible materials. Due to its high toxicity classification, storage requires restricted access with appropriate warning labels and safety documentation. The container should be tightly sealed to prevent contamination and exposure. Storage areas must comply with local regulations for toxic substances and include appropriate spill containment measures.

What to do in case of contact with 1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate?

Immediate medical attention is required for any contact with 1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate due to its Acute Tox. 2 classification. For skin contact, remove contaminated clothing and rinse thoroughly with water for at least 15 minutes. In case of eye contact, flush immediately with clean water. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek emergency medical care. Always contact poison control or emergency services.

How to dispose of 1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate properly?

1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate must be disposed of as hazardous waste according to local and European regulations due to its high toxicity classification. Disposal requires specialized hazardous waste contractors authorized to handle toxic substances. The waste must be properly labeled, documented, and transported according to ADR Class 6.1 requirements. Incineration at authorized high-temperature facilities is typically the preferred disposal method for such quaternary ammonium compounds.

How to transport 1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate?

1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate is classified as ADR Class 6.1 (toxic substances), Packing Group III for transportation purposes. Transport requires appropriate UN-specification packaging with proper labeling including GHS06, GHS08, and GHS09 pictograms. Shipping documentation must include the correct UN number and hazard classifications. Transportation must comply with ADR regulations for toxic substances, including driver certification and vehicle requirements for dangerous goods transport.

Is 1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate subject to specific regulations?

1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate is subject to comprehensive European chemical regulations under REACH and CLP due to its multiple hazard classifications. While not currently listed as a SVHC, its Acute Tox. 2 and STOT RE 1 classifications trigger strict labeling, safety data sheet, and handling requirements. Users must comply with occupational exposure limits, worker protection regulations, and may require authorization for certain uses depending on quantities and applications.

Where to buy 1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate in Europe?

1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate is available through OYSI, a specialized European distributor of technical chemicals. Due to its high toxicity classification and regulatory requirements, purchase is typically restricted to qualified industrial and research customers with appropriate safety infrastructure. Buyers must demonstrate compliance with handling and storage requirements for toxic substances. Contact OYSI directly for availability, technical specifications, and regulatory documentation required for this controlled substance.

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1-methyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium;methyl sulfate is a dangerous good. We support you with labeling, packaging, and transport documentation.

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Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.