1,1-dichloroethane

C2H4Cl2

CAS75-34-3
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

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Identification

CAS Number
75-34-3
EC Number
200-863-5
UN Number
2362
Index Number
602-011-00-1
PubChem CID
6365

Physical-chemical properties

Molecular Formula
C2H4Cl2
Molar Mass
98.96 g/mol
IUPAC Name
1,1-dichloroethane

Chemical Identifiers

InChI
InChI=1S/C2H4Cl2/c1-2(3)4/h2H,1H3
InChI Key
SCYULBFZEHDVBN-UHFFFAOYSA-N

Overview

1,1-dichloroethane (CAS 75-34-3) is a chlorinated hydrocarbon solvent with high volatility and moderate toxicity properties. This organochlorine compound, with the molecular formula C2H4Cl2, serves as an important industrial solvent and chemical intermediate in various manufacturing processes. As a colorless liquid with a characteristic sweet odor, 1,1-dichloroethane exhibits excellent solvent properties for oils, fats, and numerous organic compounds, making it valuable in specialized industrial applications. The substance presents significant safety considerations due to its flammable nature and toxicological profile. Classified as a Category 2 flammable liquid under GHS regulations, it requires careful handling and storage protocols. The compound poses acute toxicity risks through inhalation and can cause specific target organ toxicity affecting the central nervous system. Additionally, it may cause eye irritation and has potential environmental impacts on aquatic ecosystems with chronic toxicity effects. From a chemical perspective, 1,1-dichloroethane belongs to the same family of chlorinated solvents as other industrial chemicals, though it exhibits different properties compared to aromatic compounds like ethylbenzene and styrene, which find applications in polymer production. Its moderate boiling point and stability make it particularly suitable for extraction processes and as a reaction medium in organic synthesis. Primary industrial applications include its use as a solvent in metal degreasing operations, as an extractant in pharmaceutical manufacturing, and as an intermediate in the production of other chlorinated compounds. The chemical industry also utilizes it in specialized cleaning applications where its specific solvent characteristics are required. OYSI maintains reliable supply capabilities for 1,1-dichloroethane to support various European industrial sectors requiring this specialized chlorinated solvent.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; Acute Tox. 4 *; STOT SE 3; Eye Irrit. 2; Aquatic Chronic 3

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H302

Harmful if swallowed.

H335

May cause respiratory irritation.

H319

Causes serious eye irritation.

H412

Harmful to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2362
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping Name1,1-Dichlorethan
Marine PollutantNo

Frequently Asked Questions

What is 1,1-dichloroethane?

1,1-dichloroethane is an organochlorine compound with the chemical formula C2H4Cl2 and CAS number 75-34-3. It belongs to the dichloroethane family and has a molecular weight of 98.96 g/mol. This substance is classified as a flammable liquid with toxic properties, posing risks to human health and the environment. It appears as a colorless liquid with a characteristic chloroform-like odor and is used primarily as a chemical intermediate in various industrial processes.

What are the physicochemical properties of 1,1-dichloroethane?

1,1-dichloroethane is a colorless liquid at room temperature with a sweet, chloroform-like odor. It has a boiling point of approximately 57°C and a density higher than water. The substance is slightly soluble in water but readily miscible with most organic solvents including alcohols, ethers, and hydrocarbons. It exhibits moderate volatility and can form flammable vapor-air mixtures. The compound is relatively stable under normal conditions but can decompose when exposed to high temperatures or strong bases.

What is 1,1-dichloroethane used for?

1,1-dichloroethane is primarily used as a chemical intermediate in the production of vinylidene chloride, which is used to manufacture polyvinylidene chloride plastics and films. It serves as a solvent for various industrial applications, including degreasing operations and extraction processes. The substance is also utilized in the synthesis of other chlorinated compounds and as a feedstock in chemical manufacturing. Additionally, it finds limited use in specialized cleaning formulations and as a process solvent in certain pharmaceutical applications.

How to handle 1,1-dichloroethane safely?

1,1-dichloroethane must be handled with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume extraction systems to prevent vapor inhalation. Avoid contact with skin and eyes, and prevent ingestion. Keep away from heat sources, sparks, and open flames due to its flammable nature. Use non-sparking tools and ensure proper grounding of equipment to prevent static electricity buildup during transfer operations.

How to store 1,1-dichloroethane correctly?

1,1-dichloroethane should be stored in a cool, dry, well-ventilated area away from heat sources, ignition sources, and direct sunlight. Use appropriate containers made of compatible materials and ensure they are tightly sealed to prevent vapor release. Store separately from incompatible materials such as strong oxidizers, strong bases, and reactive metals. Maintain storage temperatures below 25°C and implement appropriate fire prevention measures. Regular inspection of containers for leaks or deterioration is essential for safe storage.

What to do in case of contact with 1,1-dichloroethane?

In case of skin contact with 1,1-dichloroethane, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. For eye contact, flush immediately with clean water for 15-20 minutes and seek medical attention. If inhaled, move the person to fresh air and keep them at rest. In case of ingestion, do not induce vomiting and seek immediate medical attention. Always consult a physician if symptoms persist or if significant exposure has occurred.

How to dispose of 1,1-dichloroethane appropriately?

1,1-dichloroethane must be disposed of as hazardous waste in accordance with local, national, and EU regulations. The substance cannot be disposed of in regular waste streams or discharged into sewers or the environment. Contact licensed hazardous waste disposal companies for proper treatment, which typically involves high-temperature incineration or other approved destruction methods. Ensure proper documentation and tracking throughout the disposal process. Empty containers should also be treated as hazardous waste unless properly cleaned and decontaminated.

How to transport 1,1-dichloroethane?

1,1-dichloroethane is classified under ADR as Class 3 (flammable liquid), Packing Group II, requiring specific transport regulations. It must be packaged in UN-approved containers and labeled with appropriate hazard markings and transport documentation. Vehicles must carry appropriate emergency equipment and drivers need ADR certification. The substance should be segregated from incompatible materials during transport and protected from heat sources. Proper shipping papers and emergency response information must accompany shipments at all times.

Is 1,1-dichloroethane subject to specific regulations?

1,1-dichloroethane is subject to various European regulations including REACH registration requirements and CLP classification as a flammable liquid with acute toxicity and environmental hazards. It is not currently listed as a Substance of Very High Concern (SVHC). The substance must comply with occupational exposure limits and workplace safety regulations. Industrial users must implement appropriate risk management measures and may need to report usage under certain circumstances. Transport is regulated under ADR/RID for dangerous goods.

Where to buy 1,1-dichloroethane in Europe?

1,1-dichloroethane is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across Europe. As a professional chemical supplier, OYSI provides quality-assured products with proper documentation including safety data sheets and certificates of analysis. The company serves various industries requiring this substance for manufacturing and processing applications. For specific availability, packaging options, and technical support, customers can contact OYSI directly through their European distribution network to discuss their 1,1-dichloroethane requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.