1,1,1,2,2-pentachloroethane
C2HCl5
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Identification
- CAS Number
- 76-01-7
- EC Number
- 200-925-1
- UN Number
- 1669
- Index Number
- 602-017-00-4
- PubChem CID
- 6419
Physical-chemical properties
- Molecular Formula
- C2HCl5
- Molar Mass
- 202.30 g/mol
- IUPAC Name
- 1,1,1,2,2-pentachloroethane
Chemical Identifiers
- InChI
- InChI=1S/C2HCl5/c3-1(4)2(5,6)7/h1H
- InChI Key
- BNIXVQGCZULYKV-UHFFFAOYSA-N
Overview
1,1,1,2,2-pentachloroethane (CAS 76-01-7) is a chlorinated hydrocarbon solvent with high density and significant industrial cleaning properties. This highly chlorinated organic compound represents one of the most substituted ethane derivatives, containing five chlorine atoms attached to a two-carbon backbone. With its molecular formula C2HCl5 and molecular weight of 202.3 g/mol, pentachloroethane exhibits the characteristic properties of heavy chlorinated solvents, including excellent solvency power for oils, greases, and various organic materials. The compound's structure places it among other chlorinated hydrocarbons used in specialized industrial applications, though it requires more stringent handling protocols compared to lighter alternatives like dichlorocadmium-based systems. The substance is classified under multiple hazard categories, including Category 2 carcinogen (Carc. 2) and Specific Target Organ Toxicity - Repeated Exposure Category 1 (STOT RE 1), necessitating comprehensive risk management measures. Its GHS08 and GHS09 pictograms indicate both health hazards and environmental concerns, particularly regarding aquatic ecosystems where it poses chronic toxicity risks. Transportation falls under ADR Class 6.1, reflecting its toxic nature and requiring specialized handling during logistics operations. Primary industrial applications include precision cleaning of electronic components, degreasing of metal parts in aerospace manufacturing, and specialized extraction processes in chemical synthesis. The compound's stability and selective solvency properties make it valuable in applications where other solvents prove inadequate, particularly in removing stubborn contaminants from sensitive equipment. OYSI maintains strategic inventory levels of 1,1,1,2,2-pentachloroethane to support European industrial customers requiring this specialized chlorinated solvent for critical manufacturing processes.
Safety & Classification
Carc. 2; STOT RE 1; Aquatic Chronic 2
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Transport (ADR)
| UN Number | 1669 |
| ADR Class | 6.1 |
| Packing Group | II |
| Tunnel Code | D/E |
| Proper Shipping Name | Pentachlorethan |
| Marine Pollutant | No |
Frequently Asked Questions
What is 1,1,1,2,2-pentachloroethane?
1,1,1,2,2-pentachloroethane is a chlorinated hydrocarbon with the molecular formula C2HCl5 and CAS number 76-01-7. This chemical compound has a molecular weight of 202.3 g/mol and belongs to the family of polychlorinated ethanes. It is classified as a hazardous substance with carcinogenic properties (Category 2) and potential for specific target organ toxicity following repeated exposure. The compound also presents chronic aquatic toxicity concerns.
What are the physicochemical properties of 1,1,1,2,2-pentachloroethane?
1,1,1,2,2-pentachloroethane is a dense, colorless liquid at room temperature with a characteristic sweet, chloroform-like odor. It has low solubility in water but is miscible with most organic solvents including alcohols, ethers, and hydrocarbons. The compound has a high density due to its chlorine content and exhibits low volatility compared to lighter chlorinated compounds. Its chemical stability makes it resistant to hydrolysis under normal conditions.
What is 1,1,1,2,2-pentachloroethane used for?
1,1,1,2,2-pentachloroethane is primarily used as an industrial solvent and chemical intermediate in specialized applications. It serves as a solvent for cleaning and degreasing operations in metal processing industries. The compound is also utilized as an intermediate in the synthesis of other chlorinated chemicals and pharmaceuticals. Due to its hazardous classification and environmental concerns, its use has become increasingly restricted and is limited to specific industrial processes with appropriate safety measures.
How to handle 1,1,1,2,2-pentachloroethane safely?
1,1,1,2,2-pentachloroethane requires strict safety protocols during handling due to its carcinogenic classification and toxicity. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, and respiratory protection in well-ventilated areas. Work should be conducted in fume hoods or with local exhaust ventilation to minimize inhalation exposure. Avoid skin contact and ensure immediate washing if contact occurs. Regular health monitoring is recommended for workers with potential exposure.
How to store 1,1,1,2,2-pentachloroethane correctly?
1,1,1,2,2-pentachloroethane must be stored in tightly sealed containers made of compatible materials in cool, dry, well-ventilated areas away from heat sources and incompatible substances. Storage areas should be equipped with appropriate containment systems and fire suppression equipment. The compound should be kept away from strong bases, metals, and oxidizing agents. Secondary containment is recommended to prevent environmental contamination in case of leaks or spills.
What to do in case of contact with 1,1,1,2,2-pentachloroethane?
Immediate action is required following contact with 1,1,1,2,2-pentachloroethane. For skin contact, remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. If inhaled, move the person to fresh air immediately and seek medical attention. For eye contact, rinse continuously with clean water for at least 15 minutes. In all cases of exposure, seek immediate medical attention and provide the safety data sheet to healthcare providers.
How to dispose of 1,1,1,2,2-pentachloroethane appropriately?
1,1,1,2,2-pentachloroethane disposal must comply with local, national, and international hazardous waste regulations due to its toxic and potentially carcinogenic properties. The compound requires treatment at authorized hazardous waste facilities equipped for chlorinated solvent disposal, typically through high-temperature incineration. Waste containers must be properly labeled and handled by licensed waste management companies. Never dispose of this substance in regular waste streams or sewage systems due to environmental contamination risks.
How to transport 1,1,1,2,2-pentachloroethane?
1,1,1,2,2-pentachloroethane is classified under ADR Class 6.1 (toxic substances) Packing Group II, requiring specialized transport procedures for hazardous materials. Transportation must comply with dangerous goods regulations including proper packaging, labeling with appropriate hazard symbols, and documentation. Vehicles must carry emergency response information and drivers require hazardous materials training. Shipments must use UN-approved packaging and display the required toxic substance markings and environmental hazard symbols.
Is 1,1,1,2,2-pentachloroethane subject to specific regulations?
1,1,1,2,2-pentachloroethane is subject to comprehensive chemical regulations including REACH registration requirements in Europe and CLP classification as Carcinogenic Category 2, STOT RE 1, and Aquatic Chronic 2. The compound requires safety data sheets, appropriate labeling with GHS08 and GHS09 pictograms, and the signal word 'Danger'. Workplace exposure limits apply in most jurisdictions, and environmental release reporting may be mandatory depending on quantities used.
Where to buy 1,1,1,2,2-pentachloroethane in Europe?
1,1,1,2,2-pentachloroethane is available through specialized chemical distributors in Europe, including OYSI, which supplies industrial chemicals to European markets. Due to its hazardous classification and regulatory requirements, purchase is typically restricted to qualified industrial users with appropriate safety infrastructure and regulatory compliance. Buyers must demonstrate legitimate industrial use and proper handling capabilities. Contact OYSI for availability, regulatory documentation, and technical support for this specialized chemical product.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.